| 1. |
- Montebelli, Alberto
(författare)
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Modeling the Role of Energy Management in Embodied Cognition
- 2012
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- The quest for adaptive and autonomous robots, flexible enough to smoothly comply with unstructured environments and operate in close interaction with humans, seems to require a deep rethinking of classical engineering methods. The adaptivity of natural organisms, whose cognitive capacities are rooted in their biological organization, is an obvious source of inspiration. While approaches that highlight the role of embodiment in both cognitive science and cognitive robotics are gathering momentum, the crucial role of internal bodily processes as foundational components of the biological mind is still largely neglected.This thesis advocates a perspective on embodiment that emphasizes the role of non-neural bodily dynamics in the constitution of cognitive processes in both natural and artificial systems. In the first part, it critically examines the theoretical positions that have influenced current theories and the author's own position. The second part presents the author's experimental work, based on the computer simulation of simple robotic agents engaged in energy-related tasks. Proto-metabolic dynamics, modeled on the basis of actual microbial fuel cells for energy generation, constitute the foundations of a powerful motivational engine. Following a history of adaptation, proto-metabolic states bias the robot towards specific subsets of behaviors, viably attuned to the current context, and facilitate a swift re-adaptation to novel tasks. Proto-metabolic dynamics put the situated nature of the agent-environment sensorimotor interaction within a perspective that is functional to the maintenance of the robot's overall `survival'. Adaptive processes tend to convert metabolic constraints into opportunities, branching into a rich and energetically viable behavioral diversity.
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| 2. |
- Rambusch, Jana
(författare)
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Mind Games Extended : Understanding Gameplay as Situated Activity
- 2010
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- This thesis addresses computer gameplay activities in terms of the physical handling of a game, players’ meaning-making activities, and how these two processes are closely interrelated. It is examined in greater detail which role the body plays in gameplay, but also how gameplay is shaped by sociocultural factors outside the game, including different kind of tools and players’ participation in community practices. An important step towards an understanding of these key factors and their interaction is the consideration of gameplay as situated activity where players who actively engage with games are situated in both the physical world and the virtual in-game world. To analyse exactly how players interact with both worlds, two case studies on two different games have been carried out, and three different levels of situatedness are identifed and discussed in detail in this thesis, on the basis of existing theories within situated cognition research.
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| 3. |
- Abbas, Muhammad
(författare)
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On the Implementation of Integer and Non-Integer Sampling Rate Conversion
- 2012
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- The main focus in this thesis is on the aspects related to the implementation of integer and non-integer sampling rate conversion (SRC). SRC is used in many communication and signal processing applications where two signals or systems having different sampling rates need to be interconnected. There are two basic approaches to deal with this problem. The first is to convert the signal to analog and then re-sample it at the desired rate. In the second approach, digital signal processing techniques are utilized to compute values of the new samples from the existing ones. The former approach is hardly used since the latter one introduces less noise and distortion. However, the implementation complexity for the second approach varies for different types of conversion factors. In this work, the second approach for SRC is considered and its implementation details are explored. The conversion factor in general can be an integer, a ratio of two integers, or an irrational number. The SRC by an irrational numbers is impractical and is generally stated for the completeness. They are usually approximated by some rational factor.The performance of decimators and interpolators is mainly determined by the filters, which are there to suppress aliasing effects or removing unwanted images. There are many approaches for the implementation of decimation and interpolation filters, and cascaded integrator comb (CIC) filters are one of them. CIC filters are most commonly used in the case of integer sampling rate conversions and often preferred due to their simplicity, hardware efficiency, and relatively good anti-aliasing (anti-imaging) characteristics for the first (last) stage of a decimation (interpolation). The multiplierless nature, which generally yields to low power consumption, makes CIC filters well suited for performing conversion at higher rate. Since these filters operate at the maximum sampling frequency, therefore, are critical with respect to power consumption. It is therefore necessary to have an accurate and efficient ways and approaches that could be utilized to estimate the power consumption and the important factors that are contributing to it. Switching activity is one such factor. To have a high-level estimate of dynamic power consumption, switching activity equations in CIC filters are derived, which may then be used to have an estimate of the dynamic power consumption. The modeling of leakage power is also included, which is an important parameter to consider since the input sampling rate may differ several orders of magnitude. These power estimates at higher level can then be used as a feed-back while exploring multiple alternatives.Sampling rate conversion is a typical example where it is required to determine the values between existing samples. The computation of a value between existing samples can alternatively be regarded as delaying the underlying signal by a fractional sampling period. The fractional-delay filters are used in this context to provide a fractional-delay adjustable to any desired value and are therefore suitable for both integer and non-integer factors. The structure that is used in the efficient implementation of a fractional-delay filter is know as Farrow structure or its modifications. The main advantage of the Farrow structure lies in the fact that it consists of fixed finite-impulse response (FIR) filters and there is only one adjustable fractional-delay parameter, used to evaluate a polynomial with the filter outputs as coefficients. This characteristic of the Farrow structure makes it a very attractive structure for the implementation. In the considered fixed-point implementation of the Farrow structure, closed-form expressions for suitable word lengths are derived based on scaling and round-off noise. Since multipliers share major portion of the total power consumption, a matrix-vector multiple constant multiplication approach is proposed to improve the multiplierless implementation of FIR sub-filters.The implementation of the polynomial part of the Farrow structure is investigated by considering the computational complexity of different polynomial evaluation schemes. By considering the number of operations of different types, critical path, pipelining complexity, and latency after pipelining, high-level comparisons are obtained and used to short list the suitable candidates. Most of these evaluation schemes require the explicit computation of higher order power terms. In the parallel evaluation of powers, redundancy in computations is removed by exploiting any possible sharing at word level and also at bit level. As a part of this, since exponents are additive under multiplication, an ILP formulation for the minimum addition sequence problem is proposed.
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| 4. |
- Abbasi, Mazhar Ali
(författare)
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The synthesis, characterization and device fabrication of ZnO, NiO and their composite nanostructures
- 2014
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Electronics industry has been revolutionized since last few decades because of the fabrication of electronic devices by using nanoscale based materials. But the more innovative feature in the electronic devices is the use of transparent materials, which makes the transparent electronic devices as one of the most interesting research field in nanoscience and nano-technology now a days. In order to have high performance electronic devices based on the wide band gap compound semiconductors, a selection of right transparent material is crucial step. Among all the transparent metal oxides, ZnO is one of the potential candidates due to the ease in the synthesis process, wide bandgap of 3.37 eV, a high exciton binding energy of 60 meV and diverse morphologies. Since p-type ZnO based nanodevices are still difficult to fabricate due to the instability and unreliability of p-type ZnO nanomaterial, therefore several p-type semiconductors are used for the development of p-n junctions. Among those NiO is suitable p-type compound semiconductor to make p-n junction with ZnO because of its wide band gap of 3.7 eV and environment friendly conditions for its synthesis. Keeping these attractive properties of n-type ZnO and p-type NiO, the synthesis of composite nanostructures of these two transparent oxides and fabrication of their electronic devices is presented in this dissertation work.I started my work with the synthesis of ZnO nanostructures focusing on the effect of different anions of zinc salts on the morphology and crystallinity of ZnO nanostructures. Then I grow honey-comb like NiO nanostructures on 3D nickel foam and used these nanostructures for the detection of Zinc ion. After that synthesized NiO and ZnO based composite nanostructures and characterized them, having main focus on the luminescence properties of ZnO when decorated with NiO nanostructures. The composite nanostructures of p-type NiO and n-type ZnO showed enhancement in the luminescence properties. Since pn junction is the back bone of electronic devices so working on the designing of band alignment along with the current transport properties of p-type NiO/n-type ZnO composite structures, an attempt was put forwarded to explain the phenomenon of these compound semiconducting materials. Different devices based on these two compound semiconducting materials are fabricated and designed in the present dissertation work, however still more work is required to improve the efficiency of devices like LEDs and UV detectors.
