| 1. |
- Kehoe, Laura, et al.
(författare)
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Make EU trade with Brazil sustainable
- 2019
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Ingår i: Science. - : American Association for the Advancement of Science (AAAS). - 0036-8075 .- 1095-9203. ; 364:6438, s. 341-
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Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)
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| 3. |
- Kaur-Kahlon, G., et al.
(författare)
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Response of a coastal tropical pelagic microbial community to changed salinity and temperature
- 2016
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Ingår i: Aquatic Microbial Ecology. - 0948-3055 .- 1616-1564. ; 77:1, s. 37-50
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Tidskriftsartikel (refereegranskat)abstract
- Studies on the responses of tropical microbial communities to changing hydrographic conditions are presently poorly represented. We present here the results from a mesocosm experiment conducted in southwest (SW) coastal India to investigate how changes in temperature and salinity may affect a coastal tropic microbial community. The onset of algal and bacterial blooms, the maximum production and biomass, and the interrelation between phytoplankton and bacteria were studied in replicated mesocosms. The treatments were set up featuring ambient conditions (28 °C, 35 PSU), hyposalinity (31 PSU), warming (31 °C) and a double manipulated treatment with warming and hyposalinity (31 °C, 31 PSU). The hyposaline treatment had the most considerable influence manifested as significantly lower primary production, and the most dissimilar microphytoplankton species community. The increased temperature acted as a catalyst in the double manipulated treatment and higher primary production was maintained. We investigated the dynamics of the microbial community with a structural equation model approach, and found a significant interrelation between phytoplankton biomass and bacterial abundance. Using this methodology, it became evident that temperature and salinity changes, individually and together, mediate direct and indirect effects that influence different compartments of the microbial loop. In the face of climate change, we suggest that in relatively nutrient replete tropical coastal zones, salinity and temperature changes will affect nutrient assimilation with subsequent significant effects on the quantity of microbial biomass and production.
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| 26. |
- Sanchez-Fernandez, A., et al.
(författare)
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Self-assembly and surface behaviour of pure and mixed zwitterionic amphiphiles in a deep eutectic solvent
- 2018
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Ingår i: Soft Matter. - : Royal Society of Chemistry (RSC). - 1744-683X .- 1744-6848. ; 14:26, s. 5525-5536
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Tidskriftsartikel (refereegranskat)abstract
- Recent investigations have shown that deep eutectic solvents provide a suitable environment for self-organisation of biomolecules, in particular phospholipids and proteins. However, the solvation of complex lyophilic moieties by deep eutectic solvents still remains unclear. Here we explore the behaviour of zwitterionic surfactants in choline chloride:glycerol eutectic mixture. Dodecyl-2-(trimethylammonio)ethylphosphate and N-alkyl-N,N-dimethyl-3-ammonio-1-propanesulfonate (alkyl = dodecyl, tetradecyl) surfactants were investigated by means of surface tension, X-ray reflectivity and small-angle neutron scattering. These surfactants were found to remain surface active and form globular micelles in deep eutectic solvents. Still, the surface behaviour of these species was found to differ depending on the headgroup and tail structure. The morphology of the micelles also slightly varies between surfactants, demonstrating differences in the packing of individual monomers. The characteristics of mixtures of the dodecyl surfactants is also reported, showing a deviation from ideal mixing associated with attractive interactions between sulfobetaine and phosphocholine headgroups. Such non-ideality results in variation of the surface behaviour and self-assembly of these surfactant mixtures. The results presented here will potentially lead to the development of new alternatives for drug-delivery, protein solubilisation and biosensing through a better fundamental understanding of the behaviour of zwitterionic surfactants in deep eutectic solvents.
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| 27. |
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| 28. |
- Kaur-Kahlon, Gurpreet, et al.
(författare)
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Response of a coastal tropical pelagic microbial community to changed salinity and temperature
- 2016
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Ingår i: Aquatic Microbial Ecology. - : Inter-Research Science Center. - 0948-3055 .- 1616-1564. ; 77:1, s. 37-50
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Tidskriftsartikel (refereegranskat)abstract
- Studies on the responses of tropical microbial communities to changing hydrographic conditions are poorly represented. We present here the results from a mesocosm experiment conducted in coastal southwestern India to investigate how changes in temperature and salinity may affect a coastal tropical microbial community. The onset of algal and bacterial blooms, maximum production and biomass, and the interrelationship between phytoplankton and bacteria were studied in replicated mesocosms. The treatments were set up to feature ambient conditions (28°C, 35 PSU), hyposalinity (31 PSU), warming (31°C), and a double manipulation treatment with warming and hyposalinity (31°C, 31 PSU). The hyposaline treatment had the most considerable influence, manifested as significantly lower primary production, and the most dissimilar microphytoplankton species community. The increased temperature acted as a catalyst in the double manipulation treatment, and higher primary production was maintained. We investigated the dynamics of the microbial community with a structural equation model and found a significant interrelationship between phytoplankton biomass and bacterial abundance. Using this methodology, it became evident that temperature and salinity changes, individually and together, mediate direct and indirect effects that influence different compartments of the microbial loop. In the face of climate change, we suggest that in relatively nutrient-replete tropical coastal zones, salinity and temperature changes will affect nutrient assimilation, with subsequent significant effects on the quantity of microbial biomass and production.
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| 29. |
- Kumar, S., et al.
