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- Belda, Oscar, et al.
(author)
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Molybdenum-catalyzed asymmetric allylic alkylations
- 2004
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In: Accounts of Chemical Research. - : American Chemical Society (ACS). - 0001-4842 .- 1520-4898. ; 37:3, s. 159-167
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Journal article (peer-reviewed)abstract
- The highly regio- and enantioselective molybdenum-catalyzed allylic alkylation reaction has become a powerful synthetic tool during the past few years. This Account describes the achievements gained so far in the area, with special attention directed to the different chiral ligands that have been used for inducing chirality in the products, the range of allylic substrates and nucleophiles employed, mechanistic studies, and applications of the reaction in asymmetric syntheses.
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| 2. |
- Larhed, M., et al.
(author)
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Microwave-accelerated homogeneous catalysis in organic chemistry
- 2002
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In: Accounts of Chemical Research. - Uppsala Univ, BMC, Dept Organ Pharmaceut Chem, SE-75123 Uppsala, Sweden. Royal Inst Technol, Dept Chem, SE-10044 Stockholm, Sweden. : American Chemical Society (ACS). - 0001-4842 .- 1520-4898. ; 35:9, s. 717-727
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Research review (peer-reviewed)abstract
- The efficiency of microwave flash heating in accelerating organic transformations (reaction times reduced from days and hours to minutes and seconds) has recently-been proven in several different fields of organic chemistry. This specific account mainly summarizes our own experiences in developing rapid, robust, and selective microwave-assisted transition metal-catalyzed homogeneous reactions. Applications include selective Heck couplings, cross-couplings, and asymmetric substitutions. The science of green chemistry was developed to meet the increasing demand for environmentally benign chemical processes. We believe the combination of metal catalysis and microwave heating will be of importance in the search for green laboratory-scale synthesis.
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| 3. |
- Norberg, J, et al.
(author)
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Molecular dynamics applied to nucleic acids
- 2002
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In: Accounts of chemical research. - : American Chemical Society (ACS). - 0001-4842 .- 1520-4898. ; 35:6, s. 465-472
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Journal article (peer-reviewed)
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| 4. |
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