| 421. |
- Aas, Gro Hanne
(författare)
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Kvinneforskningspolitiske (pr)øvelser
- 1999
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Licentiatavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Målsettingen for licentiatuppsatsen er å analysere nordisk kvinneforsknings formuleringer av forskningspolitiske felter, problemstillinger og utfordringer, og gjennom kontakt og diskusjon bidra til samarbeid, diskusjoner og offentlighet om forskingspolitikk i kvinneforskning. Arbeidet har tatt utgangspunkt i relativt nytt materiale fra Danmark, Norge og Sverige. I kap. 1 presenteres prosjektet, problemstillinger og materiale. Kapitlene 2-6 består av innledninger og artikler holdt eller skrevet i løpet av de to senaste åren. Diskusjoner om kjønn og akademia står i fokus i kap. 2 - "Universities have politics". I kap. 3, artikkelen "Gamle og nye drømmer", diskuteres et kvinneforskningspolitiske intervensjonsprosjekt som blev utført for en del år tilbake, og det antydes noen nye omdreiningspunkter for et slikt arbeid. Enkelte perspektiver utdypes i kap. 4, "Kvinneforskningens samfunnskontrakt", hvor termen "kvinneperspektiv" som forskningspolitisk term granskas krtitiskt. De to siste kapitlene tar utgangspunkt i den norske forskningsmeldingen som kom våren 1999. Ut fra tre lesestrategier forsøkes det leses muligheter for kvinneforskningspolitiske strategier. Det ses også på innholdet i regjeringens forskningspolitiske verdidebatt, og det diskuteres mulige intervensjoner i denne ut fra feministiske vitenskaps- og teknologistudier.
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| 422. |
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| 423. |
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| 424. |
- Aas, Wenche
(författare)
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Constitution, dynamics and structure of binary and ternary actinide complexes
- 1999
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Stoichiometry, ligand exchange reactions, coordinationgeometry and stability of complexes of type UO2LpFq(H2O)3-n(p= 1–2,q= 1-3), where L is one of the bidentate ligandspicolinate, oxalate, carbonate or acetate have beeninvestigated using single crystal X-ray diffraction, an arrayof19F-,13C-,17O- and1H-NMR techniques and potentiometric titration usingboth F-and H+selective electrodes. The experiments wereperformed in a 1.00 M NaClO4medium. The equilibrium constants were determinedat 25°C while most of the kinetic experiments were done at- 5°C. The equilibrium constants for the stepwise additionof F-to UO2L and UO2L2indicates that the prior coordination of L toU(VI) has a fairly small effect on the subsequent bonding offluoride, except for a statistical effect determined by thenumber of available coordination sites. This indicates thatternary complexes might be important for the speciation andtransport of hexavalent actinides in ground and surface watersystems. A single crystal structure of UO2(picolinate)F32-has been determined showing the same pentagonalbipyramidal symmetry as in aqueous solution studied by NMR. Theexchangeable donor atoms are situated in a plane perpendicularto the linear uranyl group. The complexes show a variety ofdifferent exchange reactions depending on the ligand used. Ithas been possible to quantify external fluoride and the otherligands exchange reactions as well asintra-molecular reactions. This type of detailedinformation has not been observed in aqueous solution before.Water takes a critical part in the exchange mechanism, and whenit is eliminated from the inner coordination sphere a muchslower kinetics can be observed.19F-NMR has showed to be a powerful technique tostudy these reactions, both because of the sensitivity of thisNMR nucleus and also the possibility to observe reactions wherefluoride is not directly involved in the mechanism. TernaryTh(edta)F1-2and (UO2)2(edta)2F1-4have been investigated using1H and19F-NMR. The fluoride complexation to Cm(III) wasstudied using time resolved fluorescence spectroscopy (TRLFS)and the stability constant for the CmF2+complex was determined at 25°C in 1.0 mNaCl.Keywords. Ternary complexes, actinides,dioxouranium(VI), curium(III), thorium(IV), ligand exchange,isomers, NMR, potentiometric titrations, aqueous solution,oxalate, picolinate, acetate, EDTA.
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| 425. |
- Aas, Wenche, et al.