(författare)
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Nitrogen uptake potential under different temperature-salinity conditions: Implications for nitrogen cycling under climate change scenarios
- 2018
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Ingår i: Marine Environmental Research. - : Elsevier BV. - 0141-1136 .- 1879-0291. ; 141:October, s. 196-204
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Tidskriftsartikel (refereegranskat)abstract
- As projected by climate change models, increase in sea surface temperature and precipitation in the future may alter nutrient cycling in the coastal regions due to potential changes in phytoplankton community structure and their ability to assimilate nitrogen (N) and carbon (C). An experiment simulating different temperature and salinity conditions (28 degrees C-35 ambient conditions, 28 degrees C-31, 31 degrees C-35 and 31 degrees C-31) in mesocosms containing 1000 L of coastal water from the Arabian Sea was performed and N uptake rates were measured using N-15 tracer technique on 2nd, 5th, 7th and 10th day of the experiment. The results show that, under all conditions, the total N (NO3- + NH4+) uptake rates were lower in the beginning and on the final day of the tracer experiment, while it peaked during middle, consistent with chlorophyll a concentrations. Total N uptake rate was significantly lower (p = 0.003) under ambient temperature -lower salinity condition (28 degrees C-31) than the others. This indicates that lowering of salinity in coastal regions due to excessive rainfall in the future may affect the N uptake potential of the phytoplankton, which may change the regional C and N budget.
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| 30. |
- López-alled, Carlos M., et al.
(författare)
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Azulene–boronate esters: colorimetric indicators for fluoride in drinking water
- 2017
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Ingår i: Chemical Communications. - 1359-7345. ; 53:93, s. 12580-12583
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Tidskriftsartikel (refereegranskat)abstract
- Low cost andin situfluoride detection by non-experts is importantfor the determination of drinking water safety in developing countries.Colour reagents can provide results quickly without expensiveequipment, but colorimetric fluoride indicators are often non-specific, complex to use or do not work in water. Here we showthat azulene–boronate indicators respond selectively to fluoride atconcentrations relevant to the WHO limit of 1.5 mg L1.
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| 31. |
- Mezheyeuski, A, et al.
(författare)
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Image analysis-derived metrics of histomorphological complexity predicts prognosis and treatment response in stage II-III colon cancer
- 2016
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Ingår i: Scientific reports. - : Springer Science and Business Media LLC. - 2045-2322. ; 6, s. 36149-
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Tidskriftsartikel (refereegranskat)abstract
- The complexity of tumor histomorphology reflects underlying tumor biology impacting on natural course and response to treatment. This study presents a method of computer-aided analysis of tissue sections, relying on multifractal (MF) analyses, of cytokeratin-stained tumor sections which quantitatively evaluates of the morphological complexity of the tumor-stroma interface. This approach was applied to colon cancer collection, from an adjuvant treatment randomized study. Metrics obtained with the method acted as independent markers for natural course of the disease, and for benefit of adjuvant treatment. Comparative analyses demonstrated that MF metrics out-performed standard histomorphological features such as tumor grade, budding and configuration of invasive front. Notably, the MF analyses-derived “αmax” –metric constitutes the first response-predictive biomarker in stage II-III colon cancer showing significant interactions with treatment in analyses using a randomized trial-derived study population. Based on these results the method appears as an attractive and easy-to-implement tool for biomarker identification.
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| 32. |
- Sanchez-fernandez, Adrian, et al.
(författare)
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Micellization of alkyltrimethylammonium bromide surfactants in choline chloride:glycerol deep eutectic solvent
- 2016
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Ingår i: Physical Chemistry Chemical Physics. - 1463-9076. ; 18:48, s. 33240-33249
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Tidskriftsartikel (refereegranskat)abstract
- Deep eutectic solvents have shown the ability to promote the self-assembly of surfactants in solution. However, some differences have been found compared with self-assembly in pure water and other polar organic solvents. The behaviour of alkyltrimethylammonium bromides in choline chloride:glycerol deep eutectic solvent has been studied by means of surface tension, X-ray and neutron reflectivity and small-angle neutron scattering. The surfactants were found to remain surface active and showed comparable critical micelle concentrations to the same surfactants in water. Our scattering studies demonstrate that these surfactants form globular micelles with ellipsoidal shape in solution. The size, shape and aggregation number of the aggregates were found to vary with the chain length of the surfactant. Specific solvent-headgroup interactions were not found in this system, unlike those we have previously postulated for anionic surfactants in choline chloride deep eutectic solvents.
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| 33. |
- Schmitt, Julien, et al.
(författare)
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TEMPO-oxidised cellulose nanofibrils; Probing the mechanisms of gelation : Via small angle X-ray scattering
- 2018
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Ingår i: Physical Chemistry Chemical Physics. - : Royal Society of Chemistry (RSC). - 1463-9076 .- 1463-9084. ; 20:23, s. 16012-16020
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Tidskriftsartikel (refereegranskat)abstract
- The structure of dispersions of TEMPO-oxidised cellulose nanofibrils (OCNF), at various concentrations, in water and in NaCl aqueous solutions, was probed using small angle X-ray scattering (SAXS). OCNF are modelled as rod-like particles with an elliptical cross-section of 10 nm and a length greater than 100 nm. As OCNF concentration increases above 1.5 wt%, repulsive interactions between fibrils are evidenced, modelled by the interaction parameter νRPA > 0. This corresponds to gel-like behaviour, where G′ > G′′ and the storage modulus, G′, shows weak frequency dependence. Hydrogels can also be formed at OCNF concentration of 1 wt% in 0.1 M NaCl(aq). SAXS patterns shows an increase of the intensity at low angle that is modelled by attractive interactions (νRPA < 0) between OCNF, arising from the screening of the surface charge of the fibrils. Results are supported by ζ potential and cryo-TEM measurements.
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