2. |
- Ruiz, J. A., et al.
(författare)
-
Autoionisation of superexcited states in N-2 to the N2+B state
- 2003
-
Ingår i: Chemical Physics Letters. - : Elsevier BV. - 0009-2614 .- 1873-4448. ; 372:02-jan, s. 139-146
-
Tidskriftsartikel (refereegranskat)abstract
- Vibrationally resolved N-2(+) (B-X) (1-2) and (0-1) emission bands were recorded after photoexcitation of N-2 in the 20-46 eV energy range. The branching ratio between these transitions reveals strong non-Franck-Condon effects. Ab initio calculations using a configuration interaction method based on Kohn-Sham orbitals indicate that the autoionisation of certain superexcited states is responsible for some structures present in the branching ratio curve.
|
|