| 1. |
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| 2. |
- Engkvist, Josefin, 1972, et al.
(författare)
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Oxidation of FeCrAl foils at 500-900 degrees C in dry O-2 and O-2 with 40% H2O
- 2009
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Ingår i: Materials at High Temperatures. - 0960-3409 .- 1878-6413. ; 26:2, s. 199-210
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Tidskriftsartikel (refereegranskat)abstract
- High temperature resistant FeCrAl alloys are frequently used in high temperature applications Such as heating elements and metal based catalytic converter bodies. When exposed to high temperatures an adherent, slowly growing, dense aluminium oxide layer forms on the surface, which protects the underlying alloy from severe degradation. The composition, structure and properties of the formed oxide layer are strongly dependent on the alloy composition, temperature and oxidation environment. In this study, the Sandvik 0C404 FeCrAl alloy, in the form of 50 mu m thick foils, was exposed isothermally in the temperature range 500-900 degrees C for 168 hours in dry O-2 and in O-2 with 40 vol.% H2O. The surface morphology, composition and microstructure of the grown oxide scales were characterized by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), grazing incidence X-ray diffraction (GI-XRD), Auger electron spectroscopy (AES), and time of flight secondary ion mass spectrometry (TOF-SIMS). The oxidation process was faster at 900 degrees C than at 500 and 700 degrees C. At 500 degrees C a thin (10-20 nm) mixed oxide of Fe, Cr and Al was formed. Exposure at 700 degrees C resulted ill a similar (40-50 nm) duplex oxide, in both dry O-2 and in O-2 With 40 vol.% H2O. These oxide scales consisted of all inner and an outer relatively pure alumina separated by a Cr-rich band. This type of duplex oxide scale also formed at 900 degrees C with a thin inward growing alpha-Al2O3 at the oxide/metal interface and an outward growing layer outside a Cr-rich band. However, at 900 degrees C the Outward growing layer showed two types of oxide morphologies; a thin smooth base oxide and a much thicker nodular oxide grown on top of substrate ridges. In dry O-2 atmosphere, the main part of this outward growing layer had transformed to alpha-Al2O3. Only in the outer part of the thick oxide nodules, metastable alumina was found. When exposed in the presence of water vapour the main pall of the metastable alumina remained untransformed.
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| 3. |
- Götlind, Helena, 1978, et al.
(författare)
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The effect of water vapor on the initial stages of oxidation of the FeCrAl alloy Kanthal AF at 900 degrees C
- 2007
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Ingår i: Oxidation of Metals. - 1573-4889 .- 0030-770X. ; , s. 251-266
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Tidskriftsartikel (refereegranskat)abstract
- The effect of water vapor on the initial stages of oxidation of the FeCrAl alloy Kanthal AF is reported. Polished samples were exposed isothermally at 900 degrees C for 1, 24, 72 and 168 h in a well-controlled environment consisting of dry O-2 or O-2 + 40% H2O. The samples were investigated using a combination of gravimetry and several surface-analytical techniques, including XRD, SEM, EDX, FIB, AES and TEM. The presence of water vapor significantly accelerates oxidation during the first 72 h. A two-layered oxide forms in both the dry and wet environments. The bottom layer consists of inward-growing alpha-Al2O3 while the outer layer initially consists of outward-growing gamma-Al2O3. A straight and narrow Cr-enriched band is present at the top of the lower (alpha-Al2O3) oxide, corresponding to the original sample surface. In dry O-2, the top (gamma-Al2O3) layer is converted into a mixture of gamma-Al2-x (Mg,Fe) (x) O-3-(x/2),O- MgAl2O4 and alpha-Al2O3. This transformation does not occur in O-2 + H2O. The initial acceleration of oxidation by H2O is attributed to the stabilization of the outward-growing gamma-alumina layer by the hydroxylation of the gamma-Al2O3 surface. A schematic mechanism of the early stages of oxidation of FeCrAl alloys is presented, emphasizing the influence of water vapor.
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| 4. |
- Heyman, Jakob, 1979-, et al.
