| 1. |
- Badr, Hussein O., et al.
(författare)
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Bottom-up, scalable synthesis of anatase nanofilament-based two-dimensional titanium carbo-oxide flakes
- 2022
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Ingår i: Materials Today. - : ELSEVIER SCI LTD. - 1369-7021 .- 1873-4103. ; 54
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Tidskriftsartikel (refereegranskat)abstract
- Two-dimensional (2D) materials offer advantages that their 3D counterparts do not. The conventional method for the bulk synthesis of 2D materials has predominantly been through etching layered solids. Herein, we convert - through a bottom-up approach - 10 binary and ternary titanium carbides, nitrides, borides, phosphides, and silicides into 2D flakes by immersing them in a tetramethylammonium hydroxide solution at temperatures in the 25-85 degrees C range. Based on X-ray diffraction, density functional theory, X-ray photoelectron, electron energy loss, Raman, X-ray absorption near edge structure spectroscopies, transmission and scanning electron microscope images and selected area diffraction, we conclude that the resulting flakes are carbon containing anatase-based layers that are, in turn, comprised of approximate to 6 x 10 angstrom(2) nanofilaments in cross-section some of which are few microns long. Electrodes made from some of these films performed well in lithium-ion and lithium-sulphur systems. These materials also reduce the viability of cancer cells thus showing potential in biomedical applications. Synthesizing 2D materials, at near ambient conditions, with non-layered, inexpensive, green precursors (e.g., TiC) is paradigm shifting and will undoubtedly open new and exciting avenues of research and applications.
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| 2. |
- Chen, Fangjun, et al.
(författare)
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Comprehensive kinetic modeling and product distribution for pyrolysis of pulp and paper mill sludge
- 2024
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Ingår i: Science of the Total Environment. - 0048-9697 .- 1879-1026. ; 924
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Tidskriftsartikel (refereegranskat)abstract
- Pyrolysis holds immense potential for clean treatment of pulp and paper mill sludge (PPMS), enabling efficient energy and chemical recovery. However, current understanding of PPMS pyrolysis kinetics and product characteristics remains incomplete. This study conducted detailed modeling of pyrolysis kinetics for two typical PPMSs from a wastepaper pulp and paper mill, namely, deinking sludge (PPMS-DS) and sewage sludge (PPMS-SS), and analyzed comprehensively pyrolysis products. The results show that apparent activation energy of PPMS-DS (169.25–226.82 kJ/mol) and PPMS-SS (189.29–411.21 kJ/mol) pyrolysis undergoes significant change, with numerous parallel reactions present. A distributed activation energy model with dual logistic distributions proves to be suitable for modeling thermal decomposition kinetics of both PPMS-DS and PPMS-SS, with coefficient of determination >0.999 and relative root mean square error <1.99 %. High temperature promotes decomposition of solid organic materials in PPMS, and maximum tar yield for both PPMS-DS (53.90 wt%, daf) and PPMS-SS (56.48 wt%, daf) is achieved at around 500 °C. Higher levels of styrene (24.45 % for PPMS-DS and 14.71 % for PPMS-SS) and ethylbenzene (8.61 % for PPMS-DS and 8.33 % for PPMS-SS) are detected in tar and could be used as chemicals. This work shows great potential to propel development of PPMS pyrolysis technology, enabling green and sustainable production in pulp and paper industry.
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| 3. |
- Ehlers, Todd A., et al.
(författare)
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Past, present, and future geo-biosphere interactions on the Tibetan Plateau and implications for permafrost
- 2022
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Ingår i: Earth-Science Reviews. - : Elsevier BV. - 0012-8252. ; 234
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Tidskriftsartikel (refereegranskat)abstract
- Interactions between the atmosphere, biosphere, cryosphere, hydrosphere, and geosphere are most active in the critical zone, a region extending from the tops of trees to the top of unweathered bedrock. Changes in one or more of these spheres can result in a cascade of changes throughout the system in ways that are often poorly understood. Here we investigate how past and present climate change have impacted permafrost, hydrology, and ecosystems on the Tibetan Plateau. We do this by compiling existing climate, hydrologic, cryosphere, biosphere, and geologic studies documenting change over decadal to glacial-interglacial timescales and longer. Our emphasis is on showing present-day trends in environmental change and how plateau ecosystems have largely flourished under warmer and wetter periods in the geologic past. We identify two future pathways that could lead to either a favorable greening or unfavorable degradation and desiccation of plateau ecosystems. Both paths are plausible given the available evidence. We contend that the key to which pathway future generations experience lies in what, if any, human intervention measures are implemented. We conclude with suggested management strategies that can be implemented to facilitate a future greening of the Tibetan Plateau.