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| 5. |
- Abouzeedan, Adli, 1955-
(författare)
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SME Performance and Its Relationship to Innovation
- 2011
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Current SME performance models suffer from a number of disadvantages. The models use intensively a business ratio approach, they look at SMEs as a homogenous group, they consider firms to be closed systems, they do not directly incorporate the impact of an enterprise’s innovation activities, and finally they are complex and rely on sophisticated statistical refining methods making them unpractical to use by SME managers. There are four major challenges when one tries to build SME performance models that lack these deficiencies. The first challenge is that the desired performance evaluation model must optimally incorporate both quantitative and qualitative input. The second challenge is that the model must incorporate non-financial input parameters, such as firm size and age (among others), in the performance evaluation models. The third is that the model must consider the variety of SMEs as concerns their business sectors, nationalities, sizes, and ages. The final challenge is that the model must be able to utilize existing limited information available from the SMEs bookkeeping practices in an optimal way.The thesis addresses three questions related to constructing a better SMEperformance model, namely (1) What are the advantages and disadvantages of the existing models used in evaluating SME performance? (2) What characterizes a comprehensive model for measuring SME performance with acknowledgement of the firm’s innovation activities? (3) How can a firm’s innovation activities be enhanced in relation to the firm’s external environment?To construct a model that copes with these challenges, I used a literature-based selection of parameters as well as a theory-based selection. I used both a conceptual approach and an empirical approach to discuss and propose a model, the Survival Index Value (or SIV) model, as an alternative to the existing performance models for SMEs.The major contributions of this thesis to the field of SME performance can be summarized in three outcomes: the SIV model as a new model of SME performance evaluation, the ASPEM as a new tool for strategic utilization of SME performance models, and a new approach to account for innovation in relation to the external environment of the firm using the IBAM tool.The work adds to the theory of the firm, as it presents a new way of evaluating firm performance. It also contributes to bridging the theory of the firm to organizational theory, by elevating the significance of networking and its impact on SME efficiency.
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| 6. |
- Adnane, Bouchaib
(författare)
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Optical characterization of Silicon-based self-assembled nanostructures
- 2010
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- This PhD thesis summarizes the work carried on the optical characterizations of some Si-based self-assembled nanostructures, particularly SiGe/Si quantum dots (QDs) and nanocrystalline (nc)-Si embedded in mesoporous silica (MS) using photoconductivity (PC), photoluminescence (PL), and photoluminescence excitation (PLE) measurements. The spectroscopic studies of SiGe/Si QDs grown on Si by molecular beam epitaxy revealed for the first time well-resolved PLE resonances. When correlated with numerical analysis, these resonances were directly related to the co-existence of spatially direct (inside the SiGe dot) and indirect (across the Si/Ge interface) recombination processes involving different dot populations selected by the monitored detection energy for PLE acquisition. The characteristics of these two transitions were further studied in detail by PLE (in some case implemented together with selective PL) on various samples, which contained either only one Ge dot layer or multiple Gedot/Si stacks, grown at substrate temperatures ranging from 430 to 580 °C; especially the temperature- and excitation power-dependence of the excitation properties. The results illustrated that the electronic structure of SiGe dots are influenced by size, Ge composition, as well as strain connected, and sometimes a mixed effect. Another attempt of the project was the fabrication of lateral transport mid-infrared photodetectors based on multiple Ge-dot/Si stacked structures. A broadband photoresponsivity of the processed multi-finger detectors was estimated to be about 90 mA/W over 3-15 μm range at 20 K, and the peaked photoresponse was measured at ~10 μm. The origin of the measured photocurrent, as elucidated by photoluminescence and photoluminescence excitation spectroscopies, was related to intersubband absorption of normal incidence infrared radiation corresponding to energies between the ground states of the heavy hole and the light hole in the valence band of the SiGe/Si QDs, and subsequent charge transfer to the Ge 2D wetting layer acting as a conduction channel. The absence of photocurrent in the energy range expected for a transition from the ground state to the first excited state of the heavy hole indicated that the holes in the SiGe dots behave essentially as 2D in character rather than a truly 3D confinement, where the transitions between heavy holes states are not allowed for TE polarized radiation (normal incidence). Finally, Si(or Ge) nanocrystals embedded in mesoporous silica samples prepared by spincoating and atomic layer chemical vapor deposition were optically investigated by means of PL with various excitation powers, together with several attempts using different post rapid thermal annealing processes. The shape and energy position of the PL spectra of the nc-Si embedded in MS samples and a reference MS template without nc incorporation were rather similar, but the luminescence was much more intense for those embedded with nanocrystals. This implies that the emission mechanism for MS samples with or without nc-Si could be the same, i.e., the light emission was governed by the surface properties of silica. The semiconductor nanocrystals played a role by sensitizing the luminescence emission through generating more photo-excited carriers. These carriers were then trapped in the defect state e.g. the interfacial oxygen defect sites and subsequently recombine to increase the PL intensity.
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| 7. |
- Afzal, Nadeem
(författare)
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Complexity and Power Reduction in Digital Delta-Sigma Modulators
- 2014
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- A number of state-of-the-art low power consuming digital delta-sigma modulator (ΔΣ) architectures for digital-to-analog converters (DAC) are presented in this thesis. In an oversampling ΔΣ DAC, the primary job of the modulator is to reduce the word length of the digital control signal to the DAC and spectrally shape the resulting quantization noise. Among the ΔΣ topologies, error-feedback modulators (EFM) are well suited for so called digital to digital modulation.In order to meet the demands, various modifications to the conventional EFM architectures have been proposed. It is observed that if the internal and external digital signals of the EFM are not properly scaled then not only the design itself but also the signal processing blocks placed after it, may be over designed. In order to avoid the possible wastage of resources, a number of scaling criteria are derived. In this regard, the total number of signal levels of the EFM output is expressed in terms of the input scale, the order of modulation and the type of the loop filter.Further on, it is described that the architectural properties of a unit element-based DAC allow us to move some of the digital processing of the EFM to the analog domain with no additional hardware cost. In order to exploit the architectural properties, digital circuitry of an arbitrary-ordered EFM is split into two parts: one producing the modulated output and another producing the filtered quantization noise. The part producing the modulated output is removed after representing the EFM output with a set of encoded signals. For both the conventional and the proposed EFM architectures, the DAC structure remains unchanged. Thus, savings are obtained since the bits to be converted are not accumulated in the digital domain but instead fed directly to the DAC.A strategy to reduce the hardware of conventional EFMs has been devised recently that uses multiple cascaded EFM units. We applied the similar approach but used several cascaded modified EFM units. The compatibility issues among the units (since the output of each proposed EFM is represented by the set of encoded signals) are resolved by a number of architectural modifications. The digital processing is distributed among each unit by splitting the primary input bus. It is shown that instead of cascading the EFM units, it is enough to cascade their loop filters only. This leads not only to area reduction but also to the reduction of power consumption and critical path.All of the designs are subjected to rigorous analysis and are described mathematically. The estimates of area and power consumption are obtained after synthesizing the designs in a 65 nm standard cell library provided by the foundry.
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| 8. |
- Ahmad, Shakeel, 1977-
(författare)
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Stimuli Generation Techniques for On-Chip Mixed-Signal Test
- 2010
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- With increased complexity of the contemporary very large integrated circuits the need for onchip test addressing not only the digital but also analog and mixed-signal RF blocks has emerged. The standard production test has become more costly and the instrumentation is pushed to its limits by the leading edge integrated circuit technologies. Also the chip performance for high frequency operation and the area overhead appear a hindrance in terms of the test access points needed for the instrumentation-based test. To overcome these problems, test implemented on a chip can be used by sharing the available resources such as digital signal processing (DSP) and A/D, D/A converters to constitute a built-in-self-test. In this case, the DSP can serve both as a stimuli generator and response analyzer.Arbitrary test signals can be achieved using DSP. Specifically, the ΣΔ modulation technique implemented in software is useful to encode a single- or two-tone stimulus as a onebit sequence to generate a spectrally pure signal with a high dynamic range. The sequence can be stored in a cyclic memory on a chip and applied to the circuit under test using a buffer and a simple reconstruction filter. In this way ADC dynamic test for harmonic and intermodulation distortion is carried out in a simple setup. The FFT artifacts are avoided by careful frequency planning for low-pass and band-pass ΣΔ encoding technique. A noise shaping based on a combination of low- and band-pass ΣΔ modulation is also useful providing a high dynamic range for measurements at high frequencies that is a new approach. However, a possible asymmetry between rise and fall time due to CMOS process variations in the driving buffer results in nonlinear distortion and increased noise at low frequencies. A simple iterative predistortion technique is used to reduce the low frequency distortion components by making use of an on-chip DC calibrated ADC that is another contribution of the author.Some tests, however, like the two-tone RF test that targets linearity performance of a radio receiver, require test stimuli based on a dedicated hardware. For the measurement of the thirdor second-intercept point (IP3/IP2) a spectrally clean stimulus is essential. Specifically, the second- or third-order harmonic or intermodulation products of the stimulus generator should be avoided as they can obscure the test measurement. A challenge in this design is the phase noise performance and spurious tones of the oscillators, and also the distortion-free addition of the two tones. The mutual pulling effect can be minimized by layout isolation techniques.A new two-tone RF generator based on a specialized phase-locked loop (PLL) architecture is presented as a viable solution for IP3/IP2 on-chip test. The PLL provides control over the frequency spacing of two voltage controlled oscillators. For the two-tone stimulus a highly linear analog adder is designed to limit distortion which could obscure the IP3 test. A specialized feedback circuit in the PLL is proposed to overcome interference by the reference spurs. The circuit is designed using 65 nm CMOS process. By using a fine spectral resolution the observed noise floor can be reduced to enable the measurement of second- or third-order intermodulation product tones. This also reflects a tradeoff between the test time and the test performance. While the test time to collect the required number of samples can be of milliseconds the number of samples need not be excessive, since the measurements are carried out at the receiver baseband, where the required sampling frequency is relatively low.
