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Thermodynamics of t...
Thermodynamics of the hydration of non-polar substances
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Mancera, RL (författare)
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- Kronberg, B (författare)
- RISE,YKI – Ytkemiska institutet
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Costas, M (författare)
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visa fler...
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Silveston, R (författare)
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visa färre...
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(creator_code:org_t)
- 1998
- 1998
- Engelska.
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Ingår i: Biophysical Chemistry. - 0301-4622 .- 1873-4200. ; 70, s. 57-63
- Relaterad länk:
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https://urn.kb.se/re...
Abstract
Ämnesord
Stäng
- We re-examine the numerical value and physical significance of TS , the temperature where the entropy of transfer Δ WLCP fitting function. It is concluded that the interpretation of TS as the temperature where hydration ceases cannot be sustained. As previously reported [R.L. Baldwin, N. Muller, Proc. Natl. Acad. Sci. USA, 89 (1992) 7110], hydration must vanish at a temperature T1 >TS, where its experimental manifestation, i.e., ΔWL CP, is zero. We discuss the concept of water relaxation around a non-polar solute molecule and its relation to the hydration process.
Nyckelord
- Hydrophobic effect
- Aqueous solutions
- Protein folding.
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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