1. |
|
|
2. |
|
|
3. |
- Stich, Troy A., et al.
(författare)
-
Structural insights into [Co4O4(C5H5N)(4)(CH3CO2)(4)](+), a rare Co(IV)-containing cuboidal complex
- 2013
-
Ingår i: Polyhedron. - : Elsevier BV. - 0277-5387 .- 1873-3719. ; 64:SI, s. 304-307
-
Tidskriftsartikel (refereegranskat)abstract
- We report high-frequency (up to 219 GHz) and correspondingly high-field electron paramagnetic resonance spectra and X-ray crystal structure of [Co4O4(pyridine)(4)(acetate)(4)](+) ([Co4O4(py)(4)(OAc)(4)](+)) that serves as a structural and spectroscopic model of cobalt-oxide films that are capable of oxidizing water. These results are, in large part, consistent with those from our earlier, lower-frequency study and serve to benchmark future high-field studies on paramagnetic states of the catalyst film. (C) 2013 Published by Elsevier Ltd.
|
|