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| 9. |
- Ahrén, Maria, 1979-
(författare)
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Metal Oxide Nanoparticles for Contrast Enhancement in Magnetic Resonance Imaging : Synthesis, Functionalization and Characterization
- 2013
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- This thesis work focuses on the design and production of nanoparticle based contrast agents for signal enhancement in magnetic resonance imaging (MRI). Three different synthesis routes are explored, primarily to produce crystalline gadolinium oxide (Gd2O3) nanoparticles, and surface modification is done to obtain stable, dispersible, biocompatible probes inducing high proton relaxivities.In Paper I and II we utilized the polyol synthesis method and nanoparticle purification was performed with dialysis. Active surface functionalization was achieved by an innermost layer of 3-mercaptopropyl trimetoxy silanes (MPTS) and an outer layer of bifunctional PEG. Surface capping was shown to greatly affect the water proton relaxation to a degree which is strongly dependent on the purification time. PEGylation also induced stabilizing effects and the ability to provide the nanoparticles with luminescent properties was proven by linking the fluorescent dye Rhodamine to the bifunctional PEG.In Paper III the magnetic behavior of yttrium (Y) alloyed Gd2O3 nanoparticles was investigated as a function of Y concentration. This was done by performing magnetic measurements and by studying the signal line width in electron paramagnetic resonance spectroscopy for Gd2O3, Y2O3 and a series of (GdxY1-x)2O3 samples produced using the combustion synthesis. The results verified that the signal line width is dependent on the percent of yttrium dilution. This is considered as an indication of that yttrium dilution changes the electron spin relaxation time in Gd2O3.Paper IV and V present a novel precipitation synthesis method for Gd2O3 nanoparticles. Acetate molecular groups were found to coordinate the nanoparticle surface increasing the water dispersability. The Gd2O3 nanoparticles induce a twice as high relaxivity per gadolinium atom, as compared to the commercially available contrast agent Magnevist. Incorporation of luminescent europium (Eu3+) ions into the Gd2O3 nanoparticles in combination with surface modification with a fluorescent branched carboxyl terminated TEG, produced dual probes with tunable luminescence, maintained relaxivity and thus a bright contrast in MRI.In Paper VI, a new approach to accomplish a dual probe was investigated. Luminescent ZnO nanoparticles decorated with Gd ions bound in an organic matrix were evaluated for MR signal enhancement and ability to function as fluorescent probes. Interestingly, these nanoprobes did show an enhanced capability to both strengthen the MR signal and increase the fluorescent quantum yield, as compared to the pure oxides.In Paper VII we investigate sub 5 nm crystalline manganese based nanoparticles produced by the precipitation synthesis used for Gd2O3 nanoparticles. Manganese oxide was chosen as another candidate for MRI contrast enhancement as it is expected to have a straight forward surface coupling chemistry. Characterization of the crystal structure and chemical composition indicated nanoparticles with a MnO core and presence of manganese species of higher valences at the nanoparticle surface. The MnO nanomaterial showed a superparamagnetic behavior and less capability to increase the MR signal as compared to Gd2O3.Characterization of the nanoparticle crystal structure and size is, throughout the work, performed by means of transmission electron microscopy, X-ray diffraction and dynamic light scattering. The chemical composition is studied with X-ray photoelectron spectroscopy, infrared spectroscopy and near edge X-ray absorption fine structure spectroscopy and the fluorescence characteristics are evaluated with fluorescence spectroscopy. In addition, theoretical models and calculated IR spectroscopy and near edge X-ray absorption fine structure spectroscopy data have been used for evaluation of experimental results.To conclude, the aim of this work is the design, production and characterization of ultrasmall rare earth based nanoparticles for signal enhancement in biomedical imaging. Surface modification clearly increases the colloidal stability and biocompatibility of the nanoparticles. Compared to the agents in clinical use today, these nanoprobes have a higher capability to enhance the MR-signal, and they will in the near future be equipped with tags for specific targeting.
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| 10. |
- Aiempanakit, Montri, 1977-
(författare)
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Reactive High Power Impulse Magnetron Sputtering of Metal Oxides
- 2013
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- The work presented in this thesis deals with reactive magnetron sputtering processes of metal oxides with a prime focus on high power impulse magnetron sputtering (HiPIMS). The aim of the research is to contribute towards understanding of the fundamental mechanisms governing a reactive HiPIMS process and to investigate their implications on the film growth.The stabilization of the HiPIMS process at the transition zone between the metal and compound modes of Al-O and Ce-O was investigated for realizing the film deposition with improved properties and higher depositionrate and the results are compared with direct current magnetron sputtering (DCMS) processes. The investigations were made for different sputtering conditions obtained by varying pulse frequency, peak power and pumping speed. For the experimental conditions employed, it was found that reactive HiPIMS can eliminate/suppress the hysteresis effect for a range of frequency, leading to a stable deposition process with a high deposition rate. The hysteresis was found to be eliminated for Al-O while for Ce-O, it was not eliminated but suppressed as compared to the DCMS. The behavior of elimination/suppression of the hysteresis may be influenced by high erosion rate during the pulse, limited target oxidation between the pulses and gas rarefaction effects in front of the target. Similar investigations were made for Ti-O employing a larger target and the hysteresis was found to be suppressed as compared to the respective DCMS, but not eliminated. It was shown that the effect of gas rarefaction is a powerful mechanism for preventing oxide formation upon the target surface. The impact of this effect depends on the off-time between the pulses. Longer off-times reduce the influence of gas rarefaction.To gain a better understanding of the discharge current-voltage behavior in a reactive HiPIMS process of metal oxides, the ion compositions and ion energy distributions were measured for Al-O and Ti-O using time averaged and time-resolved mass spectrometry. It was shown that the different discharge current behavior between non-reactive and reactive modes couldn’t be explained solely by the change in the secondary electron emission yield from the sputtering target. The high fluxes of O1+ ions contribute substantially to the discharge current giving rise to an increase in the discharge current in the oxide mode as compared to the metal mode. The results also show that the source of oxygen in the discharge is both, the target surface (via sputtering) as well as the gas phase.The investigations on the properties of HiPIMS grown films were made by synthesizing metal oxide thin films using Al-O, Ti-O and Ag-Cu-O. It was shown that Al2O3 films grown under optimum condition using reactive HiPIMS exhibit superior properties as compared to DCMS. The HiPIMS grown films exhibit higher refractive index as well as the deposition rate of the film growth was higher under the same operating conditions. The effect of HiPIMS peak power on TiO2 film properties was investigated and the results are compared with the DCMS. The properties of TiO2 films such as refractive index, film density and phase structure were experimentally determined. The ion composition during film growth was investigated and an explanation on the correlation of the film properties and ion energy was made. It was found that energetic and ionized sputtered flux in reactive HiPIMS can be used to tailor the phase formation of the TiO2 films with high peak powers facilitating the rutile phase while the anatase phase can be obtained using low peak powers. These phases can be obtained at room temperature without external substrate heating or post-deposition annealing which is in contrast to the reactive DCMS where both, anatase and rutile phases of TiO2 are obtained at either elevated growth temperatures or by employing post deposition annealing. The effect of HiPIMS peak power on the crystal structure of the grown films was also investigated for ternary compound, Ag-Cu-O, for which films were synthesized using reactive HiPIMS as well as reactive DCMS. It was found that the stoichiometric Ag2Cu2O3 can be synthesized by all examined pulsing peak powers. The oxygen gas flow rate required to form stoichiometric films is proportional to the pulsing peak power in HiPIMS. DCMS required low oxygen gas flow to synthesis the stoichiometric films. The HiPIMS grown films exhibit more pronounced crystalline structure as compared to the films grown using DCMS. This is likely an effect of highly ionized depositing flux which facilitates an intense ion bombardment during the film growth using HiPIMS. Our results indicate that Ag2Cu2O3film formation is very sensitive to the ion bombardment on the substrate as well as to the backattraction of metal and oxygen ions to the target.
