| 1. |
- Pineider, F., et al.
(författare)
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Plasmon-enhanced magneto-optical detection of single-molecule magnets
- 2019
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Ingår i: Materials Horizons. - : Royal Society of Chemistry (RSC). - 2051-6347 .- 2051-6355. ; 6:6, s. 1148-1155
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Tidskriftsartikel (refereegranskat)abstract
- Here we report on nanoarchitectures composed of molecular magnets deposited on optical nanoantennas. We demonstrate a significantly boosted magneto-optical detection of a thin film of a terbium(III) bis-phthalocianinato (TbPc2) single-molecule magnet and we track down the origin of this enhancement to nanoantenna effects at the optical level. This finding suggests that the vast knowledge on plasmon-enhanced spectroscopies can be readily extended to magneto-optics, thus paving the way to strong magneto-optical enhancements for the readout of nanometric devices embedding single-molecule magnets.
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| 2. |
- Urbanaviciute, Indre, 1990-, et al.
(författare)
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Negative piezoelectric effect in an organic supramolecular ferroelectric
- 2019
-
Ingår i: Materials Horizons. - : Royal Society of Chemistry. - 2051-6347 .- 2051-6355. ; 6, s. 1688-1698
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Tidskriftsartikel (refereegranskat)abstract
- The vast majority of ferroelectric materials demonstrate a positive piezoelectric effect. Theoretically, the negative piezoelectric coefficient d33 could be found in certain classes of ferroelectrics, yet in practice, the number of materials showing linear longitudinal contraction with increasing applied field (d33 < 0) is limited to few ferroelectric polymers. Here, we measure a pronounced negative piezoelectric effect in the family of organic ferroelectric small-molecular BTAs (trialkylbenzene-1,3,5-tricarboxamides), which can be tuned by mesogenic tail substitution and structural disorder. While the large- and small-signal strain in highly-ordered thin-film BTA capacitor devices are dominated by intrinsic contributions and originates from piezostriction, rising disorder introduces additional extrinsic factors that boost the large-signal d33 up to −20 pm V-ˆ’1 in short-tailed molecules. Interestingly, homologues with longer mesogenic tails show a large-signal electromechanical response that is dominated by the quadratic Maxwell strain with significant mechanical softening upon polarization switching, whereas the small-signal strain remains piezostrictive. Molecular dynamics and DFT calculations both predict a positive d33 for defect-free BTA stacks. Hence, the measured negative macroscopic d33 is attributed to the presence of structural defects that enable the dimensional effect to dominate the piezoelectric response of BTA thin films.
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| 3. |
- Urbanaviciute, Indre, et al.
(författare)
-
Negative piezoelectric effect in an organic supramolecular ferroelectric
- 2019
-
Ingår i: Materials Horizons. - : Royal Society of Chemistry (RSC). - 2051-6347 .- 2051-6355. ; 6:8, s. 1688-1698
-
Tidskriftsartikel (refereegranskat)abstract
- The vast majority of ferroelectric materials demonstrate a positive piezoelectric effect. Theoretically, the negative piezoelectric coefficient d(33) could be found in certain classes of ferroelectrics, yet in practice, the number of materials showing linear longitudinal contraction with increasing applied field (d(33) < 0) is limited to few ferroelectric polymers. Here, we measure a pronounced negative piezoelectric effect in the family of organic ferroelectric small-molecular BTAs (trialkylbenzene-1,3,5-tricarboxamides), which can be tuned by mesogenic tail substitution and structural disorder. While the large- and small-signal strain in highly-ordered thin-film BTA capacitor devices are dominated by intrinsic contributions and originates from piezostriction, rising disorder introduces additional extrinsic factors that boost the large-signal d(33) up to -20 pm V-1 in short-tailed molecules. Interestingly, homologues with longer mesogenic tails show a large-signal electromechanical response that is dominated by the quadratic Maxwell strain with significant mechanical softening upon polarization switching, whereas the small-signal strain remains piezostrictive. Molecular dynamics and DFT calculations both predict a positive d(33) for defect-free BTA stacks. Hence, the measured negative macroscopic d(33) is attributed to the presence of structural defects that enable the dimensional effect to dominate the piezoelectric response of BTA thin films.
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