(författare)
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A paleoglaciological reconstruction for Bayan Har Shan, NE Tibetan Plateau
- 2009
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Konferensbidrag (refereegranskat)abstract
- The paleoglaciology of the Tibetan Plateau has remained elusive because extensive areas still lack detailed scrutiny. We here present a paleoglaciological reconstruction for the Bayan Har Shan region, NE Tibetan Plateau, which could serve as a working model to investigate other poorly investigated regions. The reconstruction is primarily based on three methods for revealing the glacial history; 1) remote sensing (geomorphology), 2) field studies (stratigraphy), and 3) numerical dating techniques. Remote sensing (SRTM elevation data, Landsat ETM+ satellite imagery and Google Earth) of a 136 500 km2 area reveals an abundance of glacial landforms in the highest mountain areas and an absence of glacial landforms on intervening plateau surfaces. Stratigraphical data collected during three field seasons supplement the picture emerging from remote sensing. Glacial deposits (including erratic boulders and till) occur in the elevated mountain areas but are absent on the intervening plateau areas. Marginal moraines in central Bayan Har can be grouped to represent at least three separate glacial extents and scattered observations of glacial deposits indicate the presence of a fourth (and maximum) glacial extent. To tie the glacial geological record to a chronology we have employed terrestrial cosmogenic nuclide (TCN) exposure and optically stimulated luminescence (OSL) dating. Beryllium apparent exposure ages of 65 glacial boulders, surface cobbles/pebbles and depth profile samples yield minimum ages for the three youngest glacial extents of 40-65 ka, 60-100 ka, and 95-165 ka (with the wide age ranges due to TCN dating uncertainties). A preliminary OSL age of c. 160 ka from glacial sediments of the oldest of these glacial extents supports our interpretation based on TCN dating. The glacial extent presented here is more restricted than most previous reconstructions, most notably with very restricted glaciers over at least the last 40-65 ka. These results indicate that while continental-scale ice sheets evolved and disappeared in North America and Eurasia over the last half of the last glacial cycle, the NE corner of the Tibetan Plateau experienced relatively minor glacial fluctuations.
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| 5. |
- Heyman, Jakob, 1979-, et al.
(författare)
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An evaluation of multiple working hypotheses to explain cosmogenic exposure age data from glacial deposits in the Bayan Har Shan, NE Tibetan Plateau
- 2009
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Ingår i: Proceedings.
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Konferensbidrag (refereegranskat)abstract
- Many questions remain unanswered regarding the Quaternary glaciations of the Tibetan Plateau. We have used terrestrial cosmogenic nuclide (TCN) exposure age dating of glacial deposits to examine the style, extent, and timing of past glaciations of the Bayan Har Shan, a mountain region on the northeastern Tibetan Plateau. This area lies within a transition zone between the dry interior of the Tibetan Plateau and the wetter eastern margin affected by the Asian monsoon. Bayan Har Shan has many glacial landforms and deposits that provide evidence for former glaciation ranging from cirque and valley glaciers to ice-fields and ice caps.In an attempt to constrain the timing of glaciations in Bayan Har Shan, we have performed TCN exposure dating on 65 samples in central Bayan Har Shan from glacial deposits. boulders (39 samples), on surface pebbles/cobbles (12 samples), and on pebbles in sediment depth profiles (14 samples from four profiles) allow us to examine the timing and extent of glaciations in this area. As is often the case, there are some challenges in interpreting the range of TCN apparent exposure ages that is found in data from several samples and sample types on a single deposit and from samples taken at various sites. Thus we evaluate multiple working hypotheses to explain apparent exposure ages on glacial deposits, which in this case range from 3 ka to 129 ka. We consider three different hypotheses; 1) some samples have erroneously old exposure ages due to inheritance, 2) samples have been preserved under cold-based, non-erosive ice, and 3) samples have experienced only post-glacial shielding. Only when we adopt a hypothesis that assumes no prior exposure, and thus that maximum apparent exposure ages constrain the minimum age of formation of a feature (working hypotheses 3), do we find broad consistency between apparent exposure ages from different sample types (erratic boulders, surface pebbles/cobbles and pebbles from depth profiles). This leads to the conclusion that all of the sites of former glaciations we examined are at least 50ka in age, and that there has been no large-scale expansion of glaciers in the central Bayan Har Shan over the last 50ka.