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| 11. |
- Aijaz, Asim, 1980-
(författare)
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Synthesis of Carbon-based and Metal-Oxide Thin Films using High Power Impulse Magnetron Sputtering
- 2014
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- The work presented in this thesis deals with synthesis of carbon-based as well as metal-oxide thin films using highly ionized plasmas. The principal deposition method employed was high power impulse magnetron sputtering (HiPIMS). The investigations on plasma chemistry, plasma energetics, plasma-film interactions and its correlation to film growth and resulting film properties were made. The thesis is divided into two parts: (i) HiPIMS-based deposition of carbon-based thin films and (ii) HiPIMS-based deposition of metal-oxide thin films.In the first part of the thesis, HiPIMS based strategies are presented that were developed to address the fundamental issues of low degree of carbon ionization and low deposition rates of carbon film growth in magnetron sputtering. In the first study, a new strategy was introduced for increasing the degree of ionization of sputtered carbon via increasing the electron temperature in the discharge by using a higher ionization potential buffer gas (Ne) in place of commonly used Ar. A direct consequence of enhanced electron temperatures was observed in the form of measured large fluxes of ionized carbon at the substrate position. Consequently, high mass densities of the resulting amorphous carbon (a-C) thin films reaching 2.8 g/cm3 were obtained.In another study, feasibility of HiPIMS-based high density discharges for high-rate synthesis of dense and hard a-C thin films was explored. A strategy was compiled and implemented that entailed coupling a hydrocarbon precursor gas (C2H2) with high density discharges generated by the superposition of HiPIMS and direct current magnetron sputtering (DCMS). Appropriate control of discharge density (by tuning HiPIMS/DCMS power ratio), gas phase composition and energy of the ionized depositing species lead to a route capable of providing ten-fold increase in the deposition rate of a-C film growth compared to that obtained using HiPIMS Ar discharge in the first study. The increased deposition rate was achieved without significant incorporation of H (<10 %) and with relatively high hardness (>25 GPa) and mass density (~2.32 g/cm3). The knowledge gained in this work was utilized in a subsequent work where the feasibility of adding high ionization potential buffer gas (Ne) to increase the electron temperature in an Ar/C2H2 HiPIMS discharge was explored. It was found that the increased electron temperature lead to enhanced dissociation of hydrocarbon precursor and an increased H incorporation into the growing film. The resulting a-C thin films exhibited high hardness (~ 25 GPa), mass densities in the order of 2.2 g/cm3 and H content as low as about 11%. The striking feature of the resulting films was low stress levels where the films exhibited compressive stresses in the order of 100 MPa.In the second part of the thesis, investigations on reactive HiPIMS discharge characteristics were made for technologically relevant metal-oxide systems. In the first study, the discharge characteristics of Ti-O and Al-O were investigated by studying the discharge current characteristics and measuring the ion flux composition. Both, Ti-O and Al-O discharges were dominated by large fluxes of ionized metallic as well as sputtering and reactive gases species. The generation of large ionized fluxes influenced the discharge characteristics consequently surpassing the changes in the secondary electron emission yields which, in the case of DCMS discharges entail contrasting behavior of the discharge voltage for the two material systems. The study also suggested that the source of oxygen ions in the case of reactive HiPIMS is both, the target surface (via sputtering) as well as gas phase.In a subsequent study, the knowledge gained from the studies on metal-oxide HiPIMS discharges was utilized for investigating the behavior of reactive HiPIMS discharges related to ternary compound thin film growth. In this work Al-Si-O system, which is a promising candidate for anti-reflective and solar thermal applications, was employed to carry out the investigations under varied target compositions (Al, Al0.5Si0.5, and Al0.1Si0.9). It was found that the discharge current behavior of metal and oxide modes of Al-Si-O HiPIMS discharges were similar to those of Al-O and were independent of the target composition. The influence of energy and composition of the ionized depositing fluxes on the film growth was also investigated. It was shown that stoichiometric Al-Si-O thin films exhibiting a refractive index below 1.6 (which is desired for anti-reflective applications) can be grown. Furthermore, the refractive index and chemical composition of the resulting films were found to be unchanged with respect to the energy of the depositing species.The effect of ionized deposition fluxes that are generated in metal-oxide HiPIMS discharges was also investigated for the phase composition and optical properties of TiO2 thin films. It was found that energetic and ionized sputtered flux in reactive HiPIMS can be used to tailor the phase formation of the TiO2 films with high peak powers facilitating the rutile phase while the anatase phase can be obtained using low peak powers. It was also demonstrated that using HiPIMS, these phases can be obtained at room temperature without external substrate heating or post-deposition annealing. The results on plasma and film properties were also compared with DCMS.
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| 12. |
- Ali, Syed M. Usman
(författare)
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Fabrication and characterization of ZnO nanostructures for sensing and photonic device applications
- 2012
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Nanotechnology is an emerging inter-disciplinary paradigm which encompasses diverse fields of science and engineering converge at the nanoscale. This nanoscale science and nanostructure engineering have well demonstrated in the fabrication of sensors/transducers devices with faster response time and better sensitivity then the planer version of the sensor’s configurations. Nanotechnology is not just to grow/fabricate nanostructures by just mixing nanoscale materials together but it requires the ability to understand and to precisely manipulate and control of the developed nanomaterials in a useful way. Nanotechnology is aiding to substantially improve, even revolutionize, many technology and industry sectors like information technology, energy, environmental science, medicine/medical instrumentation, homeland security, food safety, and transportation, among many others. Such applications of nanotechnology are delivering in both expected and unexpected ways on nanotechnology’s promise to benefit the society.The semiconductor ZnO with wide band gap (~ 3.37 eV) is a distinguish and unique material and its nanostructures have attracted great attention among the researchers due to its peculiar properties such as large exciton binding energy (60 meV) at room temperature, the high electron mobility, high thermal conductivity, good transparency and easiness of fabricating it in the different type of nanostructures. Based on all these fascinating properties, ZnO have been chosen as a suitable material for the fabrication of photonic, transducers/sensors, piezoelectric, transparent and spin electronics devices etc. The objective of the current study is to highlight the recent developments in materials and techniques for electrochemical sensing and hetrostructure light emitting diodes (LEDs) luminescence properties based on the different ZnO nanostructures. The sensor devices fabricated and characterized in the work were applied to determine and monitor the real changes of the chemical or biochemical species. We have successfully demonstrated the application of our fabricated devices as primary transducers/sensors for the determination of extracellular glucose and the glucose inside the human fat cells and frog cells using the potentiometric technique. Moreover, the fabricated ZnO based nanosensors have also been applied for the selective determination of uric acid, urea and metal ions successfully. This thesis relates specifically to zinc oxide nanostructure based electrochemical sensors and photonic device (LED) applications.
