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- Shu, Rui, 1990-, et al.
(författare)
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Effect of nitrogen content on microstructure and corrosion resistance of sputter-deposited multicomponent (TiNbZrTa)Nx films
- 2020
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Ingår i: Surface & Coatings Technology. - LAUSANNE, SWITZERLAND : Elsevier BV. - 0257-8972 .- 1879-3347. ; 404
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Tidskriftsartikel (refereegranskat)abstract
- Multicomponent (TiNbZrTa)Nx films were deposited on Si(100) substrates at room temperature using magnetron sputtering with a nitrogen flow ratio fN [fN = N2/(Ar + N2)], which was varied from 0 to 30.8%. The nitrogen content in the films varied between 0 and 45.2 at.%, i.e., x = 0 to 0.83. The microstructure was characterized by X-ray diffraction and electron microscopy. The metallic TiNbZrTa film comprised a dominant bcc solid-solution phase, whereas a single NaCl-type face-centred cubic structure was observed in all nitrogen-containing films (TiNbZrTa)Nx. The mechanical, electrical, and electrochemical properties of these films varied with nitrogen content. The maximum hardness was achieved at 22.1 ± 0.3 GPa when N = 43.0 at.%. The resistivities increased from 95 to 424 μΩcm with increasing nitrogen content. A detailed study of the variation of morphology and chemical bonding with nitrogen content was performed and the corrosion resistance of the TiNbZrTa nitride films was explored in 0.1 M H2SO4. While all the films had excellent corrosion resistances at potentials up to 2.0 V vs. Ag/AgCl, the metallic film and the films with low nitrogen contents (x < 0.60) exhibited an almost stable current plateau up to 4.0 V vs. Ag/AgCl. For the films with higher nitrogen contents (x ≥ 0.68), the current plateau was retained up to 2.0 V vs. Ag/AgCl, above which a higher nitrogen content resulted in a higher current. The decrease in the corrosion resistance at these high potentials indicate the presence of a potential-dependent activation effect resulting in an increased oxidation rate of the nitrides (present under the passive oxide film) yielding a release of nitrogen from the films. TEM results indicate that the oxide layer formed after this corrosion measurement was thick and porous for the film with x = 0.76, in very good agreement with the increased corrosion rate for this film. The results demonstrate that an increased nitrogen content in (TiNbZrTa)Nx system improves their mechanical properties with retained high corrosion resistance at potentials up to 2.0 V vs. Ag/AgCl in 0.1 M H2SO4. At even higher potentials, however, the corrosion resistance decreases with increasing nitrogen concentration for films with sufficiently high nitrogen contents (i.e. x ≥ 0.68).
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| 2. |
- Xu, Jinghao, et al.
(författare)
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On the strengthening and embrittlement mechanisms of an additively manufactured Nickel-base superalloy
- 2020
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Ingår i: Materialia. - : Elsevier BV. - 2589-1529. ; 10
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Tidskriftsartikel (refereegranskat)abstract
- The γ′ phase strengthened Nickel-base superalloy is one of the most significant dual-phase alloy systems for high-temperature engineering applications. The tensile properties of laser powder-bed-fused IN738LC superalloy in the as-built state have been shown to have both good strength and ductility compared with its post-thermal treated state. A microstructural hierarchy composed of weak texture, sub-micron cellular structures and dislocation cellular walls was promoted in the as-built sample. After post-thermal treatment, the secondary phase γ′ precipitated with various size and fraction depending on heat treatment process. For room-temperature tensile tests, the dominated deformation mechanism is planar slip of dislocations in the as-built sample while dislocations bypassing the precipitates via Orowan looping in the γ′ strengthened samples. The extraordinary strengthening effect due to the dislocation substructure in the as-built sample provides an addition of 372 MPa in yield strength. The results of our calculation are in agreement with experimental yield strength for all the three different conditions investigated. Strikingly, the γ′ strengthened samples have higher work hardening rate than as-built sample but encounter premature failure. Experimental evidence shows that the embrittlement mechanism in the γ′ strengthened samples is caused by the high dislocation hardening of the grain interior region, which reduces the ability to accommodate further plastic strain and leads to premature intergranular cracking. On the basis of these results, the strengthening micromechanism and double-edge effect of strength and ductility of Nickel-base superalloy is discussed in detail.
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