| 1. |
- Huang, Liangliang, et al.
(författare)
-
Study on continuous cold-pressing technology of engineered wood flooring with EPI adhesive
- 2018
-
Ingår i: Wood research. - : Statny Drevarsky Vyskumny Ustav. - 1336-4561. ; 63:2, s. 335-342
-
Tidskriftsartikel (refereegranskat)abstract
- The effects of process parameters (adhesive spread, press time, and applied pressure) on the gluing performance of engineered wood flooring bonded with emulsion-polymer-isocyanate (EPI) adhesive were studied. The results showed (shear strength and aging test) that the major factors were adhesive spread and press time. The optimized parameters for best gluing performance of engineered wood flooring were 160 g.m-2, 14 s, and 60 s for adhesive spread, heat time, and press time, respectively, within certain ranges
|
|
| 2. |
- Yuan, Shuai, et al.
(författare)
-
[Ti8Zr2O12(COO)(16)] Cluster : An Ideal Inorganic Building Unit for Photoactive Metal-Organic Frameworks
- 2018
-
Ingår i: Acs Central Science. - : American Chemical Society (ACS). - 2374-7943 .- 2374-7951. ; 4:1, s. 105-111
-
Tidskriftsartikel (refereegranskat)abstract
- Metal-organic frameworks (MOFs) based on Ti-oxo clusters (Ti-MOFs) represent a naturally self-assembled superlattice of TiO2 nanoparticles separated by designable organic linkers as antenna chromophores, epitomizing a promising platform for solar energy conversion. However, despite the vast, diverse, and well-developed Ti-cluster chemistry, only a scarce number of Ti-MOFs have been documented. The synthetic conditions of most Ti-based clusters are incompatible with those required for MOF crystallization, which has severely limited the development of Ti-MOFs. This challenge has been met herein by the discovery of the [Ti8Zr2O12(COO)(16)] cluster as a nearly ideal building unit for photoactive MOFs. A family of isoreticular photoactive MOFs were assembled, and their orbital alignments were fine-tuned by rational functionalization of organic linkers under computational guidance. These MOFs demonstrate high porosity, excellent chemical stability, tunable photoresponse, and good activity toward photocatalytic hydrogen evolution reactions. The discovery of the [Ti8Zr2O12(COO)(16)] cluster and the facile construction of photoactive MOFs from this cluster shall pave the way for the development of future Ti-MOF-based photocatalysts. GRAPHICS
|
|
