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- Bajaj, Ashima, et al.
(författare)
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Anomalous Effect of Quantum Interference in Organic Spin Filters
- 2020
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Ingår i: The Journal of Physical Chemistry C. - : AMER CHEMICAL SOC. - 1932-7447 .- 1932-7455. ; 124:44, s. 24361-24371
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Tidskriftsartikel (refereegranskat)abstract
- The molecular topology in the single-molecule nanojunctions through which the de Broglie wave propagates plays a crucial role in controlling the molecular conductance. The enhancement and reduction of the conductance in para- and meta-connected molecules due to constructive and destructive quantum interference (QI), respectively, are quite well established. Herein, we investigated the effect of localized spin centers on spin transportation using organic radicals as molecular junctions. The role of the localized spins on the QI as well as on spin filtering capability is investigated employing density functional theory in combination with nonequilibrium Green's function (NEGF-DFT) techniques. Various organic radicals including nitroxy (NO center dot), phenoxy (PO center dot), and methyl (CH2 center dot) attached to the central benzene ring of pentacene with different terminal connections (para and meta) to gold electrodes are examined. Due to more obvious QI effects, para-connected pentacene is found to be more conductive than the meta one. Surprisingly, on incorporating a radical center, along with spin filtering, a significant reversal of QI effects is observed which manifests itself in such a way that the conductance of meta-coupled radicals is found to be more than para-coupled ones by 2 orders of magnitude. The anomaly in QI patterns induced by the radical center is analyzed and discussed in terms of orbital and structural perspectives.
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| 2. |
- Ciuciulkaite, Agne, MSc, 1991-, et al.
(författare)
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Magnetic and all-optical switching properties of amorphous TbxCo100-x alloys
- 2020
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Ingår i: Physical Review Materials. - : American Physical Society (APS). - 2475-9953. ; 4:10
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Tidskriftsartikel (refereegranskat)abstract
- Amorphous TbxCo100-x magnetic alloys exhibit a list of intriguing properties, such as perpendicular magnetic anisotropy, high magneto-optical activity, and magnetization switching using ultrashort optical pulses. Varying the Tb:Co ratio in these alloys allows for tuning properties such as the saturation magnetic moment, coercive field, and the performance of light-induced magnetization switching. In this paper, we investigate the magnetic, optical, and magneto-optical properties of various TbxCo100-x thin-film alloy compositions. We report on the effect the choice of different seeding layers has on the structural and magnetic properties of TbxCo100-x layers. We also demonstrate that for a range of alloys, deposited on fused silica substrates, with Tb content of 24-30 at. %, helicity-dependent all-optical switching of magnetization can be achieved, albeit in a multishot framework. We explain this property to arise from the helicity-dependent laser-induced magnetization on the Co sublattice due to the inverse Faraday effect. Our paper provides an insight into material aspects for future potential hybrid magnetoplasmonic TbCo-based architectures.
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