| 1. |
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| 2. |
- Shameer, S., et al.
(författare)
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TrypanoCyc: a community-led biochemical pathways database for Trypanosoma brucei
- 2015
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Ingår i: Nucleic Acids Research. - : Oxford University Press (OUP). - 0305-1048 .- 1362-4962. ; 43:D1, s. D637-D644
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Tidskriftsartikel (refereegranskat)abstract
- The metabolic network of a cell represents thecatabolic and anabolic reactions that interconvertsmall molecules (metabolites) through the activity ofenzymes, transporters and non-catalyzed chemicalreactions. Our understanding of individual metabolicnetworks is increasing as we learn more aboutthe enzymes that are active in particular cells underparticular conditions and as technologies advanceto allow detailed measurements of the cellularmetabolome. Metabolic network databases areof increasing importance in allowing us to contextualisedata sets emerging from transcriptomic,proteomic and metabolomic experiments. Here wepresent a dynamic database, TrypanoCyc (http://www.metexplore.fr/trypanocyc/), which describesthe generic and condition-specific metabolic networkof Trypanosoma brucei, a parasitic protozoan responsiblefor human and animal African trypanosomiasis.In addition to enabling navigation through the BioCyc-based TrypanoCyc interface, we have alsoimplemented a network-based representation of theinformation through MetExplore, yielding a novel environmentin which to visualise the metabolism ofthis important parasite.
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| 3. |
- Merle, Renaud, 1976-, et al.
(författare)
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Mt Bambouto Volcano, Cameroon Line : Mantle Source and Differentiation of Within-plate Alkaline Rocks
- 2017
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Ingår i: Journal of Petrology. - : Oxford University Press (OUP). - 0022-3530 .- 1460-2415. ; 58:5, s. 933-962
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Tidskriftsartikel (refereegranskat)abstract
- The Late Cretaceous–Quaternary Cameroon Volcanic Line (CVL) is a 1600 km long chain of volcanoes that straddles the continent–ocean boundary and extends from the Gulf of Guinea to the interior of the African continent. The magmatic activity started at 70 Ma and has continued until the present. The products of this magmatic activity are distinctive in terms of petrology and isotope geochemistry, the variety of volcanic rocks ranging from ultrabasic, alkaline to sub-alkaline lavas to highly evolved alkaline lavas with isotopic compositions indicating complex combinations of both sub-lithospheric (HIMU, EM, DMM) and lithospheric components (sub-continental lithospheric mantle and crust). We conducted a petrological and geochemical study of a set of volcanic rocks, sampled from the rim and interior of the Miocene Mt Bambouto caldera, one of the 12 main volcanic centres of the CVL. The rocks were analysed for their whole-rock major and trace element contents, 40Ar/39Ar ages and whole-rock Sr–Nd–Pb–Os isotopic compositions. Phonolites and quartz-trachytes of the Mt Bambouto caldera are derived by fractional crystallization of highly alkaline and moderately alkaline parental basic magmas, respectively. Assimilation of the shallow crust has affected both alkaline and subalkaline magmas, suggesting that the petrogenesis of the differentiated rocks cannot be explained by crustal contamination alone. Only minor amounts (usually less than 5%) of assimilation of upper crustal silicic rocks from the local Pan-African basement are required to produce the most differentiated compositions. The rocks with the highest crustal contribution are Q-normative trachytes from peripheral cones, as well as one Ne-trachyte. Mt Bambouto basic–ultrabasic rocks, including basanites and alkali-basalts with high 187Os/188Osi, might have experienced some crustal contamination, but it must have been a limited process. Some Mt Bambouto ultrabasic to basic rocks show large ion lithophile element enrichment, notably of Sr, Ba and P compared with Zr. These samples also have relatively radiogenic Sr and unradiogenic Pb isotopic compositions. Such compositions are similar to those of the high-Sr group identified by previous studies. Most of the basic rocks do not show such characteristics and are identified as a low-Sr group. We interpret the geochemical characteristics of the high-Sr group as resulting from the partial melting of a depleted mantle (DMM-like) peridotite source containing pyroxenite veins that had interacted with carbonatitic fluids. To test this hypothesis, we used a new modelling approach based on Monte Carlo simulation; this method has the advantage of deciphering how different mantle components interacted through time. Our modelling confirms the plausibility of a three-component source. In addition, it suggests that the carbonatitic fluid first mixed with the pyroxenititic component and the resulting melt interacted with a DMM-like mantle. Both high-Sr and low-Sr groups can be produced by such a mixing scenario but with a stronger contribution of the carbonatitic fluid for the high-Sr group. At the time of melting, these source components could have been located in a metasomatized region of the sublithospheric mantle (uppermost section of the asthenosphere) or in the sub-continental lithospheric mantle.
