| 1. |
- Xiong, Binyu, et al.
(författare)
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A flow-rate-aware data-driven model of vanadium redox flow battery based on gated recurrent unit neural network
- 2023
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Ingår i: Journal of Energy Storage. - 2352-152X. ; 74
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Tidskriftsartikel (refereegranskat)abstract
- The vanadium redox flow battery (VRB) system involves complex multi-physical and multi-timescale interactions, where the electrolyte flow rate plays a pivotal role in both static and dynamic performance. Traditionally, fixed flow rates have been employed for operational convenience. However, in today's highly dynamic energy market environment, adjusting flow rates based on operating conditions can provide significant advantages for improving VRB energy conversion efficiency and cost-effectiveness. Unfortunately, incorporating the electrolyte flow rate into conventional multi-physical models is overly complex for VRB management and control systems, as real-time operations demand low-computational and low-complexity models for onboard functionalities. This paper introduces a novel data-driven approach that integrates flow rates into VRB modeling, enhancing data processing capabilities and prediction accuracy of VRB behaviors. The proposed model adopts a gated recurrent unit (GRU) neural network as its fundamental framework, exhibiting exceptional proficiency in capturing VRB's nonlinear voltage segments. The GRU network structure is carefully designed to optimize the predictive ability of the model, with flow rate considered as a crucial input parameter to account for its influence on VRB behavior. Model refinement involves analyzing well-designed simulation results obtained during VRB operations under various flow rates. Laboratory experiments were also designed and conducted, covering different conditions of currents and flow rates to validate the proposed data-driven modeling method. Comparative analyses were performed against several state-of-the-art algorithms, including equivalent circuit models and other data-driven models, demonstrating the superiority of the proposed GRU-based VRB model considering flow rates. Thanks to the GRU's outstanding capability in processing time series data, the proposed model delivers impressively accurate terminal voltage predictions with a low error margin of no more than 0.023 V (1.3%) under wide operating ranges. These results indicate the efficacy and robustness of the proposed approach, highlighting the novelty and significance of accounting for flow rates in accurate VRB modeling for management and control system design.
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| 2. |
- Xiong, Binyu, et al.
(författare)
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Numerical analysis of vanadium redox flow batteries considering electrode deformation under various flow fields
- 2023
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Ingår i: Journal of Power Sources. - : Elsevier BV. - 0378-7753. ; 564
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Tidskriftsartikel (refereegranskat)abstract
- The porous electrode of vanadium redox flow batteries (VRBs) is subject to deformation due to mechanical stress during stack assembling. The forces compress the electrode fiber into the flow channel and thus alter the electrode porosity ratio. Due to the complex mechanisms, the effects of resulting electrode morphological changes on VRB performance were usually ignored in existing studies. This paper proposes a three-dimensional VRB model considering the uneven electrode deformation to investigate the cell performance under different electrode compression ratios with three flow-field designs. Compression ratio (CR) and the intrusive part of the electrode are obtained under various mechanical stress by adjusting gasket thickness in the experiment. The proposed electrochemical model is established based on the comprehensive description of conservation laws and analyzed using the COMSOL platform. Three indices, namely the concentration overpotential, pressure drop, and distribution uniformity, are selected for the analysis under the three flow field designs and different CRs. The numerical study reveal that the pressure drop and the concentration overpotential are sensitive to the CR but less affected by the concentration uniformity. The minimum overpotential can be reached when the CR is around 40%–50%, depending on flow field designs, while a higher CR can cause a drastically increased pressure drop. It is also found that the interdigitated flow field with a CR of 45% is considered optimal. The insights from the proposed method demonstrate the significance of considering the effects of electrode deformation in the stack design under various flow fields.
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| 3. |
- Xiong, Binyu, et al.
(författare)
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Peak Power Estimation of Vanadium Redox Flow Batteries Based on Receding Horizon Control
- 2023
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Ingår i: IEEE Journal of Emerging and Selected Topics in Power Electronics. - 2168-6777 .- 2168-6785. ; 11:1, s. 154-165
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Tidskriftsartikel (refereegranskat)abstract
- The peak power of a vanadium redox flow battery (VRB) reflects its capability to continuously absorb or release energy. Accurate estimation of peak power is essential for the safe, reliable, and efficient operation of VRB systems, but also challenging as it is limited by various factors, such as currents, flow rates, temperature, and state of charge. This article proposes a new online model-based peak power estimation scheme for VRBs. First, the model parameters and system states are accurately estimated using the recursive least squares with forgetting and the unscented Kalman filter, respectively. Next, based on a linear time-varying VRB model and the estimated states, the peak power estimation is formulated into an optimal control problem, and the problem is solved using the receding horizon control (RHC). The influence of the predictive horizon on the estimated peak power is discussed. Finally, the effectiveness of the proposed RHC-based peak power estimation scheme is experimentally verified on a 5-kW/3-kWh VRB platform.
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