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| 6. |
- Heyman, Jakob, et al.
(författare)
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Landscape evolution of the northeastern Tibetan plateau - relict surfaces and fluvial margins
- 2007
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Ingår i: Geophysical Research Abstracts.
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Konferensbidrag (refereegranskat)abstract
- The actively uplifting Tibetan plateau has a profound impact on climate and displays a landscape marked by geomorphological action. This is because the uplift is counteracted by intense fluvial incision of some of the world’s largest rivers and their tributaries that drain the plateau. Glaciers and glacial landforms occur predominantly in and around the highest elevation areas. By investigating the imprints of glacial and fluvial erosion we can enhance our understanding of the long-term landscape evolution, as well as illuminate the paleoglaciology of the Tibetan plateau. We here present an investigation of the large-scale geomorphology of the northeastern Tibetan plateau and its implication for landscape evolution and paleoenvironmental reconstructions.The northeastern part of the Tibetan plateau is characterized by a plateau surface at c. 4300 m asl with higher mountain groups reaching up to 1500 m above the surrounding plateau surface. We used SRTM 90 m digital elevation model, satellite images and Google Earth imagery to map the large-scale geomorphology for an area of c. 135.000 km2 centered around the Bayan Har mountains. Our mapping reveals a clear pattern of substantial glacial erosion on the highest, central parts of the mountain areas and decreasing amounts of glacial erosion with decreasing elevation and increasing distance away from these centers of glaciation. Beyond the areas of glacial erosion, there is a low-relief fluvial landscape that typifies the rest of the plateau surface. The plateau margins are formed by steep fluvial valleys which cut backwards into the gentle sloping relict plateau surface. Thus, the overall landscape may be divided into three classes; (i) glacially eroded surfaces in the highest areas, (ii) a relict, low-relief plateau surface, and (iii) a steep, fluvial landscape juxtaposing the former two classes.The distribution of the different landscapes indicates the following temporal evolution of the landscape. The glacial landforms indicate a repeated glaciation of the mountain areas. The steep fluvial valleys consuming the relict plateau surface represent an ongoing adjustment of the river channels to the actively uplifting plateau margin. The pattern of abandoned fluvial erosion of the northern part of the study area supports the notion of a stepwise uplift. This is because progressively younger uplift of the northern parts of the area induced a piracy of originally N-flowing rivers to currently ESE-flowing rivers along major faults (such as we infer for the Huang He river). It is noteworthy that the outline of the relict landscape, that is the pronounced break in slope between the low-relief relict landscape and the young fluvial landscape, coincides almost completely with the outline of a hypothesized former ice sheet, the Huang He ice sheet. We have not been able to confirm the presence of geomorphology or stratigraphy that would support this reconstruction. If true, however, our notion of outline conformance could indicate that the Huang He ice sheet may actually have been larger than suggested and that glacial traces are being consumed by the fluvial incision triggered by plateau uplift.
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| 7. |
- Heyman, Jakob, 1979-, et al.
(författare)
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Palaeoglaciation of Bayan Har Shan, northeastern Tibetan Plateau: glacial geology indicates maximum extents limited to ice cap and ice field scales
- 2009
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Ingår i: Journal of Quaternary Science. - : John Wiley & Sons. - 0267-8179 .- 1099-1417. ; 24:7, s. 710-727
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Tidskriftsartikel (refereegranskat)abstract
- Key locations within an extensive area of the northeastern Tibetan Plateau, centred on Bayan Har Shan, have been mapped to distinguish glacial from non-glacial deposits. Prior work suggests palaeo-glaciers ranging from valley glaciers and local ice caps in the highest mountains to a regional or even plateau-scale ice sheet. New field data show that glacial deposits are abundant in high mountain areas in association with large-scale glacial landforms. In addition, glacial deposits are present in several locations outside areas with distinct glacial erosional landforms, indicating that the most extensive palaeo-glaciers had little geomorphological impact on the landscape towards their margins. The glacial geological record does indicate extensive maximum glaciation, with local ice caps covering entire elevated mountain areas. However, absence of glacial traces in intervening lower-lying plateau areas suggests that local ice caps did not merge to form a regional ice sheet on the northeastern Tibetan Plateau around Bayan Har Shan. No evidence exists for past ice sheet glaciation.