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| 13. |
- Alling, Björn, 1980-
(författare)
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Configurational and Magnetic Interactions in Multicomponent Systems
- 2010
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- This thesis is a theoretical study of configurational and magnetic interactions in multicomponent solids. These interactions are the projections onto the configurational and magnetic degrees of freedom of the underlying electronic quantum mechanical system, and can be used to model, explain and predict the properties of materials. For example, the interactions govern temperature induced configurational and magnetic order-disorder transitions in Heusler alloys and ternary nitrides.In particular three perspectives are studied. The first is how the interactions can be derived from first-principles calculations at relevant physical conditions. The second is their consequences, like the critical temperatures for disordering, obtained with e.g. Monte Carlo simulations. The third is their origin in terms of the underlying electronic structure of the materials.Intrinsic defects in the half-Heusler system NiMnSb are studied and it is found that low-energy defects do not destroy the important half-metallic property at low concentrations. Deliberate doping of NiMnSb with 3d-metals is considered and it is found that replacing some Ni with extra Mn or Cr creates new strong magnetic interactions which could be beneficial for applications at elevated temperature. A self-consistent scheme to include the effects of thermal expansion and one-electron excitations in the calculation of the magnetic critical temperature is introduced and applied to a study of Ni1−xCuxMnSb.A supercell implementation of the disordered local moments approach is suggested and benchmarked for the treatment of paramagnetic CrN as a disordered magnetic phase. It is found that the orthorhombic-to-cubic phase transition in this nitride can be understood as a first-order magnetic order-disorder transition. The ferromagnetism in Ti1−xCrxN solid solutions, an unusual property in nitrides, is explained in terms of a charge transfer induced change in the Cr-Cr magnetic interactions.Cubic Ti1−xAlxN solid solutions displays a complex and concentration dependent phase separation tendency. A unified cluster expansion method is presented that can be used to simulate the configurational thermodynamics of this system. It is shown that short range clustering do influence the free energy of mixing but only slightly change the isostructural phase diagram as compared to mean-field estimates.
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| 14. |
- Alvi, Naveed ul Hassan
(författare)
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Luminescence Properties of ZnO Nanostructures and Their Implementation as White Light Emitting Diodes (LEDs)
- 2011
-
Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- In this thesis, luminescence properties of ZnO nanostructures (nanorods, nanotubes, nanowalls and nanoflowers) are investigated by different approaches for possible future application of these nanostructures as white light emitting diodes. ZnO nanostructures were grown by different growth techniques on different p-type substrates. Still it is a challenge for the researchers to produce a stable and reproducible high quality p-type ZnO and this seriously hinders the progress of ZnO homojunction LEDs. Therefore the excellent properties of ZnO can be utilized by constructing heterojunction with other p-type materials.The first part of the thesis includes paper I-IV. In this part, the luminescence properties of ZnO nanorods grown on different p-type substrates (GaN, 4H-SiC) and different ZnO nanostructures (nanorods, nanotubes, nanoflowers, and nanowalls) grown on the same substrate were investigated. The effect of the post-growth annealing of ZnO nanorods and nanotubes on the deep level emissions and color rendering properties were also investigated.In paper I, ZnO nanorods were grown on p-type GaN and 4H-SiC substrates by low temperature aqueous chemical growth (ACG) method. The luminescence properties of the fabricated LEDs were investigated at room temperature by electroluminescence (EL) and photoluminescence (PL) measurements and consistency was found between both the measurements. The LEDs showed very bright emission that was a combination of three emission peaks in the violet-blue, green and orange-red regions in the visible spectrum.In paper II, different ZnO nanostructures (nanorods, nanotubes, nanoflowers, and nanowalls) were grown on p-GaN and the luminescence properties of these nanostructures based LEDs were comparatively investigated by EL and PL measurements. The nanowalls structures were found to be emitting the highest emission in the visible region, while the nanorods have the highest emissions in the UV region due to its good crystal quality. It was also estimated that the ZnO nanowalls structures have strong white light with the highest color rendering index (CRI) of 95 with correlated color temperature (CCT) of 6518 K.In paper III, we have investigated the origin of the red emissions in ZnO by using post-growth annealing. The ZnO nanotubes were achieved on p-GaN and then annealed in different ambients (argon, air, oxygen and nitrogen) at 600 oC for 30 min. By comparative investigations of EL spectra of the LEDs it was found that more than one deep level defects are involved in the red emission from ZnO nanotubes/p-GaN LEDs. It was concluded that the red emission in ZnO can be attributed to oxygen interstitials (Oi) and oxygen vacancies (Vo) in the range of 620 nm (1.99 eV) to 690 nm (1.79 eV) and 690 nm (1.79 eV) to 750 nm (1.65 eV), respectively.In paper IV, we have investigated the effect of post-growth annealing on the color rendering properties of ZnO nanorods based LEDs. ZnO nanorods were grown on p-GaN by using ACG method. The as grown nanorods were annealed in nitrogen, oxygen, argon, and air ambients at 600 oC for 30 min. The color rendering indices (CRIs) and correlated color temperatures (CCTs) were estimated from the spectra emitted by the LEDs. It was found that the annealing ambients especially air, oxygen, and nitrogen were found to be very effective. The LEDs based on nanorods annealed in nitrogen ambient, have excellent color rendering properties with CRIs and CCTs of 97 and 2363 K in the forward bias and 98 and 3157 K in the reverse bias.In the 2nd part of the thesis, the junction temperature of n-ZnO nanorods based LEDs at the built-in potential was modeled and experiments were performed to validate the model. The LEDs were fabricated by ZnO nanorods grown on different p-type substrates (4H-SiC, GaN, and Si) by the ACG method. The model and experimental values of the temperature coefficient of the forward voltage near the built-in potential (~Vo) were compared. It was found that the series resistance has the main contribution in the junction temperature of the fabricated devices.In the 3rd part of the thesis, the influence of helium (He+) ion irradiation bombardment on luminescence properties of ZnO nanorods based LEDs were investigated. ZnO nanorods were grown by the vapor-liquid-solid (VLS) growth method. The fabricated LEDs were irradiated by using 2 MeV He+ ions with fluencies of ~ 2×1013 ions/cm2 and ~ 4×1013 ions/cm2. It was observed that the He+ ions irradiation affects the near band edge emissions as well as the deep level emissions in ZnO. A blue shift about 0.0347 eV and 0.082 eV was observed in the PL spectra in the near band emission and green emission, respectively. EL measurements also showed a blue shift of 0.125 eV in the broad green emission after irradiation. He+ ion irradiation affects the color rendering properties and decreases the color rendering indices from 92 to 89.
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| 15. |
- Amadori, Kristian
(författare)
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Geometry Based Design Automation : Applied to Aircraft Modelling and Optimization
- 2012
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Product development processes are continuously challenged by demands for increased efficiency. As engineering products become more and more complex, efficient tools and methods for integrated and automated design are needed throughout the development process. Multidisciplinary Design Optimization (MDO) is one promising technique that has the potential to drastically improve concurrent design. MDO frameworks combine several disciplinary models with the aim of gaining a holistic perspective of a system, while capturing the synergies between different subsystems. Among all disciplines, the geometric model is recognized as playing a key role, because it collects most of the data required to any other disciplinary analysis. In the present thesis, methodologies to enable multidisciplinary optimization in early aircraft design phases are studied. In particular, the research aims at putting the CAD geometric model in the loop. This requires the ability to automatically generate or update the geometric model, here referred to as geometry-based design automation.The thesis proposes the use of Knowledge Based Engineering (KBE) techniques to achieve design reuse and automation. In particular, so called High Level CAD templates (HLCts) are suggested to automate geometry generation and updates. HLCts can be compared to parametric LEGO® blocks containing a set of design and analysis parameters. These are produced and stored in libraries, giving engineers or a computer agent the possibility to first topologically select the templates and then modify the shape of each template parametrically.Since parameterization is central to modelling by means of HLCts, a thorough analysis of the subject is also performed. In most of the literature on MDO and KBE two recurring requirements concerning the geometrical model are expressed: the model should be flexible and robust. However, these requirements have never been properly formulated or defined. Hence, in the thesis a mathematical formulation for geometry model robustness and flexibility are proposed. These formulations ultimately allow the performance of geometric models to be precisely measured and compared.Finally, a prototyping and validation process is presented. The aim is to quickly and cost-effectively validate analytical results from an MDO process. The proposed process adopts different manufacturing techniques depending on the size and purpose of the intended prototype. In the last part of the thesis, three application examples are presented. The examples are chosen from research projects that have been carried out at Linköping University and show how the proposed theoretical results have been successfully employed in practice.