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| 4. |
- Tian, Yu, et al.
(författare)
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Revealing morphology rules of MX precipitates in Ti-V-Nb multi-microalloyed steels
- 2022
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Ingår i: Materials Characterization. - : Elsevier BV. - 1044-5803 .- 1873-4189. ; 188
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Tidskriftsartikel (refereegranskat)abstract
- Despite a large number of studies relevant to MX (M = Ti, V, Nb; X = C, N) precipitation in microalloyed steels, the evolution rules of the precipitate morphology remain unclear. In this work, the precipitation behavior and morphological characteristics of MX precipitates in deformed Ti-V-Nb multi-microalloyed steels under contin-uous cooling were revealed through integrating transmission electron microscopy and theoretical models. The experimental results demonstrate that the precipitates are mainly Ti-rich cuboidal multi-component precipitates and irregular compound precipitates formed in austenite, and fine spherical V8C7 precipitates formed in ferrite. For the first time, the L parameter model that evaluates the shape of MX precipitates has been introduced into microalloyed steels, together with the validating experiments. In austenite, as the L increases, precipitates tend to become cuboidal under equilibrium conditions while rod-like elongating along their (100) orientation under deformation conditions; in ferrite, as the L increases, precipitates tend to be disk-like under equilibrium con-ditions while thin elliptical cylindrical extending along their (110) orientation on the habit plane under defor-mation conditions. The evolution rules of precipitate morphology revealed in this work provide insights in controlling precipitates morphology to develop high-performance microalloyed steels.
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| 5. |
- Wang, Yu, et al.
(författare)
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FlexZNS : Building High-Performance ZNS SSDs with Size-Flexible and Parity-Protected Zones
- 2023
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Ingår i: Proceedings - 2023 IEEE 41st International Conference on Computer Design, ICCD 2023. - : Institute of Electrical and Electronics Engineers (IEEE). ; , s. 291-299
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Konferensbidrag (refereegranskat)abstract
- NVMe zoned namespace (ZNS) SSDs present a new class of storage devices with attractive features including low cost, software definability, and stable performance. However, one primary culprit that hinders the adoption of ZNS is the high garbage collection (GC) overhead it brings to host software. The ZNS interface divides the logical address space into size-fixed zones that must be written sequentially. Despite being friendly to flash memory, ZNS requires host software to perform out-of-place updates and GC on individual zones. Current ZNS SSDs typically employ a large zone size (e.g., of GBs) to be conducive to die-level RAID protection on flash memory. This impedes flexible data placement, such as mixing data with different lifetimes in the same zone, and incurs sizable data migrations during zone GC. To address this problem, we propose FlexZNS, a novel ZNS SSD design that provides reliable zoned storage allowing host software to configure the zone size flexibly as well as multiple zone sizes. The size variability of zones poses two interrelated challenges, one for the SSD controller to establish per-zone RAID protection, and the other for host software to manage variable zone capacity loss caused by parity storage. To tackle the challenges, FlexZNS decouples the storage of parity from individual zones on flash memory and hides the zone capacity loss from the host software. We verify FlexZNS on a ZNS-compatible file system F2FS and a popular key-value store RocksDB. Extensive experiments demonstrate that FlexZNS can significantly improve the system performance and reduce GC-induced write amplification, compared with a conventional ZNS SSD with large-sized zones.
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| 6. |
- Woo, Jong Hun, et al.
