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- Gong, Haiqing, et al.
(författare)
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Synergies in sustainable phosphorus use and greenhouse gas emissions mitigation in China: : Perspectives from the entire supply chain from fertilizer production to agricultural use
- 2022
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Ingår i: Science of the Total Environment. - : Elsevier BV. - 0048-9697 .- 1879-1026. ; , s. 155997-155997
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Tidskriftsartikel (refereegranskat)abstract
- Synergies to achieve high phosphorus (P) use efficiency (PUE) and mitigate greenhouse gas (GHG) emissions are critical for developing strategies aimed toward agricultural green development. However, the potential effects of such synergies in the entire P supply chain through optimizing P management in crop production are poorly understood. In this study, a partial life cycle of a GHG emissions model was developed to quantify the P-related GHG emissions in the entire P supply chain in China. Our results showed that 16.3 kg CO2-equivalent (CO2-eq) was produced from the entire P supply chain per unit of P used for grain agriculture (maize, rice, and wheat). P-related GHG emissions in China increased more than five-fold from 1980 (7.2 Tg CO2-eq) to 2018 (44.9 Tg CO2-eq). GHG emissions were found to be strongly associated with the intensity of grain production in China, and they varied considerably across production regions owing to the differences in the P fertilizer production efficiency. Mineral P fertilizer use in crop production was the primary source of P-related GHG emissions. The results suggest that sustainable P management by matching mineral P fertilizer rates and fertilizer types with crop needs can mitigate GHG emissions by 10.8–27.7 Tg (24.0–65.1%). Moreover, this can improve PUE and reduce mineral P input by 0.7–1.4 Tg (24.0–46.0%). These findings highlight that potential synergies between high PUE and low P-related GHG emissions can be achieved via sustainable P management, thereby enhancing green agricultural development in China and other regions worldwide.
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| 2. |
- Zhang, Xiaoqiang, et al.
(författare)
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Thermal stress analysis at the interface of cathode and electrolyte in solid oxide fuel cells
- 2020
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Ingår i: International Communications in Heat and Mass Transfer. - : Elsevier BV. - 0735-1933. ; 118
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Tidskriftsartikel (refereegranskat)abstract
- A benign thermal stress in solid oxide fuel cell is of great importance for its stability and the interfaces between different components suffer from unexpected risks of instability such as electrode delamination and crack due to varying thermal expansion coefficients. Besides, chromium poisoning cathode materials leads to phase changes, which possibly induces thermal stresses at the interface of electrolyte and cathode. A three dimensional model at the microscale level is thus developed to unravel the effect of thermal stress on the interface. The model is constructed by governing equations including heat, species, momentum, ion and electronic transportation. The contact modes between the active cathode and electrolyte are studied to reveal the cell performance and thermal stresses, which are strongly related to the number of contact sites and the contact area. Moreover, chromium poisoning the contact causes the disordered distribution of thermal stresses with the increase of the contact sites, worsening the cell current density and durability. The resulting conclusions are expected to offer a solution to avoid possible fatal mechanical failure due to unfavorable interface design and chromium attack.
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