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- Dubrovinskaia, N., et al.
(författare)
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Beating the miscibility barrier between iron group elements and magnesium by high-pressure alloying
- 2005
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Ingår i: Physical Review Letters. - : American Physical Society. - 0031-9007 .- 1079-7114. ; 95:24
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Tidskriftsartikel (refereegranskat)abstract
- Iron and magnesium are almost immiscible at ambient pressure. The low solubility of Mg in Fe is due to a very large size mismatch between the alloy components. However, the compressibility of Mg is much higher than that of Fe, and therefore the difference in atomic sizes between elements decreases dramatically with pressure. Based on the predictions of ab initio calculations, we demonstrate in a series of experiments in a multianvil apparatus and in electrically and laser-heated diamond anvil cells that high pressure promotes solubility of magnesium in iron. At the megabar pressure range, more than 10 at. % of Mg can dissolve in Fe and then the alloy can be quenched to ambient conditions. A generality of the concept of high-pressure alloying between immiscible elements is demonstrated by its application to two other Fe group elements, Co and Ni.
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- Dubrovinskaia, N., et al.
(författare)
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Compressibility of boron-doped diamond
- 2006
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Ingår i: High Pressure Research. - : Informa UK Limited. - 0895-7959 .- 1477-2299. ; 26, No. 2, s. 79-85
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Tidskriftsartikel (refereegranskat)
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- Dubrovinsky, L., et al.
(författare)
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Noblest of all metals is structurally unstable at high pressure
- 2007
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Ingår i: Physical Review Letters. - : American Physical Society. - 0031-9007 .- 1079-7114. ; 98:4
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Tidskriftsartikel (refereegranskat)abstract
- In a series of experiments in externally electrically heated diamond anvil cells we demonstrate that at pressures above similar to 240 GPa gold adopts a hexagonal-close-packed structure. Ab initio calculations predict that at pressures about 250 GPa different stacking sequences of close-packed atomic layers in gold become virtually degenerate in energy, strongly supporting the experimental observations.
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