| 41. |
- Wiesmaier, S., et al.
(author)
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Bimodality of lavas in the teide-pico viejo succession in tenerife-the role of crustal melting in the origin of recent phonolites
- 2012
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In: Journal of Petrology. - : Oxford University Press (OUP). - 0022-3530 .- 1460-2415. ; 53:12, s. 2465-2495
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Journal article (peer-reviewed)abstract
- In Tenerife, lavas of the recent Teide-Pico Viejo central complex show a marked bimodality in composition from initially mafic lavas (200-30 ka) to highly differentiated phonolites (30-0 ka). After this abrupt change, the bimodality of the lavas continued to manifest itself between the now felsic Teide-Pico Viejo central complex and the adjacent, but exclusively mafic, rift zones. Whole-rock trace element fingerprinting distinguishes three compositional groups (mafic, transitional, felsic). Groundmass Sr-Nd-Pb-O and feldspar δ. 18O data demonstrate open-system behaviour for the petrogenesis of the Teide-Pico Viejo felsic lavas by high. 87Sr/. 86Sr ratios of up to 0·7049, uniform. 206Pb/. 204Pb (19·75-19·78), variable. 207Pb/. 204Pb (15·53-15·62) and heterogeneous δ. 18O values (5·43-6·80‰). However, ocean sediment contamination can be excluded because of the low. 206Pb/. 204Pb ratios of North Atlantic sediments. Isotope mixing hyperbolae reproduce the entire Teide-Pico Viejo succession and require an assimilant of predominantly felsic composition. Unsystematic and heterogeneous variation of δ. 18O in fresh and unaltered feldspars across the Teide-Pico Viejo succession indicates magmatic addition of diverse δ. 18O assimilants, altered near surface at high and low temperatures. The best fit for these requirements is provided by nepheline syenite that occurs as fresh or altered lithic blocks in voluminous pre-Teide ignimbrite deposits and is similarly heterogeneous in oxygen isotope composition. Nepheline syenite blocks are considered to represent deep remnants of associated earlier eruptions and were thus available for assimilation at depth. Rare earth element modelling indicates that nepheline syenite needs to be melted in bulk to form a suitable end-member composition. Using this assimilant, energy-constrained assimilation fractional crystallization (EC-AFC) modelling reproduces the bulk of the succession, which leads us to suggest that Teide-Pico Viejo petrogenesis is governed by assimilation and fractional crystallization. Both mixing hyperbolae and EC-AFC models indicate that assimilation is more pronounced for the more felsic lavas. The maximum assimilation is evident in the most strongly differentiated (and the most radiogenic in Sr) lava and computes to >97·8% of the assimilant. This most evolved eruption probably represents nepheline syenite bulk melts that formed spatially decoupled from juvenile material. This study therefore recognizes a wider variability of magmatic differentiation processes at Teide-Pico Viejo than previously thought.
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| 42. |
- Wiesmaier, Sebastian, et al.
(author)
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Magmatic Differentiation in the Teide–Pico Viejo Succession : Isotope Analysis as a Key to Deciphering the Origin of Phonolite Magma
- 2013
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In: Teide Volcano. - Berlin, Heidelberg : Springer Berlin/Heidelberg. - 9783642258923 - 9783642258930 ; , s. 173-190
-
Book chapter (peer-reviewed)abstract
- In Tenerife, lavas of the recent Teide–Pico Viejo central complex show a marked bimodality in composition from initially mafic lava (200–30 ka) to highly differentiated phonolite (30–0 ka). Groundmass Sr–Nd–Pb–O and feldspar 18O data demonstrate open system behaviour for the petrogenesis of Teide–Pico Viejo felsic lavas, but contamination by ocean sediment can be excluded due to the low 206Pb/204Pb ratios of North Atlantic sediment. Isotope mixing hyperbolae require an assimilant of predominantly felsic composition for the Teide–Pico Viejo succession. Unsystematic and heterogeneous variation of 18O in fresh and unaltered feldspars across the Teide–Pico Viejo succession indicates magmatic addition of diverse 18O assimilants, best matched by nepheline syenites that occur as fresh and altered lithic blocks in voluminous pre-Teide ignimbrite deposits. Rare earth element modelling indicates that nepheline syenite needs to be melted in bulk to form a suitable end-member composition. Energy-Constrained Assimilation Fractional Crystallisation (EC-AFC) modelling reproduces the bulk of the succession, which implies that the petrogenesis of Teide–Pico Viejo lavas is governed by the coupled assimilation of nepheline syenite during fractional crystallisation. The most differentiated (and most radiogenic) lava computes to >97.8 % assimilant, likely represented by a nepheline syenite bulk melt that formed by underplating with juvenile mafic material. These recent research developments therefore recognise a wider variability of magmatic differentiation processes at Teide–Pico Viejo than previously considered.
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| 43. |
- Wolff, Johannes M., et al.
(author)
-
Is intermittent androgen-deprivation therapy beneficial for patients with advanced prostate cancer?
- 2014
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In: BJU International. - : Wiley. - 1464-4096. ; 114:4, s. 476-483
-
Research review (peer-reviewed)abstract
- Use of intermittent androgen-deprivation therapy (IADT) in patients with prostate cancer has been evaluated in several studies, in an attempt to delay the development of castration resistance and reduce side-effects associated with ADT. However it is still not clear whether survival is adversely affected in patients treated with IADT. In this review, we explore the available data in an attempt to identify the most suitable candidate patients for IADT, and discuss factors that may inform appropriate patient stratification. ADT is first-line treatment for advanced/metastatic prostate cancer and is also recommended for use with definitive radiotherapy for high-risk localised prostate cancer. The changes in hormone levels induced by ADT can lead to short-and long-term side-effects which, although treatable in most cases, can significantly reduce the tolerability of ADT treatment. IADT has been investigated in several phase II and phase III studies in patients with locally advanced or metastatic prostate cancer, in an attempt to delay time to tumour progression and reduce the side-effect burden of ADT. In selected patient groups IADT is no less effective than continuous ADT, ameliorating the impact of ADT-related side-effects, and, to a degree, their impact on patient health-related quality of life (HRQL). Further comparative study is required, particularly in relation to HRQL and long-term complications associated with ADT.
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| 44. |
- Wolff, M. F. H., et al.
(author)
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Synthesis and magnetic characterization of MnAs nanoparticles via nanoparticle conversion
- 2011
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In: Nanotechnology. - : IOP Publishing. - 0957-4484 .- 1361-6528. ; 22:5
-
Journal article (peer-reviewed)abstract
- We report on the synthesis of ferromagnetic manganese arsenide (MnAs) nanoparticles via the conversion of primary Mn particles which are generated in an aerosol process in a spark discharge generator. After sintering and size selection in an aerosol setup, the particles are deposited on GaAs(100) B and Si(111) substrates. Subsequent conversion to MnAs particles takes place in an annealing process under a hydrogen atmosphere with an arsine background pressure. The magnetic properties are studied using a SQUID magnetometer. The annealed MnAs particles exhibit hexagonal facets and show anisotropic magnetic behaviour on GaAs(100) B substrates, whereas on Si(111) they remain spherical and show isotropic magnetic behaviour. Scanning transmission electron microscopy studies are used to confirm the conversion from Mn to MnAs.
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| 45. |
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