(författare)
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Assessment Framework of Smart Shipyard Maturity Level via Data Envelopment Analysis
- 2021
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Ingår i: Sustainability. - : MDPI AG. - 2071-1050. ; 13:4
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Tidskriftsartikel (refereegranskat)abstract
- The fourth industrial revolution ("Industry 4.0") has caused an escalating need for smart technologies in manufacturing industries. Companies are examining various cutting-edge technologies to realize smart manufacturing and construct smart factories and are devoting efforts to improve their maturity level. However, productivity improvement is rarely achieved because of the large variety of new technologies and their wide range of applications; thus, elaborately setting improvement goals and plans are seldom accomplished. Fortunately, many researchers have presented guidelines for diagnosing the smartness maturity level and systematic directions to improve it, for the eventual improvement of productivity. However, most research has focused on mass production industries wherein the overall smartness maturity level is already high (e.g., high-level automation). These studies thus have limited applicability to the shipbuilding industry, which is basically a built-to-order industry. In this study, through a technical demand survey of the shipbuilding industry and an investigation of existing smart manufacturing and smart factories, the keywords of connectivity, automation, and intelligence were derived and based on these keywords, we developed a new diagnostic framework for smart shipyard maturity level assessment. The framework was applied to eight shipyards in South Korea to diagnose their smartness maturity level, and a data envelopment analysis (DEA) was performed to confirm the usefulness of the diagnosis results. By comparing the DEA models, the results with the smart level as an input represents the actual efficiency of shipyards better than the results of conventional models.
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| 7. |
- Zhou, Yongqiang, et al.
(författare)
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Rainstorm events shift the molecular composition and export of dissolved organic matter in a large drinking water reservoir in China : High frequency buoys and field observations
- 2020
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Ingår i: Water Research. - : Elsevier BV. - 0043-1354 .- 1879-2448. ; 187
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Tidskriftsartikel (refereegranskat)abstract
- Rainstorm events can flush large amounts of terrestrial organic-rich material into lakes that are used for drinking water. To date, few studies have been carried out to investigate how rainstorm events change the molecular composition, bio-lability, and flux of upstream-imported dissolved organic matter (DOM), which can impact the odor and taste of drinking water as well as the efficiency of wastewater treatment. We undertook high-frequency buoy monitoring and point sample collection (n = 495), during high, moderate, and low inflow discharge, in Lake Qiandao, a key drinking water source for about 10 million people. Data from two online fluorescent DOM sensors deployed and field samples collected at the river site, Jiekou, and the lake site, Xiaojinshan, showed that rainstorm events increased the specific UV absorbance (SUVA254), humification index (HIX), humic-like components (C1-C2), and FT-ICR MS derived condensed aromatic and polyphenolic compounds (p < 0.001) and decreased the spectral slope of DOM (S275–295), spectral slope ratio (SR), biological index (BIX), and highly bio-degradable peptide-like and aliphatic substances (p < 0.001). Our results suggest that rainstorm events enhanced the export to the lake of colored, hydrophobic, and aromatic DOM. Upstream-derived dissolved organic carbon (DOC) concentrations decreased (p < 0.001), while DOC bio-availability (BDOC) increased only slightly (p < 0.05) during rainstorm events. The loss rate of DOC in Lake Qiandao is 0.82 × 104 t C yr−1, of which 0.30 × 104 t C yr−1 is highly bio-labile, and higher occurrences of both ≥ 25 mm d − 1 and ≥ 50 mm d − 1 rainfall events are anticipated by linear fittings for this region in the future. The application of in situ fluorescence sensors provides an early warning of DOC surge incidents caused by rainstorm events and may be useful in advising drinking water treatment plant managers of changes in raw water DOM quality and treatability.
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| 8. |
- Zhu, Jie, 1990, et al.
(författare)
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Bi-level ramp merging coordination for dense mixed traffic conditions
- 2024
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Ingår i: Fundamental Research. - 2096-9457 .- 2667-3258. ; In Press
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Tidskriftsartikel (refereegranskat)abstract
- Connected and Autonomous Vehicles (CAVs) hold great potential to improve traffic efficiency, emissions and safety in freeway on-ramp bottlenecks through coordination between mainstream and on-ramp vehicles. This study proposes a bi-level coordination strategy for freeway on-ramp merging of mixed traffic consisting of CAVs and human-driven vehicles (HDVs) to optimize the overall traffic efficiency and safety in congested traffic scenarios at the traffic flow level instead of platoon levels. The macro level employs an optimization model based on fundamental diagrams and shock wave theories to make optimal coordination decisions, including optimal minimum merging platoon size to trigger merging coordination and optimal coordination speed, based on macroscopic traffic state in mainline and ramp (i.e., traffic volume and penetration rates of CAVs). Furthermore, the micro level determines the real platoon size in each merging cycle as per random arrival patterns and designs the coordinated trajectories of the mainline facilitating vehicle and ramp platoon. A receding horizon scheme is implemented to accommodate human drivers’ stochastics as well. The developed bi-level strategy is tested in terms of improving efficiency and safety in a simulation-based case study under various traffic volumes and CAV penetration rates. The results show the proposed coordination addresses the uncertainties in mixed traffic as expected and substantially improves ramp merging operation in terms of merging efficiency and traffic robustness, and reducing collision risk and emissions, especially under high traffic volume conditions.
