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On the dissolution ...
On the dissolution state of cellulose in cold alkali solutions
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- Hagman, Joel (författare)
- Lund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Gentile, Luigi (författare)
- Lund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Jessen, Christian Moestrup (författare)
- Lund University
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- Behrens, Manja (författare)
- Lund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Bergquist, Karl-Erik (författare)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Olsson, Ulf (författare)
- Lund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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(creator_code:org_t)
- 2017-03-30
- 2017
- Engelska 13 s.
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Ingår i: Cellulose. - : Springer Science and Business Media LLC. - 0969-0239 .- 1572-882X. ; , s. 2003-2015
- Relaterad länk:
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http://dx.doi.org/10... (free)
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https://link.springe...
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https://lup.lub.lu.s...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- We have characterized the dissolved state of microcrystalline cellulose (MCC) in cold alkali [2.0 M NaOH(aq)] solutions using a combination of small angle X-ray (SAXS) and static light scattering (SLS), (Formula presented.)H NMR, NMR self-diffusion, and rheology experiments. NMR and SAXS data demonstrate that the cellulose is fully molecularly dissolved. SLS, however, shows the presence of large concentration fluctuations in the solution, consistent with significant attractive cellulose-cellulose interactions. The scattering data are consistent with fractal cellulose aggregates of micrometre size having a mass fractal dimension (Formula presented.). At 25(Formula presented.) the solution structure remains unchanged on the time scale of weeks. However, upon heating the solutions above 35(Formula presented.) additional aggregation occurs on the time scale of minutes. Decreasing or increasing the NaOH concentration away from the “optimum” 2 M also leads to additional aggregation. This is seen as an increase of the SAXS intensity at lower q values. Addition of urea (1.8 and 3.6 M, respectively) does not significantly influence the solution structure. With these examples, we will discuss how scattering methods can be used to assess the quality of solvents for cellulose.
Ämnesord
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
Nyckelord
- Aggregation
- Co-solvent
- Cold alkali (NaOH)
- Microcrystalline cellulose (MCC)
- NMR
- Rheology
- Small angle X-ray scattering (SAXS)
- Static light scattering (SLS)
- Temperature dependence
- Urea
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
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