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| 16. |
- Amankwah, Henry, 1969-
(författare)
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Mathematical Optimization Models and Methods for Open-Pit Mining
- 2011
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Open-pit mining is an operation in which blocks from the ground are dug to extract the ore contained in them, and in this process a deeper and deeper pit is formed until the mining operation ends. Mining is often a highly complex industrial operation, with respect to both technological and planning aspects. The latter may involve decisions about which ore to mine and in which order. Furthermore, mining operations are typically capital intensive and long-term, and subject to uncertainties regarding ore grades, future mining costs, and the market prices of the precious metals contained in the ore. Today, most of the high-grade or low-cost ore deposits have already been depleted, and to obtain sufficient profitability in mining operations it is therefore today often a necessity to achieve operational efficiency with respect to both technological and planning issues.In this thesis, we study the open-pit design problem, the open-pit mining scheduling problem, and the open-pit design problem with geological and price uncertainty. These problems give rise to (mixed) discrete optimization models that in real-life settings are large scale and computationally challenging.The open-pit design problem is to find an optimal ultimate contour of the pit, given estimates of ore grades, that are typically obtained from samples in drill holes, estimates of costs for mining and processing ore, and physical constraints on mining precedence and maximal pit slope. As is well known, this problem can be solved as a maximum flow problem in a special network. In a first paper, we show that two well known parametric procedures for finding a sequence of intermediate contours leading to an ultimate one, can be interpreted as Lagrangian dual approaches to certain side-constrained design models. In a second paper, we give an alternative derivation of the maximum flow problem of the design problem.We also study the combined open-pit design and mining scheduling problem, which is the problem of simultaneously finding an ultimate pit contour and the sequence in which the parts of the orebody shall be removed, subject to mining capacity restrictions. The goal is to maximize the discounted net profit during the life-time of the mine. We show in a third paper that the combined problem can also be formulated as a maximum flow problem, if the mining capacity restrictions are relaxed; in this case the network however needs to be time-expanded.In a fourth paper, we provide some suggestions for Lagrangian dual heuristic and time aggregation approaches for the open-pit scheduling problem. Finally, we study the open-pit design problem under uncertainty, which is taken into account by using the concept of conditional value-atrisk. This concept enables us to incorporate a variety of possible uncertainties, especially regarding grades, costs and prices, in the planning process. In real-life situations, the resulting models would however become very computationally challenging.
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| 17. |
- Amin, Gul
(författare)
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ZnO and CuO Nanostructures: Low Temperature Growth, Characterization, their Optoelectronic and Sensing Applications
- 2012
-
Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- One dimensional (1-D), zinc oxide (ZnO) and copper (II) oxide (CuO), nanostructures have great potential for applications in the fields of optoelectronic and sensor devices. Research on nanostructures is a fascinating field that has evolved during the last few years especially after the utilization of the hydrothermal growth method. Using this method variety of nanostructures can be grown from solutions, it is a cheap, easy, and environment friendly approach. These nanostructures can be synthesized on various conventional and nonconventional substrates such as silicon, plastic, fabrics and paper etc.The primary purpose of the work presented in this thesis is to realize controllable growth of ZnO, CuO and nanohybrid ZnO/CuO nanostructures and to process and develop white light emitting diodes and sensor devices from the corresponding nanostructures.The first part of the thesis deals with ZnO nanostructures grown under different hydrothermal conditions in order to gain a better understanding of the growth. Possible parameters affecting the growth such as the pH, the growth temperature, the growth time, and the precursors concentration which can alter the morphology of the nanostructures were investigated (paper 1). Utilizing the advantage of the low temperature for growth we synthesized ZnO nanostructures on different substrates, specifically on flexible substrates, which are likely to be integrated with flexible organic substrates for future foldable and disposable electronics (paper 2, 3).In the second part of the thesis, using the results and findings from the growth of ZnO nanostructures, it was possible to successfully implement ZnO nanostructures for white light emitting diodes (LEDs) on different flexible substrates (paper 4, 5).In paper 4 we realized a ZnO/polymer LED grown on a paper substrate. In paper 5 we extended the idea to print the ZnO nanorods/polymer hybrid LEDs with potential application to large area flexible displays.In the last part of the thesis, CuO and nanohybrid ZnO/CuO nanostructures were utilized to fabricate Ag+ detection and humidity sensors. In paper 6 we reported Ag+ selective electrochemical sensor based on the use of functionalized CuO nanopetals. To combine the advantages of both oxides nanostructures and to improve the performance we fabricated a pn-heterojuction using intrinsic n-ZnO nanorods and p-CuO nanostructures which were then utilized as an efficient humidity sensor (paper 7).
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| 18. |
- Amiri, Shahnaz, 1962-
(författare)
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Economic and Environmental Benefits of CHP-based District Heating Systems in Sweden
- 2013
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Future energy systems and thus the climate are affected by many factors, such as energy resources, energy demand, energy policy and the choice of energy technologies. Energy systems of the future are facing three main challenges; the steady growth of global energy demand, the energy resource depletion, as well as the increasing emissions of carbon dioxide (CO2) and other greenhouse gases and their impact on climate change. To meet the mentioned challenges with sustainability in mind, actions that increase energy efficiency and choosing an energy-efficient energy system which is cost efficient will be essential. Combined heat and power (CHP) plants and district heating and cooling could contribute greatly to increased system efficiency by using energy otherwise wasted.The aim of this study is to increase the understanding of how CHP-based district heating and cooling systems using different primary energy sources can contribute to more cost-efficient energy systems, which reduce global CO2 emissions, and to highlight the impact of some important parameters and measures on Swedish municipal district heating systems. An important assumption in this study is the estimation of CO2 emissions from electricity production, which is based on marginal electricity perspectives. In the short term, the marginal electricity is assumed to come from coal-fired condensing power plants while in the long term it consists of electricity produced by natural gas-fired combined cycle condensing power plants. This means that the local electricity production will replace the marginal electricity production. The underlying assumption is an ideal fully deregulated European electricity market where trade barriers are removed and there are no restrictions on transfer capacity.The results show that electricity generation in CHP plants, particularly in higher efficiency combined steam and gas turbine heat and power plants using natural gas, can reduce the global environmental impact of energy usage to a great extent. The results confirm, through the scenarios presented in this study, that waste as a fuel in CHP-based district heating systems is fully utilised since it has the lowest operational costs. The results also show how implementation of a biogas-based CHP plant in a biogas system contributes to an efficient system, as well as lowering both CO2 emissions and system costs. The results show that replacing electricity-driven (e.g. compression) cooling by heat-driven cooling using district heating (e.g. absorption chillers) in a CHP system is a cost-effective and climate friendly technology as electricity consumption is reduced while at the same time the electricity generation will be increased. The results of the study also show that there is potential to expand district heating systems to areas with lower heat density, with both environmental and economic benefits for the district heating companies.The results reveal that the operation of a studied CHP-based district heating system with an imposed emission limit is very sensitive to the way CO2 emissions are accounted, i.e., local CO2 emissions or emissions from marginal electricity production. The results show how the electricity production increases in the marginal case compared with the local one in order to reduce global CO2 emissions. The results also revealed that not only electricity and fuel prices but also policy instruments are important factors in promoting CHP-based district heating and cooling systems. The use of electricity certificates has a large influence for the introduction of biogas-based cogeneration. Another conclusion from the modelling is that present Swedish policy instruments are strong incentives for cogeneration with similar impact as applying external costs.
