| 1. |
- Barnes, C. J., et al.
(författare)
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Using Th-U-Pb geochronology to extract crystallization ages of Paleozoic metamorphic monazite contaminated by initial Pb
- 2021
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Ingår i: Chemical Geology. - : Elsevier. - 0009-2541 .- 1872-6836. ; 582
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Tidskriftsartikel (refereegranskat)abstract
- Geochronology of Th-rich minerals is advantageous as it allows use of three isotopic systems (i.e., Pb-206/U-238, Pb-207/U-235, and Pb-208/Th-232) for accurate data assessment. The Pb-208/Th-232 system is especially advantageous in cases where the dated mineral includes an initial Pb component, as Pb-208/Th-232 is the least sensitive to the effects of initial Pb amongst the three systems. This benefit is demonstrated with monazite from a white mica schist of the Tsakkok Lens, Scandinavian Caledonides, where three distinct generations of Paleozoic monazite (Mnzsingle bondI, Mnz-II, Mnz-III) are recognized and dated using laser ablation inductively coupled mass spectrometry. The generations are interpreted to represent monazite crystallization in high-pressure conditions (Mnzsingle bondI), followed by lower-pressure monazite growth (Mnz-II), and likely dissolution-reprecipitation of the pre-existing monazite (Mnz-III). The results are compared in Tera-Wasserburg, Wetherill, and Th-U-Pb concordia space for each monazite generation. In both Tera-Wasserburg and Wetherill space, the data are all discordant and indicate an initial Pb component in the monazite. The trend and magnitude of discordance due to initial Pb in Mnz-I and Mnz-II is generally controlled by UO2 content of the monazite, with higher UO2 equating to greater radiogenic Pb and a dampening of the initial Pb effect, which is most prominent in the Pb-207/U-235 system. For the same generations, initial Pb discordance of Pb-206/U-238 versus Pb-208/Th-232 is less apparent due to the insensitivity of Pb-208/Th-232. Mnz-III does not follow the initial Pb trends, likely due to disturbance of the chemical and isotopic systems during recrystallization. Additional discordance in Mnz-I and Mnz-II, which is not related to initial Pb, is recognized and increases with actinide content. The additional discordance may be due to Pb-mobilization in Mnz-I and Mnz-II domains and is revealed when utilizing the( 208)Pb/Th-232 system due to its insensitivity to initial Pb effects. Consequently, relying only on the U-Pb systems can lead to significant initial Pb overcorrections in Tera-Wasserburg or Wetherill concordia space and to calculations of erroneously young concordia dates. The Th-U-Pb concordia method, incorporating all three systems, does not require an initial Pb correction and, therefore, can account for the additional discordance. The Th-U-Pb concordia dates are interpretated as accurate crystallization ages for Mnz-I (484.7 +/- 1.1 Ma, MSWD: 1.4) and Mnz-II (474.7 +/- 1.2 Ma, MSWD: 1.9). The timing for Mnz-III formation is not well-resolved as it formed via result of dissolution-reprecipitation of the pre-existing monazite, likely under lower amphibolite- to greenschist-facies conditions.
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| 2. |
- Drake, Henrik, Docent, 1979-, et al.
(författare)
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Biosignatures of ancient microbial life are present across the igneous crust of the Fennoscandian shield
- 2021
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Ingår i: Communications Earth & Environment. - : Springer Nature. - 2662-4435. ; 2:1
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Tidskriftsartikel (refereegranskat)abstract
- Earth’s crust contains a substantial proportion of global biomass, hosting microbial life up to several kilometers depth. Yet, knowledge of the evolution and extent of life in this environment remains elusive and patchy. Here we present isotopic, molecular and morphological signatures for deep ancient life in vein mineral specimens from mines distributed across the Precambrian Fennoscandian shield. Stable carbon isotopic signatures of calcite indicate microbial methanogenesis. In addition, sulfur isotope variability in pyrite, supported by stable carbon isotopic signatures of methyl-branched fatty acids, suggest subsequent bacterial sulfate reduction. Carbonate geochronology constrains the timing of these processes to the Cenozoic. We suggest that signatures of an ancient deep biosphere and long-term microbial activity are present throughout this shield. We suggest that microbes may have been active in the continental igneous crust over geological timescales, and that subsurface investigations may be valuable in the search for extra-terrestrial life.
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| 3. |
- Kershaw, Jane, et al.
(författare)
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The scale of dirham imports to the Baltic in the ninth century : new evidence from archaeometric analyses of early Viking-Age silver
- 2021
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Ingår i: Fornvännen. - Stockholm : Kungl. Vitterhets Historie och Antikvitets Akademien. - 0015-7813 .- 1404-9430. ; 116:3, s. 185-204
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Tidskriftsartikel (refereegranskat)abstract
- We present a high precision, minimally-destructive geochemical (lead isotope and trace element) analysis of nine cast silver items from early Viking-Age hoards from the Baltic. Comparing the data to a large reference dataset comprising Islamic dirhams and ninth-century Western European silver, we find that the artefacts were cast chiefly from recycled Islamic silver. Isotopic modelling reveals, further, that the Islamic silver derives from a stock that entered the central Baltic in the first half of the ninth century. This period has traditionally been characterised as one of low-level dirham import, before the escalation of the dirham trade from c. AD 860/70. Our results suggest instead that dirhams entered the central Balticin significant numbers before c. 850, but were routinely melted down for casting into artefacts. This has two important implications. First, it suggests that the early ninth-century Baltic economy was more closely coupled to Eurasian trade networks than current appreciated. Second, it calls into question the reliance on extant dirhams as a guide to Scandinavia’s engagement in long-distance traderoutes.
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| 6. |
- Tillberg, Mikael, 1990, et al.
(författare)
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Reconstructing craton-scale tectonic events via in situ Rb-Sr geochronology of poly-phased vein mineralization
- 2021
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Ingår i: Terra Nova. - : Wiley. - 0954-4879 .- 1365-3121. ; 33:5, s. 502-510
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Tidskriftsartikel (refereegranskat)abstract
- Fault- and fracture-hosted multi-stage mineral assemblages that formed by fracture reactivation and fluid migration, constitute archives of the tectonic evolution of Precambrian cratons. Complex intergrowth patterns of these mineral records often hinder absolute dating of mineralization events for geological models. We apply LA-ICP-MS/MS in situ Rb-Sr dating of single crystal growth zones in sub-mm-wide vein mineralization assemblages including illite, K-feldspar, albite, calcite, mica, zeolites, fluorite and/or epidote at three Palaeoproterozoic crystalline bedrock sites over 300 km apart in the Fennoscandian Shield. The dating campaign reveals multiple age clusters between ca. 1757 +/- 15 and 355 +/- 12 Ma correlating with fluid flow and fracture reactivation events initiated by far-field orogens and their foreland basin evolution. This new approach for reconstructing geological histories of Precambrian cratons connects micro-scale age determinations of different mineral growth zones in fractures with regional-scale crustal dynamic responses to tectonic events.
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