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| 8. |
- Josefsson, Helena, 1978, et al.
(författare)
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Oxidation of FeCrAl alloys at 500-900 degrees C in dry O-2
- 2005
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Ingår i: MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION 56 (11): 801-805 NOV 2005. - 0947-5117. ; 56(11), s. 801-805
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Tidskriftsartikel (refereegranskat)abstract
- This paper reports on the oxidation of a commercial FeCrAl alloy, Kanthal AF, in the temperature range 500-900 degrees C. The samples are exposed isothermally in dry oxygen for up to 72 h using a thermo-balance. In addition, 168 h exposures are carried out in a tube furnace. The exposed samples are investigated by grazing angle Xray diffraction (XRD), scanning electron microscopy/energy dispersive X-ray analysis (SEM/EDX), and auger electron spectroscopy (AES). The rate of oxidation increases with temperature, the kinetics being parabolic in the range 700-900 degrees C. At all exposure temperatures, most of the sample surface is covered by a thin smooth base oxide. In addition, RE-rich particles, with a typical size of 1-3 mu m form. At 800 and 900 degrees C patches of thick oxide appear, featuring needle-formed crystallites situated on top of the base oxide. The thick oxide usually forms around Y-rich oxide particles. The concentration of iron and chromium in the oxide decreases with increasing temperature. XRD proves the formation of alpha-Al2O3 already at 700 degrees C, The low temperature of formation of alpha-Al2O3 is attributed to the presence of chromium in the initial oxide. It is proposed that corundum nucleation is facilitated on a surface consisting of the isostructural escolaite, (Cr2O3). After exposure at 900 degrees C AES shows large amounts of Mg in the outer part of the oxide, MgAl2O4 being detected by XRD together with gamma- and alpha-Al2O3.
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| 9. |
- Josefsson, Helena, 1978, et al.
(författare)
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The Formation of Oxide Scale on FeCrAl at 900°C in dry O2 and O2 + 40% H2O
- 2005
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Ingår i: 206th ECS Meeting; Honolulu, HI; United States; 3 October 2004 through 8 October 2004. ; PV 2004-16, s. 56-66
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Konferensbidrag (refereegranskat)abstract
- Polished Kanthal AF samples were oxidized isothermally at 900°C in O2 and in O2+40% H2O for between 1 and 168 hours. The samples were analysed gravimetrically, by Grazing-Incidence X-ray diffraction, Scanning Electron Microscopy, Energy Dispersive X-ray analysis and Auger Electron Spectroscopy profiling. Much of the surface is covered by a thin and smooth base oxide with Mg-rich nodules on top. In addition, patches of thick uneven oxide and RE-oxide protrusions are present on the surface. Exposure to O2+40% H2O results in significantly higher initial oxidation rate than dry O2. The presence of water vapour also influences oxide morphology. The thick oxide patches exhibit needle-like crystals in dry O2 while rounded oxide agglomerates dominate in O2/H2O. The chemical composition of the oxide was the same in O2 and in O2+40% H2O. α-Al 2O3, γ-Al2O3 and MgAl 2O4 form in both environments.
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| 10. |
- Liu, Fang, 1975, et al.
(författare)
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Cyclic oxidation of two FeCrAlRE foils at 1100 oC - The influence of the concentration of minor alloying elements on scale microstructure
- 2008
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Ingår i: Materials Science Forum. - 1662-9752 .- 0255-5476. ; 595-598, s. 707-716
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Konferensbidrag (refereegranskat)abstract
- Two FeCrAlRE alloys, a commercial, 0C404, and a model alloy in the form of thin foils,with different Mn, Nb, Mo and Ti concentrations were subjected to cyclic oxidation in lab air at1100°C. The oxidized samples were studied by gravimetry, Grazing-Incidence X-ray Diffraction(GI-XRD), Scanning Transmission Electron Microscopy (STEM), and Energy Dispersive X-ray(EDX) analysis. The two FeCrAl alloys exhibit different oxidation kinetics; however, both alloyshave the same weight gain after 500 hours exposure. During the early stages the scale consistsmainly of α-Al2O3 together with some oxide particles containing Mn, Al, Fe and Cr formed on thealloys. After 500 hours the 0C404 scale locally also consists of larger polycrystalline regions ofMn-Cr-Al spinel. In addition, Si-rich oxide, chromia and Al-Cr oxide could be observed at themetal/oxide interface.