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| 4. |
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| 5. |
- Oostingh, K. F., et al.
(författare)
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Spatio-temporal Geochemical Evolution of the SE Australian Upper Mantle Deciphered from the Sr, Nd and Pb Isotope Compositions of Cenozoic Intraplate Volcanic Rocks
- 2016
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Ingår i: Journal of Petrology. - : Oxford University Press (OUP). - 0022-3530 .- 1460-2415. ; 57:8, s. 1509-1530
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Tidskriftsartikel (refereegranskat)abstract
- Intraplate basaltic volcanic rocks ranging in age from Late Cretaceous to Holocene are distributed across southeastern Australia in Victoria and eastern South Australia. They comprise four provinces differentiated on the basis of age and spatial distribution. The youngest of these (<4·6 Ma) is the Newer Volcanic Province (NVP), which incorporates lava flows, scoria cones and maars, distributed across western and central Victoria into South Australia. The oldest eruptive rocks belong to the 95–19 Ma Older Volcanic Province, which comprises basaltic lava flows and shallow intrusions distributed across eastern and central Victoria. When examined within the broader framework of geochemical data available for Cretaceous to Cenozoic intraplate volcanism in southeastern Australia, new major, minor and trace element and Sr, Nd and Pb isotope analyses of volcanic rocks from the NVP suggest that their parental magmas originated from a distinctively different mantle source compared with that of the Older Volcanics. We propose that the magmas represented by the Older Volcanics originated from low degrees of partial melting of a mixed source of Indian mid-ocean ridge basalt (MORB)-source mantle and calcio-carbonatite metasomatized sub-continental lithospheric mantle (SCLM), followed by up to 20% fractional crystallization. The magmas of the youngest (<500 ka) suite of the NVP (the Newer Cones) were generated by up to 13% partial melting of a garnet-rich source, followed by similar degrees of fractional crystallization. We also suggest that the temporally intermediate Euroa Volcanics (∼7 Ma) reflect chemical evolution from the source of the Older Volcanics to that of the Newer Cones. Furthermore, energy-constrained recharge, assimilation and fractional crystallization (EC-RA x FC) modelling suggests that the Sr isotope signature of the ∼4·6–1 Ma Newer Plains component of the NVP can be explained by up to 5% upper crustal assimilation. On the basis of these results and data from the literature for mantle xenoliths, we propose a geodynamic model involving decompression melting of metasomatized veins at the base of the SCLM generating the Older Volcanics and modifying the ambient asthenosphere of Indian MORB isotope character. This was followed by thermal erosion and entrainment of the resulting depleted SCLM into the modified Indian MORB-source asthenospheric mantle, generating the Newer Cones. Such a model is in agreement with recent geophysical observations in the area suggesting edge-driven convection with shear-driven upwelling as a potential geodynamic model resulting in temporal upwelling in the region.
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| 6. |
- Holm-Alwmark, S., et al.