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| 19. |
- Amloy, Supaluck, 1980-
(författare)
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Polarization-resolved photoluminescence spectroscopy of III-nitride quantum dots
- 2013
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- In this thesis, results from studies on (In)GaN quantum dots (QDs) are presented, including investigations of the structural, optical and electronic properties. The experimental studies were performed on GaN and InGaN QDs grown by molecular beam epitaxy, taking advantage of the Stranki-Krastanov growth mode for the GaN QD samples and the composition segregation for the InGaN QD samples.Optical spectroscopy of the (In)GaN QDs was performed with a combination of different experimental techniques, e.g. stationary microphotoluminescence (μPL) and timeresolved μPL. The μPL spectroscopy is suitable for studies of single QDs due to the wellfocused excitation laser spot, and it typically does not require any special sample preparation. The powerful combination of power and polarization dependences was used to distinguish the exciton and the biexciton emissions from other emission lines in the recorded spectra.The QDs could be observed with random in-plane anisotropy, as determined by the strong linear polarization for single QDs but with different angular orientation from dot to dot. Additionally, these experimental results are in good agreement with the computational results revealing a similar degree of polarization for the exciton and the biexciton emissions. Further, the theory predicts that the discrepancy of the polarization degree is larger between the positive and negative trions in comparison with the exciton and the biexciton. Based on this result, polarization resolved spectroscopy is proposed as a simple tool for the identification of trions and their charge states.The fine-structure splitting (FSS) and the biexciton binding energy (Ebxx) are essential QD parameters of relevance for the possible generation of quantum entangled photon pairs in a cascade recombination of the biexciton. In general, the Coulomb interaction between the negatively charged electron and the positively charged hole lifts the fourfold degeneracy of the electron and hole pair ground state, forming a set of zero-dimensional exciton states of unequal energies. This Coulomb-induced splitting, referred to as the FSS, results in an electronic fine structure, which is strongly dependent on the symmetry of the exciton wave function. The FSS was in this work resolved and investigated for excitons in InGaN QDs, using polarization-sensitive μPL spectroscopy employed on the cleaved-edge of the samples. As expected, the FSS is found to exhibit identical magnitudes, but with reversed sign for the exciton and the biexciton. For quantum information applications, a vanishing FSS is required, since otherwise the emissions of the polarization-entangled photon pairs in the cascade biexciton recombination will be prohibited.The biexcitons are found to exhibit both positive and negative binding energies for the investigated QDs. Since a negative binding energy indicates a repulsive Coulomb interaction, such biexcitons (or exciton complexes) cannot exist in structures of higher dimensionality. On the other hand, a biexciton with a negative binding energy can be found in QDs, since the exciton complexes still remain bound due to their three dimensional confinement. Moreover, the biexciton binding energy depends on the dot size, which implies that a careful size control of dots could enable manipulation of the biexciton binding energy. A large Ebxx value enables better and cheaper spectral filtering, in order to purify the single photon emission, while a proposed time reordering scheme relies on zero Ebxx for the generation of entangled photons.The dynamics of the exciton and the biexciton emissions from InGaN QD were measured by means of time-resolved μPL. The lifetimes of the exciton related emissions are demonstrated to depend on the dot size. Both the exciton and the biexciton emissions reveal mono-exponential decays, with a biexciton lifetime, which is about two times shorter than the exciton lifetime. This implies that the QD is small, with a size comparable to the exciton Bohr radius. The photon generation rates can be manipulated by controlling the QDs size, which in turn can be utilized for generation of single- and entangled-photons on demand, with a potential for applications in e.g. quantum information.The polarization of the emitted single photons can be manipulated by using a polarizer, but to the prize of photon loss and reduced emission intensity. Alternative methods to control the polarization of the emission light are a manipulation of the dot symmetry statically by its shape or dynamically by an externally applied electric field. Predictions based on performed calculations show that in materials with a small spin-orbit split-off energy (ΔSO), like the III-nitride materials, the polarization degree of the emission is more sensitive to dot asymmetry than in materials with a large value for ΔSO, e.g. the III-arsenide materials. Moreover, for an electric field applied in the 1͞10 and the 11͞2 directions of the zinc-blende lens-shaped QDs grown on the (111) plane, the polarization degree of InN QDs is found to be significantly more, by a factor of ~50 times, sensitive to the electric field than for GaN QDs. This work demonstrates that especially the InN based QD, are suitable for manipulation of the polarization by the direct control of the dot symmetry or by externally applied electric fields.
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| 20. |
- Andersson, Ann-Christine
(författare)
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Quality Improvement in Healthcare : Experiences from a Swedish County Council Initiative
- 2013
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Quality improvement (QI) has become an important issue in healthcare settings. A central question for many healthcare systems is how to manage improvement initiatives adequately. All county councils and regions managing healthcare in Sweden have started to work with QI at an organizational system level, to varied extents. The Kalmar county council improvement initiative constitutes the empirical basis of this thesis. The aim of the thesis is to provide knowledge about different aspects of a county-wide improvement initiative, and a broader understanding of factors and strategies that affect participation, management and outcomes. The overall study design is based on a case study.The first two studies illuminate the practice-based (micro level), bottom-up perspective. Inductively five different areas (categories) were identified. Factors influencing participation in improvement initiatives provided the basis for the next study. The result showed that different staff categories were attracted by different initiatives. The next two studies illuminate the top-down (macro/meso) management perspective. Managers’ views of how patients can participate were investigated and a content analysis of the written answers was made. Four main areas (categories) were identified. A survey study investigated all of the county council managers’ experiences of the whole improvement initiative. Overall the managers thought that the improvement work was worth the effort. To evaluate the Breakthrough Collaborative program, a survey was developed and tested. This survey was used to investigate process and outcome of the BC program. The majority of the respondents were satisfied with their work, but wanted more time for teams to meet and work. To find out if an improvement program can affect outcome and contribute to sustainable changes, interviews were made with project applicants (n=202). Almost half (48%) of the projects were funded, and of those 51% were sustained. Of the rejected (not funded) projects, 28% were accomplished and sustained anyway. The results in this thesis cannot show that the “golden mean” exists, or that a single best way to manage changes and improvements in a healthcare organization has been found, but the way QI initiatives are organized does affect participation and outcomes. The intention, from the management topdown system level, encouraging staff and units and letting practice-based ideas develop at all system levels, can stimulate and facilitate improvement work.
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| 21. |
- Andersson, Henric, 1963-
(författare)
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Variability and Customization of Simulator Products : A Product Line Approach in Model Based Systems Engineering
- 2012
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- AIRCRAFT DEVELOPERS, like other organizations within development and manufacturing, are experiencing increasing complexity in their products and growing competition in the global market. Products are built from increasingly advanced technologies and their mechanical, electronic, and software parts grow in number and become more interconnected. Different approaches are used to manage information and knowledge of products in various stages of their lifecycle."Reuse" and "Model Based Development" are two prominent trends for improving industrial development efficiency. The product line approach is used to reduce the time to create product variants by reusing components. The model based approach provides means to capture knowledge about a system in the early lifecycle stages for usage throughout its entire lifetime. It also enables structured data management as a basis for analysis, automation, and team collaboration for efficient management of large systems and families of products.This work is focused on the combination of methods and techniques within;modeling and simulation-based development, and(re)use of simulation models through the product line concept.With increasing computational performance and more efficient techniques/tools for building simulation models, the number of models increases, and their usage ranges from concept evaluation to end-user training. The activities related to model verification and validation contribute to a large part of the overall cost for development and maintenance of simulation models. The studied methodology aims to reduce the number of similar models created by different teams during design, testing, and end-user support of industrial products.Results of the work include evaluation of a configurator to customize and integrate simulation models for different types of aircraft simulators that are part of a simulator product family. Furthermore, contribution comprises results where constraints in the primary product family (aircraft) govern the configuration space of the secondary product family (simulators). Evaluation of the proposed methodology was carried out in cooperation with the simulator department for the 39 Gripen fighter aircraft at Saab Aeronautics.