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| 11. |
- Liu, Fang, 1975, et al.
(författare)
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Early stages of the oxidation of a FeCrAlRE alloy (Kanthal AF) at 900 °C: A detailed microstructural investigation
- 2008
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Ingår i: Corrosion Science. - : Elsevier BV. - 0010-938X. ; 50:8, s. 2272-2281
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Tidskriftsartikel (refereegranskat)abstract
- Early stages of the evolution of Al2O3 scales formed on a FeCrAlRE alloy (Kanthal AF) have been investigatedby analytical TEM. The samples were oxidized isothermally at 900 °C in dry O2 or O2 + 40% H2O for1 h or 24 h. All oxide scales exhibited a two-layered structure, with a continuous inward growing a-Al2O3inner layer and an outward growing outer layer. After 1 h, the outer oxide layer consisted of c-Al2O3 inboth environments. After 24 h exposure in dry O2, the c-Al2O3 in the outer oxide layer was partly transformedto a-Al2O3 and spinel oxide (Mg1-xFexAl2O4). In contrast, the c-Al2O3 in the outer layer was nottransformed after 24 h in O2 + 40% H2O, showing that water vapour stabilizes c-Al2O3. All oxide scalescontained a Cr-rich band, a product of the initial oxidation. The inner a-Al2O3 layer is suggested to nucleateon Cr2O3 or Cr2-xFexO3 in the initial oxide.
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| 12. |
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| 13. |
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| 14. |
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| 15. |
- Liu, Yanling
(författare)
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Electric DNA arrays for determination of pathogenic Bacillus cereus
- 2007
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Licentiatavhandling (övrigt vetenskapligt/konstnärligt)abstract
- Silicon-based electric chip arrays were developed for characterization of Bacillus cereus with respect to the capacity to produce toxins involved in food poisoning and foodborne infections. Bacteria of the B. cereus group contain different sets of four toxins encoded by eight genes. The purpose of this work was to develop a fast method for determination of the presence of these genes in colonies from primary enrichment cultures. The specific DNA detection was based on immobilization of DNA capture probes, which hybridize to specific sites on the target genes. Biotin-labeled detection probes were designed to hybridize with the target DNA adjacent to the capture probes. An extravidin - alkaline phosphatase complex was subsequently bound to the hybridized detection probes. Finally, p-aminophenyl phosphate was added as substrate for the enzyme, and the product p-aminophenol was brought in contact with the interdigitated gold electrode on the silicon chips surface. The p-aminophenol was oxidized at the anode to quinoneimine, which was then reduced back to paminophenol at the cathode. This redox recycling generates a current that was used as the DNA-chip response to the target DNA. Two versions of the assay were used. In the first version the capture probes were immobilized on magnetic beads and all chemical reactions until and including the enzymatic reaction took place in an eppendorf tube while the redox recycling was used to measure the amount of paminophenol produced after transfer from the tube to the silicon chip surface. In the second version a silicon chip array was used with 16 parallel electrode positions, each activated by immobilization of one type of capture probes on the gold electrodes. With this system all chemical reactions took place at the chip surface. The kinetics of cell disruption and DNA fragmentation from B. cereus by ultrasonication was determined. Maximum cell disruption was achieved within 5 min and the chip response increased in proportion to the ultrasonic time. Further ultrasonication up to 10 min resulted in further increasing current although no further cell disruption was observed. If the sonication time was extended above 10 min the signal declined. Based on analysis of the DNA size distribution by early end-point PCR and gel electrophoresis, it is suggested that the first 5 min ultrasonication increased the signal by increasing the release of target DNA molecules. Thereafter the signal was increased by fragmentation of target DNA which increases the diffusion rate and also the accessibility of the hybridization site. Finally, the DNA fragment sizes approached that of the hybridization site (51-bp) which may