| 1. |
- Huang, Zheng, et al.
(författare)
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Constructing type-II CuInSe2/CuInS2 core/shell quantum dots for high-performance photoelectrochemical cells
- 2024
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Ingår i: SCIENCE CHINA Materials. - 2095-8226. ; 67:1, s. 134-142
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Tidskriftsartikel (refereegranskat)abstract
- CuInSe2 (CISe) quantum dots (QDs) have shown promising applications in photoelectrochemical (PEC) cells due to their nontoxicity, high extinction coefficient, and wide optical absorption range; however, their low PEC performance prevents their applications due to insufficient charge carrier separation and severe charge recombination. Herein, CISe/CuInS2 (CISe/CIS) core/shell structured QDs are designed and constructed to promote charge separation and diminish interface defects. Afterward, the copper vacancy (VCu) state of CISe/CIS QDs is enriched by modulating the precursor molar ratios of In/Cu. Therefore, the radiative recombination of the conduction band edge electrons with the VCu localized holes becomes dominant and prolongs the carrier lifetime compared with intrinsic band-to-band recombination, thus promoting charge separation. Consequently, the VCu-rich CISe/CIS QD-based photoanode shows a high photocurrent density of 8.0 mA cm−2, which is one of the highest values reported for CISe QD-based PEC cells. This work provides an effective approach for promoting charge carrier separation and transfer through surface or intrinsic defect mediation for PEC applications of I–III–VI semiconductor nanocrystals.
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| 2. |
- Lin, Jianfeng, et al.
(författare)
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Experimental investigation and intelligent control of the magnus anti-rolling device for ship stability at zero speed
- 2024
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Ingår i: Ocean Engineering. - 0029-8018. ; 308
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Tidskriftsartikel (refereegranskat)abstract
- Under zero-speed conditions, ships are particularly susceptible to the effects of waves, which directly impact the safety of the vessel. A ship anti-rolling device based on the Magnus effect is designed to mitigate rolling motions across a full range of speeds, thereby enhancing the vessel's stability. This study presents an experimental investigation and intelligent control of Magnus anti-rolling devices aimed at enhancing ship stability at zero speed. The test setup, intelligent control algorithm, and experimental procedures specifically tailored for evaluating the Magnus anti-rolling device were designed. Following this, a comprehensive analysis was conducted to assess the effects of different cylinder geometries, swinging speeds, initial roll angles, and control methods on the anti-rolling characteristics of the device. Results demonstrate that the intelligent control method achieves an average anti-rolling efficiency of 89%. Additionally, the optimised geometric model of the Magnus anti-rolling device exhibits improved anti-rolling efficiency relative to the original model. The study confirms the stability and robustness of the intelligent Magnus anti-rolling device and suggests future research directions for practical applications aboard full-scale vessels in complex marine environments.
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