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Use of ionic liquid...
Use of ionic liquids in the pretreatment of forest and agricultural residues for the production of bioethanol
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- Pezoa, R. (author)
- Institute for Cell Dynamics and Biotechnology (ICDB), Department of Chemical Engineering and Biotechnology, University of Chile, Santiago, Chile
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- Cortinez, V. (author)
- Institute for Cell Dynamics and Biotechnology (ICDB), Department of Chemical Engineering and Biotechnology, University of Chile, Santiago, Chile
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- Hyvärinen, S. (author)
- Laboratory of Industrial Chemistry and Reaction Engineering, Process Chemistry Centre, Åbo Akademi University, Turku, Finland
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- Reunanen, M. (author)
- Wood and Paper Chemistry, Åbo Akademi University, Turku, Finland
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- Hemming, J. (author)
- Wood and Paper Chemistry, Åbo Akademi University, Turku, Finland
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- Lienqueo, M. E. (author)
- Institute for Cell Dynamics and Biotechnology (ICDB), Department of Chemical Engineering and Biotechnology, University of Chile, Santiago, Chile
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- Salazar, O. (author)
- Institute for Cell Dynamics and Biotechnology (ICDB), Department of Chemical Engineering and Biotechnology, University of Chile, Santiago, Chile
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- Carmona, R. (author)
- Department of Wood Engineering, Faculty of Forest Sciences, University of Chile, Chile
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- Garcia, A. (author)
- Vice Presidency of Research and Development, University of Chile, Chile
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- Murzin, D. YU. (author)
- Laboratory of Industrial Chemistry and Reaction Engineering, Process Chemistry Centre, Åbo Akademi University, Turku, Finland
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- Mikkola, Jyri-Pekka (author)
- Umeå universitet,Kemiska institutionen,Laboratory of Industrial Chemistry and Reaction Engineering, Process Chemistry Centre, Åbo Akademi University, Turku, Finland
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(creator_code:org_t)
- Publishing House of the Romanian Academy, 2010
- 2010
- English.
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In: Cellulose Chemistry and Technology. - : Publishing House of the Romanian Academy. - 0576-9787. ; 44:4-6, s. 165-172
- Related links:
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http://www.cellulose...
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https://urn.kb.se/re...
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Abstract
Subject headings
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- Pretreatment of lignocellulosic materials is an important step to achieve higher amounts of simple sugars, mono- and disaccharides, for obtaining ethanol as a biofuel, via enzymatic hydrolysis. The study introduces a concept that utilizes ionic liquids (ILs) as solvents in the pretreatment step, before enzymatic saccharification, for both forest residues (Eucalyptus (Eucalyptus globulus Labill.) and Lenga (Nothofagus pumilio (POEPP. EX. ENDL.) KRASSER) and for agricultural residues (wheat and corn). The procedure was evaluated at four different temperatures (80, 121, 150 and 170 °C) for 30 and 60 min, respectively, with 1-ethyl-3-methylimidazolium chloride ([EMIM+][Cl-]). Subsequent enzymatic hydrolysis of these materials was carried out at 47 °C, for 72 h, with commercial cellulases. The results demonstrated that the best experimental conditions found for wheat, corn and Eucalyptus residues were the following: 150 °C, for 60 min, yielding a total of 46, 48 and 30% sugars, respectively; in the case of Lenga residues, the optimum conditions were: 150 °C for 30 min, yielding a total of 40% sugars after saccharification. Temperatures exceeding 170 °C are not recommended for this type of pretreatment with [EMIM+][Cl-], because significant portions of cellulose could be dissolved in this IL. Finally, an analysis of the solid material after ionic liquid pretreatment is required, to determine the changes related to lignin, cellulose and hemicellulose composition.
Subject headings
- NATURVETENSKAP -- Biologi -- Biokemi och molekylärbiologi (hsv//swe)
- NATURAL SCIENCES -- Biological Sciences -- Biochemistry and Molecular Biology (hsv//eng)
Keyword
- bioethanol
- pretreatment
- ionic liquids
- forest and agricultural residues
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Pezoa, R.
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Cortinez, V.
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Hyvärinen, S.
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Reunanen, M.
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Hemming, J.
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Lienqueo, M. E.
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show more...
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Salazar, O.
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Carmona, R.
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Garcia, A.
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Murzin, D. YU.
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Mikkola, Jyri-Pe ...
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Biological Scien ...
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and Biochemistry and ...
- Articles in the publication
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Cellulose Chemis ...
- By the university
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Umeå University