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- Augusto Berrocal, Jose, et al.
(författare)
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Consequences of conformational flexibility in hydrogen-bond-driven self-assembly processes
- 2016
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Ingår i: Chemical Communications. - : ROYAL SOC CHEMISTRY. - 1359-7345 .- 1364-548X. ; 52:72, s. 10870-10873
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Tidskriftsartikel (refereegranskat)abstract
- We report the synthesis and self-assembly of chiral, conformationally flexible C-3-symmetrical trisamides. A strong Cotton effect is observed for the supramolecular polymers in linear alkanes but not in cyclic alkanes. MD simulations suggest 2:1 conformations of the amides within the aggregates in both types of solvents, but a chiral bias in only linear alkanes.
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