(författare)
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An Early Jurassic age for the Puchezh-Katunki impact structure (Russia) based on 40Ar/39Ar data and palynology
- 2019
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Ingår i: Meteoritics and Planetary Science. - : Wiley. - 1086-9379 .- 1945-5100. ; 54:8, s. 1764-1780
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Tidskriftsartikel (refereegranskat)abstract
- The Puchezh-Katunki impact structure, 40–80 km in diameter, located ~400 km northeast of Moscow (Russia), has a poorly constrained age between ~164 and 203 Ma (most commonly quoted as 167 ± 3 Ma). Due to its relatively large size, the Puchezh-Katunki structure has been a prime candidate for discussions on the link between hypervelocity impacts and extinction events. Here, we present new 40Ar/39Ar data from step-heating analysis of five impact melt rock samples that allow us to significantly improve the age range for the formation of the Puchezh-Katunki impact structure to 192–196 Ma. Our results also show that there is not necessarily a simple relationship between the observed petrographic features of an impact melt rock sample and the obtained 40Ar/39Ar age spectra and inverse isochrons. Furthermore, a new palynological investigation of the postimpact crater lake sediments supports an age significantly older than quoted in the literature, i.e., in the interval late Sinemurian to early Pliensbachian, in accordance with the new radioisotopic age estimate presented here. The new age range of the structure is currently the most reliable age estimate of the Puchezh-Katunki impact event.
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| 7. |
- Marzoli, Andrea, et al.
(författare)
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The Central Atlantic Magmatic Province (CAMP) in Morocco
- 2019
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Ingår i: Journal of Petrology. - : Oxford University Press (OUP). - 0022-3530 .- 1460-2415. ; 60:5, s. 945-996
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Tidskriftsartikel (refereegranskat)abstract
- The Central Atlantic Magmatic Province (CAMP) is a large igneous province (LIP) composed of basic dykes, sills, layered intrusions and lava flows emplaced before Pangea break-up and currently distributed on the four continents surrounding the Atlantic Ocean. One of the oldest, best preserved and most complete sub-provinces of the CAMP is located in Morocco. Geochemical, geochronologic, petrographic and magnetostratigraphic data obtained in previous studies allowed identification of four strato-chemical magmatic units, i.e. the Lower, Intermediate, Upper and Recurrent units. For this study, we completed a detailed sampling of the CAMP in Morocco, from the Anti Atlas in the south to the Meseta in the north. We provide a complete mineralogical, petrologic (major and trace elements on whole-rocks and minerals), geochronologic (40Ar/39Ar and U–Pb ages) and geochemical set of data (including Sr–Nd–Pb–Os isotope systematics) for basaltic and basaltic–andesitic lava flow piles and for their presumed feeder dykes and sills. Combined with field observations, these data suggest a very rapid (<0·3 Ma) emplacement of over 95% of the preserved magmatic rocks. In particular, new and previously published data for the Lower to Upper unit samples yielded indistinguishable 40Ar/39Ar (mean age = 201·2 ± 0·8 Ma) and U–Pb ages (201·57 ± 0·04 Ma), suggesting emplacement coincident with the main phase of the end-Triassic biotic turnover (c.201·5 to 201·3 Ma). Eruptions are suggested to have been pulsed with rates in excess of 10 km3/year during five main volcanic pulses, each pulse possibly lasting only a few centuries. Such high eruption rates reinforce the likelihood that CAMP magmatism triggered the end-Triassic climate change and mass extinction. Only the Recurrent unit may have been younger but by no more than 1 Ma. Whole-rock and mineral geochemistry constrain the petrogenesis of the CAMP basalts. The Moroccan magmas evolved in mid-crustal reservoirs (7–20 km deep) where most of the differentiation occurred. However, a previous stage of crystallization probably occurred at even greater depths. The four units cannot be linked by closed-system fractional crystallization processes, but require distinct parental magmas and/or distinct crustal assimilation processes. EC-AFC modeling shows that limited crustal assimilation (maximum c.5–8% assimilation of e.g. Eburnean or Pan-African granites) could explain some, but not all the observed geochemical variations. Intermediate unit magmas are apparently the most contaminated and may have been derived from parental magmas similar to the Upper basalts (as attested by indistinguishable trace element contents in the augites analysed for these units). Chemical differences between Central High Atlas and Middle Atlas samples in the Intermediate unit could be explained by distinct crustal contaminants (lower crustal rocks or Pan-African granites for the former and Eburnean granites for the latter). The CAMP units in Morocco are likely derived from 5–10% melting of enriched peridotite sources. The differences observed in REE ratios for the four units are attributed to variations in both source mineralogy and melting degree. In particular, the Lower basalts require a garnet peridotite source, while the Upper basalts were probably formed from a shallower melting region straddling the garnet–spinel transition. Recurrent basalts instead are relatively shallow-level melts generated mainly from spinel peridotites. Sr–Nd–Pb–Os isotopic ratios in the CAMP units from Morocco are similar to those of other CAMP sub-provinces and suggest a significant enrichment of the mantle-source regions by subducted crustal components. The enriched signature is attributed to involvement of about 5–10% recycled crustal materials introduced into an ambient depleted or PREMA-type mantle, while involvement of mantle-plume components like those sampled by present-day Central Atlantic Ocean Island Basalts (OIB, e.g. Cape Verde and Canary Islands) is not supported by the observed compositions. Only Recurrent basalts may possibly reflect a Central Atlantic plume-like signature similar to the Common or FOZO components.
