| 1. |
- Lobov, Gleb, et al.
(författare)
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Dynamic manipulation of optical anisotropy of suspended Poly-3-hexylthiophene nanofibers
- 2016
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Ingår i: Advanced Optical Materials. - : Wiley. - 2162-7568 .- 2195-1071. ; 4:10, s. 1651-1656
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Tidskriftsartikel (refereegranskat)abstract
- Poly-3-hexylthiophene (P3HT) nanofibers are 1D crystalline semiconducting nanostructures, which are known for their application in photovoltaics. Due to the internal arrangement, P3HT nanofibers possess optical anisotropy, which can be enhanced on a macroscale if nanofibers are aligned. Alternating electric field, applied to a solution with dispersed nanofibers, causes their alignment and serves as a method to produce solid layers with ordered nanofibers. The transmission ellipsometry measurements demonstrate the dichroic absorption and birefringence of ordered nanofibers in a wide spectral range of 400–1700 nm. Moreover, the length of nanofibers has a crucial impact on their degree of alignment. Using electric birefringence technique, it is shown that external electric field applied to the solution with P3HT nanofibers can cause direct birefringence modulation. Dynamic alignment of dispersed nanofibers changes the refractive index of the solution and, therefore, the polarization of transmitted light. A reversible reorientation of nanofibers is organized by using a quadrupole configuration of poling electrodes. With further development, the described method can be used in the area of active optical fiber components, lab-on-chip or sensors. It also reveals the potential of 1D conducting polymeric structures as objects whose highly anisotropic properties can be implemented in electro-optical applications..
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| 2. |
- Lobov, Gleb, et al.
(författare)
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Electro-optical effects of high aspect ratio P3HT nanofibers colloid in polymer micro-fluid cells
- 2017
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Ingår i: Optics Letters. - : OSA Publishing. - 0146-9592 .- 1539-4794. ; 42:11, s. 2157-2160
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Tidskriftsartikel (refereegranskat)abstract
- This Letter reports the electro-optical (EO) effect of Poly(3-hexylthiophene-2,5-diyl) (P3HT) nanofibers colloid in a polymer micro-fluidic EO cell. P3HT nanofibers are high aspect ratio semiconducting nanostructures, and can be collectively aligned by an external alternating electric field. Optical transmission modulated by the electric field is a manifestation of the electro-optical effect due to high inner crystallinity of P3HT nanofibers. According to our results, the degree of alignment reaches a maximum at 0.6 V/μm of electric field strength, implying a big polarizability value due to geometry and electrical properties of P3HT nanofibers. We believe that one-dimensional crystalline organic nanostructures have a large potential in EO devices due to their significant anisotropy, wide variety of properties, low actuation voltages, and opportunity to be tailored via adjustment of the fabrication process.
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| 3. |
- Lobov, Gleb, et al.
(författare)
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Optical birefringence from P3HT nanofibers in alternating electric field
- 2016
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Ingår i: Optics InfoBase Conference Papers. - : OSA - The Optical Society. - 9781943580194
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Konferensbidrag (refereegranskat)abstract
- AC poling allowing to control the orientation of P3HT nanofibers, result in strong optical birefringence with promising implementation in a novel type of optical modulator, without necessary embedding into any hosting matrix, e.g. liquid crystal.
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| 4. |
- Lobov, G. S., et al.
(författare)
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Direct birefringence and transmission modulation via dynamic alignment of P3HT nanofibers in an advanced opto-fluidic component
- 2017
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Ingår i: Optical Materials Express. - 2159-3930 .- 2159-3930. ; 7:1, s. 52-61
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Tidskriftsartikel (refereegranskat)abstract
- Poly-3-hexylthiophene (P3HT) nanofibers are semiconducting high-aspect ratio nanostructures with anisotropic absorption and birefringence properties found at different regions of the optical spectrum. In addition, P3HT nanofibers possess an ability to be aligned by an external electric field, while being dispersed in a liquid. In this manuscript we show that such collective ordering of nanofibers, similar to liquid crystal material, significantly changes the properties of transmitted light. With a specially fabricated opto-fluidic component, we monitored the phase and transmission modulation of light propagating through the solution of P3HT nanofibers, being placed in the electric field with strength up to 0.1 V/μm. This report describes a technique for light modulation, which can be implemented in optical fiber-based devices or on-chip integrated components.
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| 5. |
- Lobov, Gleb S., et al.
(författare)
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Electric field induced optical anisotropy of P3HT nanofibers in a liquid solution
- 2015
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Ingår i: Optical Materials Express. - : Optical Society of America. - 2159-3930 .- 2159-3930. ; 5:11, s. 2642-2647
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Tidskriftsartikel (refereegranskat)abstract
- The nanofiber morphology of regioregular Poly-3- hexylthiophene (P3HT) is a 1D crystalline structure organized by π - π stacking of the backbone chains. In this study, we report the impact of electric field on the orientation and optical properties of P3HT nanofibers dispersed in liquid solution. We demonstrate that alternating electric field aligns nanofibers, whereas static electric field forces them to migrate towards the cathode. The alignment of nanofibers introduces anisotropic optical properties, which can be dynamically manipulated until the solvent has evaporated. Time resolved spectroscopic measurements revealed that the electro-optical response time decreases significantly with the magnitude of applied electric field. Thus, for electric field 1.3 V ·μm-1 the response time was measured as low as 20 ms, while for 0.65 V ·μm-1 it was 110-150 ms. Observed phenomenon is the first mention of P3HT supramolecules associated with electrooptical effect. Proposed method provides real time control over the orientation of nanofibers, which is a starting point for a novel practical implementation. With further development P3HT nanofibers can be used individually as an anisotropic solution or as an active component in a guest-host system.
