Sökning: WFRF:(Hawke J.)
> (2000-2004) >
The relationship be...
The relationship between soil solution pH and Al3+ concentrations in a range of South Island (New Zealand) soils
-
- Adams, M L (författare)
- University of Canterbury, New Zealand
-
- Hawke, D J (författare)
- University of Canterbury, New Zealand
-
- Nilsson, Nils (författare)
- University of Canterbury, New Zealand
-
visa fler...
-
- Powell, K J (författare)
- University of Canterbury, New Zealand
-
visa färre...
-
(creator_code:org_t)
- 2000
- 2000
- Engelska.
-
Ingår i: Australian Journal of Soil Research. - 0004-9573 .- 1446-568X. ; 38:1, s. 141-153
- Relaterad länk:
-
https://urn.kb.se/re...
-
visa fler...
-
https://doi.org/10.1...
-
visa färre...
Abstract
Ämnesord
Stäng
- Concentrations of Al3+ were calculated in soil solutions from concentrations of the monomeric ‘reactive Al’ species ([Al3+] + [Al(OH)2+] + [Al(OH)2+] + [AlF2+]) obtained using a recently reported flow injection analysis (FIA) chelating resin technique. Soil solution samples came from 7 sites encompassing a range of New Zealand soils (Brown, Gley, Pallic, Podzol, and Recent Soils) and vegetation types (pasture, shrub lands, and indigenous and exotic forest). Previously published data from a further 7 sites, obtained using a rapid (7 s) FIA technique, were transformed to give compatible results. The resultant data (n = 85) covered the pH range 2.7–7.6, and showed a single curvilinear relationship for log [Al3+] v. soil solution pH, regardless of vegetation or soil type. At pH >5.6, the data had a slope of –2.98 and fell between the amorphous Al(OH)3 and gibbsite solubility lines. At pH <5.0, the data had a slope of –0.46; further, the soil solutions were under-saturated with respect to both minerals. These results are interpreted as indicating control of Al solubility by Al(OH)3(s) (at pH >5.6) and soil organic matter (at pH <5.0), respectively. This interpretation is supported by data from a pH-dependent Al–fulvic acid binding curve, for which calculated values of [Al3+] follow the same curvilinear relationship determined from the soil solution samples.
Ämnesord
- NATURVETENSKAP -- Geovetenskap och miljövetenskap -- Miljövetenskap (hsv//swe)
- NATURAL SCIENCES -- Earth and Related Environmental Sciences -- Environmental Sciences (hsv//eng)
Nyckelord
- flow injection analysis
- solubility
- speciation
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
Hitta via bibliotek
Till lärosätets databas