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- De Spiegeleer, Alexandre, 1990-
(författare)
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There and back again... An Earth magneto-tale : understanding plasma flows in the magnetotail
- 2020
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- On average, the Earth's magnetotail plasma sheet seems to be a calm region of the magnetosphere where the plasma moves slowly towards Earth. However, the plasma sheet actually hosts many phenomena, some of which can affect Earth. For example, high-speed flows of plasma with speed larger than 400 km/s are observed in the plasma sheet and they can lead to aurorae. Such dynamical phenomena and the impact they may have on Earth naturally makes the plasma sheet an important region of study. Even though these high-speed flows can affect Earth, they are observed less than 5% of the time, meaning that most of the time, other disturbances take place in the plasma sheet. Our aim is to investigate and better understand the plasma dynamics in the plasma sheet.The plasma above and below the cross-tail current sheet was previously thought to convect in the same direction. However, we find that under clearly non-zero Interplanetary Magnetic Field (IMF)By (dawn-dusk component), the plasma has a tendency to convect in opposite dawn-dusk direction across the current sheet near the midnight sector depending on the sign of IMF By.The high-speed plasma flows are known to be associated with an increase of the northward component of the magnetic field as they propagate toward Earth. Using simulations, we notice that the magnetic field lines are bent by the high-speed flows and dents can appear. The deformation of the magnetic field is such that it may be directed towards the tail above the cross-tail current sheet and towards the Earth below it. This is opposite to the expected orientation of the magnetic field thus making this feature important in order to properly identify the region in which a spacecraft is located.At times, the plasma can be seen to move back and forth in an oscillatory manner. We investigate statistically such oscillatory behaviour and compare them to high-speed flows and to time periods when the plasma is calm. These oscillatory flows are observed about 8% of the time in the plasma sheet. They typically have a frequency of about 1.7 mHz (~10 min period) and usually last about 41 min.Some oscillations of the plasma velocity are observed along the magnetic field. The particles measured by the satellite initially have a velocity parallel to the magnetic field and towards Earth. Gradually with time, the measured velocity of the particles turns around to first become more perpendicular to the magnetic field and then be along the magnetic field but away from Earth. These signatures are interpreted simply as being due to mirroring particles injected tailward of the satellite and move toward Earth. The particles are then reflected, and move away from Earth. We investigate the general features of such oscillations along the magnetic field and find that the source of the particles is typically located less than 25 RE (Earth's radii) tailward of the satellite.
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| 2. |
- Garcia-Quintana, Laura, et al.
(författare)
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Stabilisation of the superoxide anion in bis(fluorosulfonyl)imide (FSI) ionic liquid by small chain length phosphonium cations: Voltammetric, DFT modelling and spectroscopic perspectives
- 2021
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Ingår i: Electrochemistry Communications. - : Elsevier BV. - 1388-2481. ; 127
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Tidskriftsartikel (refereegranskat)abstract
- Ionic liquids (ILs) containing the bis(fluorosulfonyl)imide anion, FSI, have been investigated as electrolytes for metal-air batteries. Full chemical reversibility is found for the reduction of oxygen to superoxide at 60 degrees C under short time scale conditions of cyclic voltammetry at a glassy carbon electrode when the IL contains the small chain length triisobutyl(methyl)phosphonium rather than a pyrrolidinium cation. DFT calculations suggest that this is a consequence of the higher ion pair association energy and shorter intermolecular distance associated with the interaction of the superoxide anion with the phosphonium cation. Stabilization on longer timescales was also established by spectroscopic techniques when the phosphonium based ILs were exposed to KO2. Studies on superoxide stability in related ionic liquids containing the triisobutyl(methyl)phosphonium cation with the fluorosulfonyl(trifluoromethanesulfonyl)imide, FTFSI, or bis(trifluoromethanesulfonyl)imide, TFSI, anions are also reported.Y
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| 3. |
- Makhlooghiazad, Faezeh, et al.
(författare)
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Electrolytes for sodium batteries
- 2021
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Ingår i: Na-ion Batteries. - : Wiley. ; , s. 205-241
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Bokkapitel (övrigt vetenskapligt/konstnärligt)abstract
- This chapter presents an overview of different liquid and solid electrolytes employed for sodium batteries. It covers the basics in more depth and discusses the current status of ionic liquid (IL)-based electrolytes. The chapter outlines the challenges that remain to be solved to enable the realization of sodium batteries based on such electrolytes. Organic liquid electrolytes for sodium batteries typically consist of one or more sodium salts dissolved in one or more organic solvents. Organic ionic plastic crystals, the solid-state analogues of ILs, are emerging solid-state electrolytes that have advantageous properties, similar to ILs. ILs-based electrolytes present some unique properties that endows significant safety enhancements in comparison with conventional organic solvents, mostly related to higher decomposition temperatures. The IL-based electrolytes must also show an economic viability in comparison with conventional organic liquid electrolytes.
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| 4. |
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| 5. |
- Wang, Guang, et al.
(författare)
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Evolution of structural dimensions in mesoporous template precursor from hexagonal lyotropic liquid crystals
- 2020
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Ingår i: Journal of Physics. - : Institute of Physics (IOP). - 0953-8984 .- 1361-648X. ; 32:7
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Tidskriftsartikel (refereegranskat)abstract
- Producing nanopores from hexagonal lyotropic liquid crystals (LLCs) templates requires not only retaining phase morphology of the templates but also precisely controlling structural dimensions of unit cells. In this study, SAXS and H-2 NMR are used to investigate dimensional evolutions of ternary systems consisting of polymerizable species, (ethylene glycol) diacrylate (PEGDA) and/or 2-hydroxyethyl methacrylate (HEMA), in a LLCs template of hexagonally packed cylinders formed from dodecyl trimethylammonium bromide (DTAB) and water. With the addition of those polymerizable species, the system rearranges into a new hexagonal system with a smaller aggregation number, smaller pores and a thicker pore wall thickness. The hexagonal system will coexist with an aqueous-rich phase containing isotropically distributed DTAB if sufficient PEGDA is applied but the single hexagonal system could be restored by partially replacing the PEGDA with HEMA. The mobility of DTAB molecules within the aggregates varies depending on monomer compositions. The changes in structural dimensions of the unit cells and phase behaviors after adding polymerizable monomers allow dimensional control of mesochannels and potentially enable the control of selectivity and robustness of polymerized nanomaterials via molecular design.
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| 6. |
- Zhang, Heng, et al.
(författare)
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From Solid-Solution Electrodes and the Rocking-Chair Concept to Today's Batteries
- 2020
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Ingår i: Angewandte Chemie - International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 59:2, s. 534-538
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Tidskriftsartikel (refereegranskat)abstract
- Lithium-ion batteries (LIBs) have become ubiquitous power sources for small electronic devices, electric vehicles, and stationary energy storage systems. Despite the success of LIBs which is acknowledged by their increasing commodity market, the historical evolution of the chemistry behind the LIB technologies is laden with obstacles and yet to be unambiguously documented. This Viewpoint outlines chronologically the most essential findings related to today's LIBs, including commercial electrode and electrolyte materials, but furthermore also depicts how the today popular and widely emerging solid-state batteries were instrumental at very early stages in the development of LIBs.
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