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| 6. |
- Lobov, Gleb S., et al.
(författare)
-
Electro-optical response of P3HT nanofibers in liquid solution
- 2015
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Ingår i: Asia Communications and Photonics Conference, ACPC 2015. - Washington, D.C. : OSA. - 9781943580064
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Konferensbidrag (refereegranskat)abstract
- AC electric poling introduces in P3HT nanofibers anisotropic electro-optical response and birefringence. Along with birefringence, such material exhibits strong amplitude modulation which makes it more efficient alternative to liquid crystals.
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| 7. |
- Lobov, Gleb S., et al.
(författare)
-
Electro-optical response of P3HT nanofibers in liquid solution
- 2015
-
Ingår i: Asia Communications and Photonics Conference 2015. - : Optical Society of America. - 9781943580064
-
Konferensbidrag (refereegranskat)abstract
- AC electric poling introduces in P3HT nanofibers anisotropic electro-optical response and birefringence. Along with birefringence, such material exhibits strong amplitude modulation which makes it more efficient alternative to liquid crystals.
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| 8. |
- Lobov, Gleb S., et al.
(författare)
-
Size Impact of Ordered P3HT Nanofibers on Optical Anisotropy
- 2016
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Ingår i: Macromolecular Chemistry and Physics. - : John Wiley & Sons. - 1022-1352 .- 1521-3935. ; 217:9, s. 1089-1095
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Tidskriftsartikel (refereegranskat)abstract
- Poly-3-hexylthiophene (P3HT) nanofibers are 1D crystalline structures with semiconductor properties. When P3HT nanofi bers are dispersed in nonconducting solvent, they react to external alternate electric field by aligning along the field lines. This can be used to create layers of ordered nanofi bers and is referred to as alternating current poling method. P3HT nanofi bers with three different size distributions are fabricated, using self-assembly mechanism in marginal solvents, and used for the alignment studies. Anisotropic absorption of oriented 2 mu m long nanofi bers exponentially increases with the magnitude of applied field to a certain asymptotic limit at 0.8 V mu m(-1), while 100-500 nm long nanofi bers respond to electric field negligibly. Effective optical birefringence of oriented 2 mu m long nanofi bers is calculated, based on the phase shift at 633 nm and the average layer thickness, to be 0.41. These results combined with further studies on real-time control over orientation of P3HT nanofi bers in liquid solution or host system are promising in terms of exploiting them in electroabsorptive and electrorefractive applications.
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| 9. |
- Naruse, M., et al.
(författare)
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Percolation of optical excitation mediated by near-field interactions
- 2017
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Ingår i: Physica A: Statistical Mechanics and its Applications. - : Elsevier. - 0378-4371. ; 471, s. 162-168
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Tidskriftsartikel (refereegranskat)abstract
- Optical excitation transfer in nanostructured matter has been intensively studied in various material systems for versatile applications. Herein, we theoretically and numerically discuss the percolation of optical excitations in randomly organized nanostructures caused by optical near-field interactions governed by Yukawa potential in a two-dimensional stochastic model. The model results demonstrate the appearance of two phases of percolation of optical excitation as a function of the localization degree of near-field interaction. Moreover, it indicates sublinear scaling with percolation distances when the light localization is strong. Furthermore, such a character is maximized at a particular size of environments. The results provide fundamental insights into optical excitation transfer and will facilitate the design and analysis of nanoscale signal-transfer characteristics.
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| 10. |
- Sun, Xu, 1987-, et al.
(författare)
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All-Optical Switching Using a Hybrid Plasmonic Donut Resonator With Photothermal Absorber
- 2016
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Ingår i: IEEE Photonics Technology Letters. - : Institute of Electrical and Electronics Engineers (IEEE). - 1041-1135 .- 1941-0174. ; 28:15, s. 1609-1612
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Tidskriftsartikel (refereegranskat)abstract
- A novel hybrid plasmonic (HP) donut resonator integrated with a photothermal plasmonic absorber has been developed, which can be used as a compact all-optical switch or modulator. The radius of the fabricated HP donut resonator is 1.8 mu m, with a resonant wavelength around 1550 nm and a quality factor (Q factor) around 600. The photothermal plasmonic absorber is directly integrated above the HP device, which can absorb as much as 75% of impinging optical power at 1064 nm wavelength. Since the absorber is in tight contact to the Si ridge of the HP waveguide, the absorbed optical power can efficiently heat up the Si ridge, and hence change the resonant wavelength of the HP donut resonator by Si thermal expansion effect. Experimental results show that the power used for 15 dB amplitude switch is only 10 mW, with rise and fall response times around 18 and 14 mu s, respectively.
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