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| 22. |
- Andersson, Viktor
(författare)
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Electron tomography and optical modelling for organic solar cells
- 2012
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Organic solar cells using carbon based materials have the potential to deliver cheap solar electricity. The aim is to be able to produce solar cells with common printing techniques on flexible substrates, and as organic materials can be made soluble in various solvents, they are well adapted to such techniques. There is a large variation of organic materials produced for solar cells, both small molecules and polymers. Alterations of the molecular structure induce changes of the electrical and optical properties, such as band gap, mobility and light absorption. During the development of organic solar cells, the step of mixing of an electron donor and an electron acceptor caused a leap in power conversion efficiency improvement, due to an enhanced exciton dissociation rate. Top performing organic solar cells now exhibit a power conversion efficiency of over 10%. Currently, a mix of a conjugated polymer, or smaller molecule, and a fullerene derivative are commonly used as electron donor and acceptor. Here, the blend morphology plays an important role. Excitons formed in either of the donor or acceptor phase need to diffuse to the vicinity of the donor-acceptor interface to efficiently dissociate. Exciton diffusion lengths in organic materials are usually in the order of 5-10 nm, so the phases should not be much larger than this, for good exciton quenching. These charges must also be extracted, which implies that a network connected to the electrodes is needed. Consequently, a balance of these demands is important for the production of efficient organic solar cells.Morphology has been found to have a significant impact on the solar cell behaviour and has thus been widely studied. The aim of this work has been to visualize the morphology of active layers of organic solar cells in three dimensions by the use of electron tomography. The technique has been applied to materials consisting of conjugated polymers blended with fullerene derivatives. Though the contrast in these blends is poor, three-dimensional reconstructions have been produced, showing the phase formation in three dimensions at the scale of a few nanometres. Several material systems have been investigated and preparation techniques compared.Even if excitons are readily dissociated and paths for charge extraction exist, the low charge mobilities of many materials put a limit on film thickness. Although more light could be absorbed by increased film thickness, performance is hampered due to increased charge recombination. A large amount of light is thus reflected and not used for energy conversion. Much work has been put into increasing the light absorption without hampering the solar cell performance. Aside from improved material properties, various light trapping techniques have been studied. The aim is here to increase the optical path length in the active layer, and in this way improve the absorption without enhanced extinction coefficient.At much larger dimensions, light trapping in solar cells with folded configuration has been studied by the use of optical modelling. An advantage of these V-cells is that two materials with complementing optical properties may be used together to form a tandem solar cell, which may be connected in either serial or parallel configuration, with maintained light trapping feature. In this work optical absorption in V-cells has been modelled and compared to that of planar ones.
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| 23. |
- Andrésen, Cecilia
(författare)
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Protein Structure and Interaction in Health and Disease
- 2011
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- This thesis focuses on protein structure, dynamics and interaction and their relation to human disease. In particular, the biophysical and structural properties of both well-ordered and partially disordered proteins are studied using a range of biophysical techniques such as circular dichroism spectroscopy, fluorescence spectroscopy, mass spectrometry and nuclear magnetic resonance spectroscopy. Pseudomonas aeruginosa is a human pathogen due to its multidrug resistance (MDR) caused by overexpression of efflux pump systems. This thesis describes how MDR mutations within the MexR repressor of the MexAB-OprM system reduce the DNA affinity by altering its stability with maintained structure. The oncogenic protein c-Myc is involved in many essential biological functions such as cell proliferation, differentiation and apoptosis and is also highly associated with several forms of human cancers, and where the N-terminal domain is regulated by a plethora of protein interactions. In this thesis the intrinsically disordered N-terminal part of c-Myc and its interactions with the proteins Bin1 and TBP are described. Myc binds Bin1 with maintained disorder in a multivalent manner, which may explain why the onco-protein can interact with such a wide range of binding partners. A similarly dynamic interaction is observed for Myc with the TATA-binding protein (TBP). The essential human multidomain glutaredoxin Grx3 is associated with several biological functions such as redox signaling, proliferation and signal transduction. We have solved the structure and analyzed the dynamic properties in the ps-ns and ms time scale for the two N-terminal domains, providing a platform for further analysis of the Grx3 protein and its interactions. Taken together, this thesis emphasizes the importance of joint structural, biophysical and dynamic studies to better understand protein function in health and disease.
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| 24. |
- Ankelhed, Daniel, 1980-
(författare)
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On design of low order H-infinity controllers
- 2011
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- When designing controllers with robust performance and stabilization requirements, H-infinity synthesis is a common tool to use. These controllers are often obtained by solving mathematical optimization problems. The controllers that result from these algorithms are typically of very high order, which complicates implementation. Low order controllers are usually desired, since they are considered more reliable than high order controllers. However, if a constraint on the maximum order of the controller is set that is lower than the order of the so-called augmented system, the optimization problem becomes nonconvex and it is relatively difficult to solve. This is true even when the order of the augmented system is low.In this thesis, optimization methods for solving these problems are considered. In contrast to other methods in the literature, the approach used in this thesis is based on formulating the constraint on the maximum order of the controller as a rational function in an equality constraint. Three methods are then suggested for solving this smooth nonconvex optimization problem.The first two methods use the fact that the rational function is nonnegative. The problem is then reformulated as an optimization problem where the rational function is to be minimized over a convex set defined by linear matrix inequalities (LMIs). This problem is then solved using two different interior point methods.In the third method the problem is solved by using a partially augmented Lagrangian formulation where the equality constraint is relaxed and incorporated into the objective function, but where the LMIs are kept as constraints. Again, the feasible set is convex and the objective function is nonconvex.The proposed methods are evaluated and compared with two well-known methods from the literature. The results indicate that the first two suggested methods perform well especially when the number of states in the augmented system is less than 10 and 20, respectively. The third method has comparable performance with two methods from literature when the number of states in the augmented system is less than 25.
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- Arwidson, Jonas, 1972-
(författare)
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Thermal Fatigue Life Prediction of Solder Joints in Avionics by Surrogate Modeling : A Contribution to Physics of Failure in Reliability Prediction
- 2013
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Manufacturers of aerospace, defense, and high performance (ADHP) equipment are currently facing multiple challenges related to the reliability of electronic systems. The continuing reduction in size of electronic components combined with increasing clock frequencies and greater functionality, results in increased power density. As an effect, controlling the temperature of electronic components is central in electronic product development in order to maintain and potentially improve the reliability of the equipment. Simultaneously, the transition to lead-free electronic equipment will most probably propagate also to the ADHP industry. Compared to well-proven tin-lead solder, the knowledge about field operation reliability of lead-free solders is still limited, as well as the availability of damage evaluation models validated for field temperature conditions. Hence, the need to fill in several knowledge gaps related to reliability and reliability prediction of lead-free solder alloys is emphasized. Having perceived increasing problems experienced in the reliability of fielded equipment, the ADHP industry has suggested inclusion of physics-of-failure (PoF) in reliability prediction of electronics as one potential measure to improve the reliability of the electronic systems.This thesis aims to contribute to the development of reliable ADHP systems, with the main focus on electronic equipment for the aerospace industry. In order to accomplish this, the thesis provides design guidelines for power distribution on a double-sided printed circuit board assembly (PBA) as a measure to improve the thermal performance without increasing the weight of the system, and a novel, computationally efficient method for PoF-based evaluation of damage accumulation in solder joints in harsh, non-cyclic field operation temperature environments.Thermal fatigue failure mechanisms and state‑of‑the‑art thermal design and design tools are presented, with focus on the requirements that may arise from avionic use, such as low weight, high reliability, and ability to sustain functional during high vibration levels and high g-forces. Paper I, II, and III describes an in-depth investigation that has been performed utilizing advanced thermal modeling of power distribution on a double-sided PBA as a measure to improve the thermal performance of electronic modules.Paper IV contributes to increasing the accuracy of thermal fatigue life prediction in solder joints, by employing existing analytical models for predicting thermal fatigue life, but enhancing the prediction result by incorporating advanced thermal analysis in the procedure.Papers V and VI suggest and elaborate on a computational method that utilizes surrogate stress and strain modeling of a solder joint, to quickly evaluate the damage accumulated in a critical solder joint from non-cyclic, non-simplified field operation temperature profiles, with accuracy comparable to finite element modeling. The method has been tested on a ball grid array package with SnAgCu solder joints. This package is included in an extensive set of accelerated tests that helps to qualify certain packages and solder alloys for avionic use. The tests include -20°C to +80°C and -55°C to +125°C thermal cycling of a statistically sound population of a number of selected packages, assembled with SnAgCu, Sn100C, and SnPbAg solder alloys. Statistical analysis of the results confirms that the SnAgCu-alloy may outperform SnPbAg solder at moderate thermal loads on the solder joints.In Papers VII and VIII, the timeframe is extended to a future, in which validated life prediction models will be available, and the suggested method is expected to increase the accuracy of embedded prognostics of remaining useful thermal fatigue life of a critical solder joint.The key contribution of the thesis is the added value of the proposed computational method utilized in the design phase for electronic equipment. Due to its ability for time-efficient operation on uncompressed temperature data, the method gives contribution to the accuracy, and thereby also to the credibility, of reliability prediction of electronic packages in the design phase. This especially relates to applications where thermal fatigue is a dominant contributor to the damage of solder joints.
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