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Synthesis of a Ru(b...
Synthesis of a Ru(bpy)(3)-type complex linked to a free terpyridine ligand and its use for preparation of polynuclear bimetallic complexes
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Wolpher, H. (författare)
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- Huang, Ping (författare)
- Lund University,Lunds universitet,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Borgstrom, M. (författare)
- Uppsala universitet,Fysikalisk-kemiska institutionen
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- Bergquist, Jonas (författare)
- Uppsala universitet,Kemiska institutionen,Analytisk kemi,Avdelningen för analytisk kemi
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- Styring, Stenbjörn (författare)
- Lund University,Lunds universitet,Biokemi och Strukturbiologi,Centrum för Molekylär Proteinvetenskap,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Biochemistry and Structural Biology,Center for Molecular Protein Science,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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Sun, Licheng C. (författare)
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Akermark, B. (författare)
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(creator_code:org_t)
- Elsevier BV, 2004
- 2004
- Engelska.
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Ingår i: Catalysis Today. - : Elsevier BV. - 0920-5861 .- 1873-4308. ; 98:4, s. 529-536:98, s. 529-536
- Relaterad länk:
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http://dx.doi.org/10...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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https://urn.kb.se/re...
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https://lup.lub.lu.s...
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Abstract
Ämnesord
Stäng
- A terpyridine ligand has been covalently linked to a Ru(bpy)(3) complex via an amide bond. By using this functionalized terpyridine ligand, a series of multinuclear bimetallic complexes have been synthesized and characterized. One of these complexes has the structure of di-mu-oxobridged Mn dimer. EPR spectra of this complex showed that, depending on the procedure for the preparation, the oxidation states of the Mn dimer is either a Mn-2(III,IV) dimer or a mixture of this and Mn-2(IV,IV) dimer. Water oxidation catalyzed by this complex has been performed.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- water oxidation
- artificial photosynthesis
- photosystem II
- ruthenium-manganese
- electrochemistry
- EPR
- homogeneous catalysis
- mononuclear manganese(iv) complexes
- intramolecular electron-transfer
- mixed-valence interactions
- water oxidation
- paramagnetic resonance
- oxygen evolution
- photosystem-ii
- artificial photosynthesis
- epr spectroscopy
- frozen solutions
- NATURAL SCIENCES
- electrochemistry
- ruthenium-manganese
- photosystem II
- water oxidation
- artificial photosynthesis
- EPR
- homogeneous catalysis
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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