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| 9. |
- Zhu, Jie, et al.
(författare)
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Highly secretory expression of recombinant cowpea chlorotic mottle virus capsid proteins in Pichia pastoris and in-vitro encapsulation of ruthenium nanoparticles for catalysis
- 2020
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Ingår i: Protein Expression and Purification. - : Elsevier BV. - 1046-5928 .- 1096-0279. ; 174
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Tidskriftsartikel (refereegranskat)abstract
- The applications of viral protein cages have expanded rapidly into the fields of bionanotechnology and materials science. However, the low-cost production of viral capsid proteins (CPs) on a large scale is always a challenge. Herein, we develop a highly efficient expression system by constructing recombinant Pichia pastoris cells as a “factory” for the secretion of soluble cowpea chlorotic mottle virus (CCMV) CPs. Under optimal induction conditions (0.9 mg/mL of methanol concentration at 30 °C for 96 h), a high yield of approximately 95 mg/L of CCMV CPs was harvested from the fermentation supernatant with CPs purity >90%, which has significantly simplified the rest of the purification process. The resultant CPs are employed to encapsulate Ruthenium (Ru) nanoparticles (NPs) via in-vitro self-assembly to prepare hybrid nanocatalyst, i.e. Ru@virus-like particles (VLPs). The catalytic activity over Ru@VLPs was evaluated by reducing 4-nitrophenol (4-NP) to 4-aminophenol (4-AP). The results indicate that, with the protection of protein cages, Ru NPs were highly stabilized during the catalytic reaction. This results in enhanced catalytic activity (reaction rate constant k = 0.14 min−1) in comparison with unsupported citrate-stabilized Ru NPs (Ru-CA) (k = 0.08 min−1). Additionally, comparatively lower activation energy over Ru@VLPs (approximately 32 kJ/mol) than that over Ru-CA (approximately 39 kJ/mol) could be attributed to the synergistic effect between Ru NPs and some functional groups such as amino groups (–NH2) on CPs that weakened the activation barrier of 4-NP reduction. Therefore, enhanced activity and decreased activation energy over Ru@VLPs demonstrated the superiority of Ru@VLPs to unsupported Ru-CA.
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| 10. |
- Zhu, Jie, 1990, et al.
(författare)
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Merging control strategies of connected and autonomous vehicles at freeway on-ramps: a comprehensive review
- 2022
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Ingår i: Journal of Intelligent and Connected Vehicles. - 2399-9802. ; 5:2, s. 99-111
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Forskningsöversikt (refereegranskat)abstract
- Purpose – On-ramp merging areas are typical bottlenecks in the freeway network since merging on-ramp vehicles may cause intensive disturbances on the mainline traffic flow and lead to various negative impacts on traffic efficiency and safety. The connected and autonomous vehicles (CAVs), with their capabilities of real-time communication and precise motion control, hold a great potential to facilitate ramp merging operation through enhanced coordination strategies. This paper aims to present a comprehensive review of the existing ramp merging strategies leveraging CAVs, focusing on the latest trends and developments in the research field. Design/methodology/approach – The review comprehensively covers 44 papers recently published in leading transportation journals. Based on the application context, control strategies are categorized into three categories: merging into sing-lane freeways with total CAVs, merging into singlane freeways with mixed traffic flows and merging into multilane freeways. Findings – Relevant literature is reviewed regarding the required technologies, control decision level, applied methods and impacts on traffic performance. More importantly, the authors identify the existing research gaps and provide insightful discussions on the potential and promising directions for future research based on the review, which facilitates further advancement in this research topic. Originality/value – Many strategies based on the communication and automation capabilities of CAVs have been developed over the past decades, devoted to facilitating the merging/lane-changing maneuvers at freeway on-ramps. Despite the significant progress made, an up-to-date review covering these latest developments is missing to the authors’ best knowledge. This paper conducts a thorough review of the cooperation/ coordination strategies that facilitate freeway on-ramp merging using CAVs, focusing on the latest developments in this field. Based on the review, the authors identify the existing research gaps in CAV ramp merging and discuss the potential and promising future research directions to address the gaps.
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