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Exfoliation of Grap...
Exfoliation of Graphite into Graphene in Aqueous Solutions of Inorganic Salts
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- Parvez, Khaled (author)
- Max Planck Institute Polymer Research, Germany
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- Wu, Zhong-Shuai (author)
- Max Planck Institute Polymer Research, Germany
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- Li, Rongjin (author)
- Max Planck Institute Polymer Research, Germany
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- Liu, Xianjie (author)
- Linköpings universitet,Ytors Fysik och Kemi,Tekniska högskolan
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- Graf, Robert (author)
- Max Planck Institute Polymer Research, Germany
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- Feng, Xinliang (author)
- Max Planck Institute Polymer Research, Germany Shanghai Jiao Tong University, Peoples R China
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- Muellen, Klaus (author)
- Max Planck Institute Polymer Research, Germany
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(creator_code:org_t)
- 2014-04-09
- 2014
- English.
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In: Journal of the American Chemical Society. - : American Chemical Society. - 0002-7863 .- 1520-5126. ; 136:16, s. 6083-6091
- Related links:
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https://pure.mpg.de/...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
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- Mass production of high-quality graphene sheets is essential for their practical application in electronics, optoelectronics, composite materials, and energy-storage devices. Here we report a prompt electrochemical exfoliation of graphene sheets into aqueous solutions of different inorganic salts ((NH4)(2)SO4, Na2SO4, K2SO4, etc.). Exfoliation in these electrolytes leads to graphene with a high yield (greater than85%, less than= 3 layers), large lateral size (up to 44 mu m), low oxidation degree (a C/O ratio of 17.2), and a remarkable hole mobility of 310 cm(2) V-1 s(-1). Further, highly conductive graphene films (11 Omega sq(-1)) are readily fabricated on an A4-size paper by applying brush painting of a concentrated graphene ink (10 mg mL(-1), in N,N-dimethylformamide). All-solid-state flexible supercapacitors manufactured on the basis of such graphene films deliver a high area capacitance of 11.3 mF cm(-2) and an excellent rate capability of 5000 mV s(-1). The described electrochemical exfoliation shows great promise for the industrial-scale synthesis of high-quality graphene for numerous advanced applications.
Keyword
- TECHNOLOGY
- TEKNIKVETENSKAP
Publication and Content Type
- ref (subject category)
- art (subject category)
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