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| 8. |
- Merle, Renaud E., 1976-, et al.
(författare)
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Geochronology of the Tore-Madeira Rise seamounts and surrounding areas : a review
- 2018
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Ingår i: Australian Journal of Earth Sciences. - : Taylor & Francis. - 0812-0099 .- 1440-0952. ; 65:5, s. 591-605
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Tidskriftsartikel (refereegranskat)abstract
- We present new 40Ar/39Ar data for two of the Tore-Madeira Rise (TMR) volcanic seamounts. A sample from Tore East seamount on the northern part of the TMR yielded an ultra-precise age of 80.50 ± 0.13 Ma (2σ) that is similar within uncertainties to a published age obtained by U–Pb TIMS technique on titanites and zircons extracted from Tore NW seamount. Another sample from Isabelle seamount, located on the southern part of the TMR failed to produce a plateau age but yielded a minimum age estimate of >85 Ma. We filtered the published ages available on the TMR, the surrounding seamounts and the massifs of southwest Portugal to better understand the origin of this magmatic province. Together with this dataset, our new data suggest that: (1) a hypothetical Madeira hot-spot track spanning from Serra de Monchique on the continent to Madeira Archipelago is difficult to reconcile with the occurrence of several seamounts geographically located within or very close to this alleged hot-spot track yet being much older than the age predicted by the age trend. (2) The geographical distribution and age pattern of the TMR and surrounding areas magmatism are still best explained by the interaction of a mantle melting anomaly emitting magma pulses and the different motion phases of the Iberia plate since 103 Ma.
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| 9. |
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| 10. |
- Seifert, T., et al.
(författare)
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Efficient metallic spintronic emitters of ultrabroadband terahertz radiation
- 2016
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Ingår i: Nature Photonics. - 1749-4885 .- 1749-4893. ; 10:7, s. 483-
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Tidskriftsartikel (refereegranskat)abstract
- Terahertz electromagnetic radiation is extremely useful for numerous applications, including imaging and spectroscopy. It is thus highly desirable to have an efficient table-top emitter covering the 1-30 THz window that is driven by a low-cost, low-power femtosecond laser oscillator. So far, all solid-state emitters solely exploit physics related to the electron charge and deliver emission spectra with substantial gaps. Here, we take advantage of the electron spin to realize a conceptually new terahertz source that relies on three tailored fundamental spintronic and photonic phenomena in magnetic metal multilayers: ultrafast photoinduced spin currents, the inverse spin-Hall effect and a broadband Fabry-Perot resonance. Guided by an analytical model, this spintronic route offers unique possibilities for systematic optimization. We find that a 5.8-nm-thick W/CoFeB/Pt trilayer generates ultrashort pulses fully covering the 1-30 THz range. Our novel source outperforms laser-oscillator-driven emitters such as ZnTe(110) crystals in terms of bandwidth, terahertz field amplitude, flexibility, scalability and cost.
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