reduce the signal because of cleavage of the target DNA in the hybridization region. These studies were performed with the bead-based hybridization assay. The assay was highly specific to the target gene (hblC) of both B. cereus and B. thuringiensis with no response from negative control cells of B. subtilis. The 16 positions of the silicon chip array were activated by immobilization of all known toxin-coding genes of B. cereus and also included both a positive control and a negative control electrode positions. When these chips were exposed to ultrasonicated B. cereus, the gold electrodes were fouled by some component in DNA cell lysates. To circumvent this, the released large DNA was first extracted and then ultrasonicated again, since the extract mainly contains large molecular weight DNA. This DNA extract was applied to characterize one “diarrheal” and one “emetic” strain of B. cereus with the DNA chip arrays. The results agreed with PCR control analysis which means that these electric DNA chip arrays can be used to characterize bacterial colonies with respect to the genes coding of all known toxins of B. cereus: haemolysin (hblA, hblC, hblD), non-haemolytic enterotoxin (nheA, nheB, nheC), cytotoxin K-2 (cytK-2), and cereulide (ces). The chip assay required about 30 min after application of DNA samples. Due to the generic properties of the chips, this technique should also be applicable for characterization of the pathogenicity potential of many other organisms. Keywords: Bacillus cereus, haemolysin, non-haemolytic enterotoxin, cytotoxin K-2, cereulide, toxin-coding genes, bacterial colony, electric DNA chip, ultrasonication, DNA fragmentation.
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| 16. |
- Stroeven, Arjen, et al.
(författare)
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Landscape analysis of the Huang He headwaters, NE Tibetan Plateau — Patterns of glacial and fluvial erosion
- 2009
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Ingår i: Geomorphology. - : Elsevier. - 0169-555X .- 1872-695X. ; 103:2, s. 212-226
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Tidskriftsartikel (refereegranskat)abstract
- The large-scale geomorphology of the Huang He (Yellow River) headwaters, centered around the Bayan Har Shan (5267 m asl) in the northeastern part of the Tibetan Plateau, is dominated by an uplifted remnant of a low-relief relict plateau with several mountain ranges. We have performed geomorphological mapping using SRTM topographic data and Landsat 7 ETM+ satellite imagery to evaluate landscape characteristics and patterns, and to investigate the relative importance of different erosional processes in the dissection of this plateau remnant. The distribution of valley morphologies indicates that the eastern and southern margins of the plateau remnant have been extensively dissected by the Huang He and Chang Jiang (Yangtze) rivers and associated tributaries, while the mountain ranges have valley morphologies with U-shaped cross-sections that indicate large impacts from glacial erosion during Quaternary glaciations. An east-west decrease in the abundance of glacial valleys in mountains above 4800 m asl suggests that the diminishing size of the mountain blocks, coupled with increased continentality, resulted in more restricted glaciations to the west. Glacial valleys in mountain blocks on the plateau remnant are wider and deeper than adjacent fluvial valleys. This indicates that, integrated over time, the glacial system has been more effective in eroding the mountains of the relict upland surface than the fluvial system. This erosion relationship is reversed, however, on the plateau margin where dramatic fluvial rejuvenation in valleys that are part of the Huang He and Chang Jiang watersheds has consumed whatever glacial morphology existed. A remarkable correspondence exists between the outline of the relict plateau remnant and the outline that has been proposed for the Huang He Ice Sheet. This coincidence could mean that the Huang He Ice Sheet was larger than originally proposed, but that evidence for this has been consumed by fluvial incision at the plateau margin. Alternatively, this coincidence could indicate that what has been described as an ice sheet border is merely the outline of a relict plateau landscape. In apparent support of the latter, the absence of large-scale glacial geomorphological evidence on the plains of the relict plateau surface is not consistent with the hypothesis of a Huang He Ice Sheet.
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