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Search: WFRF:(Bechstein R.) > (2010-2014)

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1.
  • Su, R., et al. (author)
  • How the Anatase-to-Rutile Ratio Influences the Photoreactivity of TiO2
  • 2011
  • In: Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 115:49, s. 24287-24292
  • Journal article (peer-reviewed)abstract
    • In 1991, Bickley et al. proposed a synergetic effect between anatase and rutile in Degussa P25. Since then, there has been an intensive debate about the correctness of this proposal, the origin of the synergism, and the right polymorph composition. However, a comparison of pure titanium dioxide samples with various anatase-to-rutile ratios, but otherwise identical properties, is missing. In this paper, we report about a series of utterly pure, highly porous titanium dioxide films with identical grain sizes, surface areas, and crystallinity, but varying polymorph compositions. Photocatalytic oxidation of methylene blue was utilized to investigate the influence of the anatase-to-rutile ratio on the photoreactivity. We clearly observe the synergetic effect within a well-defined range of anatase-to-rutile ratios. A film with similar to 60% anatase and similar to 40% rutile exhibits optimal performance at a 50% improved activity compared with pure anatase.
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2.
  • Su, R., et al. (author)
  • Rapid Synthesis of Porous, Mixed Phase Titania Films with Tailored Orientation of Rutile for Enhanced Photocatalytic Performance
  • 2013
  • In: Journal of Physical Chemistry C. - : American Chemical Society (ACS). - 1932-7447 .- 1932-7455. ; 117:51, s. 27039-27046
  • Journal article (peer-reviewed)abstract
    • We report on a new, one-step electrochemical oxidation method for the rapid synthesis of mixed phase, polycrystalline TiO2 porous films with oriented rutile within a few minutes. The orientation as well as the surface chemical composition of rutile nanocrystallites can readily be tuned by adjusting the additive concentrations of HCl or HF in the electrolyte during synthesis. All TiO2 films show similar large specific surface area, which is ideal for the application of photocatalysis and photoelectrocatalysis. Compared to the random-oriented TiO2 film, films with an increasing portion of exposed rutile (101) facets were found to be characterized by enhanced photocatalytic oxidation and photoelectrochemical performances. We also observed a synergistic promotion effect of the orientation and surface F impurity. Most interesting, our tailor-oriented porous TiO2 films prepared using HF as additive show an impressive photocurrent generation at zero bias, which is similar to 50 times higher compared to that of the random-oriented TiO2 film.
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  • Result 1-4 of 4

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