(författare)
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Equilibria and dynamics in binary and ternary uranyl oxalate and acetate/fluoride complexes
- 1999
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Ingår i: Journal of the Chemical Society - Dalton Transactions. - : Royal Society of Chemistry (RSC). - 0300-9246 .- 1364-5447. ; :8, s. 1311-1317
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Tidskriftsartikel (refereegranskat)abstract
- The formation of ternary UO2(ac)pFq2-p-q (p = 1 or 2 and q = 1-3) complexes, and their equilibrium constants were investigated by potentiometric titrations and 19F NMR spectroscopy. The equilibrium constants have been determined from the emf data in a NaClO4 medium at constant sodium concentration, [Na+] = 1.00 M at 25°C, except for the UO2(ac)F32- complex where 19F NMR at -5°C was used. The magnitude of the equilibrium constant for the stepwise addition of fluoride indicates that prior co-ordination of acetate has only a small effect on the subsequent bonding of fluoride. The acetate exchange in the ternary UO2(ac)F32- complex was studied using 19F NMR. Through magnetisation transfer experiments, it was possible to confirm the provisional mechanism from a previous study and also the consistency of the rate constants for the five different exchange pathways required to describe the fluoride exchange. The exchange takes place via the intermediate UO2F3(H2O)2-, indicating that the acetate exchange follows an interchange mechanism with solvent participation in the transition state. The rates and mechanisms of the ligand exchange reactions in UO2(ox)2(H2O)2- and UO2(ac)2(H2O) have been studied using 13C NMR techniques at -5°C. The rate law is v = k-[complex][ligand], and the second order rate constant and the activation parameters for both systems have been determined. The reactions most likely take place through an Eigen-Wilkins type of mechanism, where the first step is a pre-equilibrium of an outer-sphere complex followed by a rate determining exchange of water. The rate constants for the water exchange reactions are very similar to that in UO2(H2O)52+. The information from the binary oxalate system rules out the formation of UO2(ox)2(H2O)2- as an intermediate in the exchange reactions in the previously studied UO2(ox)2F3-, also in this case confirming a previously suggested exchange mechanism. The H+/D+ isotope effects and a linear free energy relationship suggest that the main catalytic effect of H+ on ligand exchange rates is due to the formation of a protonated precursor. Hence, the catalytic effect depends on the basicity of the ligand and the site for the proton attack.
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| 426. |
- Aasa, Anna, et al.
(författare)
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Collecting dialect data and making use of them an interim report from Swedia 2000
- 2000
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Ingår i: Proceedings FONETIK 2000. ; , s. 17-20
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- This paper consists of two, somewhat disparate parts. In the first part, some experiences of two years of fieldwork are summarized, concentrating, as the subtitle suggests, on the very heart of phonetic fieldwork: the encounters and interviews with the informants. As a result of the fieldwork, the project now has access to recordings from approximately 1300 speakers of more than 100 dialects of Swedish. We are currently initiating research on various aspects of the sound patterns of these dialects. The second part of the paper is meant to give an overview of some of our research plans for the near future.
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| 427. |
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| 428. |
- Aasa, Annika, 1963
(författare)
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User Defined Syntax
- 1992
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- This thesis describes two examples of user defined syntax. The first, and most thoroughly investigated, is a new datatype construction, the conctype, the elements of which have a very flexible syntax. An embedded language can easily be introduced into a programming language using conctypes and computations are easily expressed using the concrete syntax and a special pattern matching form. The second example is user defined distfix operators which give a user possibility to extend the syntax for expressions in a programming language. We describe both a user's view and the implementation of these two examples. In both cases, context-free grammars serve as a basis for the definition of the new syntax. A problem that is investigated is how to disambiguate grammars with precedences. To see how this should be done we investigate which language a grammar together with precedence rules defines. For a sub-class of context-free grammars we give a predicate that defines the precedence correct syntax trees according to some precedence rules. We also give an algorithm that transforms such a grammar to an ordinary unambiguous context-free grammar and prove the correctness of the algorithm. We use the algorithm in our implementation of distfix operators. For more general grammars, we isolate one kind of ambiguity which is suitable to resolve with precedence rules. We define the generated language for such a grammar by an attribute grammar. This approach of resolving ambiguity is used in the implementation of conctypes.
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| 429. |
- Aasa, Anna, et al.
(författare)
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Vowel quantity in West Swedish - the villain of the piece?
- 2000
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Ingår i: Proceedings of the Swedish Phonetics Conference FONETIK 2000.. ; , s. 17-20
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- This paper consists of two, somewhat disparate parts. In the first part, some experiences of two years of fieldwork are summarized, concentrating, as the subtitle suggests, on the very heart of phonetic fieldwork: the encounters and interviews with the informants. As a result of the fieldwork, the project now has access to recordings from approximately 1300 speakers of more than 100 dialects of Swedish. We are currently initiating research on various aspects of the sound patterns of these dialects. The second part of the paper is meant to give an overview of some of our research plans for the near future.
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| 430. |
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