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UV-induced dissociation of CH2BrI probed by intense femtosecond XUV pulses

Kockert, Hansjochen (author)
Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England.,University of Oxford
Lee, Jason W. L. (author)
Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England.;Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany.,University of Oxford,German Electron Synchrotron (DESY)
Allum, Felix (author)
Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England.,University of Oxford
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Amini, Kasra (author)
Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England.,University of Oxford
Bari, Sadia (author)
Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany.,German Electron Synchrotron (DESY)
Bomme, Cedric (author)
Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany.,German Electron Synchrotron (DESY)
Brausse, Felix (author)
Max Born Inst, D-12489 Berlin, Germany.,Max Born Institute for Nonlinear Optics and Short Pulse Spectroscopy
Brouard, Mark (author)
Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England.,University of Oxford
Burt, Michael (author)
Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England.,University of Oxford
de Miranda, Barbara Cunha (author)
Sorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, F-75005 Paris, France.,Paris-Sorbonne University
Duesterer, Stefan (author)
Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany.,German Electron Synchrotron (DESY)
Eng-Johnsson, Per (author)
Lund University,Lunds universitet,Lunds lasercentrum, LLC,Annan verksamhet, LTH,Lunds Tekniska Högskola,Atomfysik,Fysiska institutionen,Institutioner vid LTH,LTH profilområde: Avancerade ljuskällor,LTH profilområden,Lund Laser Centre, LLC,Other operations, LTH,Faculty of Engineering, LTH,Atomic Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH,LTH Profile Area: Photon Science and Technology,LTH Profile areas,Faculty of Engineering, LTH
Erk, Benjamin (author)
Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany.,German Electron Synchrotron (DESY)
Geleoc, Marie (author)
Univ Paris Saclay, CEA, CNRS, LIDYL, F-91191 Gif Sur Yvette, France.,University of Paris-Saclay
Geneaux, Romain (author)
Univ Paris Saclay, CEA, CNRS, LIDYL, F-91191 Gif Sur Yvette, France.,University of Paris-Saclay
Gentleman, Alexander S. (author)
Univ Oxford, Dept Chem, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England.,University of Oxford
Guillemin, Renaud (author)
Sorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, F-75005 Paris, France.,Paris-Sorbonne University
Goldsztejn, Gildas (author)
Max Born Inst, D-12489 Berlin, Germany.;Sorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, F-75005 Paris, France.,Max Born Institute for Nonlinear Optics and Short Pulse Spectroscopy,Paris-Sorbonne University
Holland, David M. P. (author)
Daresbury Lab, Warrington WA4 4AD, Cheshire, England.,Daresbury Laboratory
Ismail, Iyas (author)
Sorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, F-75005 Paris, France.,Paris-Sorbonne University
Journel, Loic (author)
Sorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, F-75005 Paris, France.,Paris-Sorbonne University
Kierspel, Thomas (author)
Deutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci, D-22607 Hamburg, Germany.;Univ Hamburg, Dept Phys, D-22761 Hamburg, Germany.,University of Hamburg
Kuepper, Jochen (author)
Deutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci, D-22607 Hamburg, Germany.;Univ Hamburg, Dept Phys, D-22761 Hamburg, Germany.;Univ Hamburg, Ctr Ultrafast Imaging, D-22761 Hamburg, Germany.;Univ Hamburg, Dept Chem, D-20146 Hamburg, Germany.,University of Hamburg
Lahl, Jan (author)
Lund University,Lunds universitet,Atomfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Atomic Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
Mackenzie, Stuart R. (author)
Univ Oxford, Dept Chem, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England.,University of Oxford
Maclot, Sylvain, 1986 (author)
Lund University,Lunds universitet,Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU),Lund Univ, Dept Phys, S-22100 Lund, Sweden.;Gothenburg Univ, Dept Phys, Box 100, S-40530 Gothenburg, Sweden.,Atomfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Atomic Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
Manschwetus, Bastian (author)
Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany.,German Electron Synchrotron (DESY)
Mereshchenko, Andrey S. (author)
St Petersburg State Univ, St Petersburg 199034, Russia.,Saint Petersburg State University
Mullins, Terence (author)
Deutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci, D-22607 Hamburg, Germany.;European XFEL, D-22869 Schenefeld, Germany.
Olshin, Pavel K. (author)
St Petersburg State Univ, St Petersburg 199034, Russia.,Saint Petersburg State University
Palaudoux, Jérôme (author)
Sorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, F-75005 Paris, France.,The French National Centre for Scientific Research (CNRS),Paris-Sorbonne University
Penent, Francis (author)
Sorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, F-75005 Paris, France.,Paris-Sorbonne University
Piancastelli, Maria Novella (author)
Uppsala University,Uppsala universitet,Kemisk och biomolekylär fysik,Sorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, F-75005 Paris, France.,Paris-Sorbonne University
Rompotis, Dimitrios (author)
Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany.;European XFEL, D-22869 Schenefeld, Germany.,German Electron Synchrotron (DESY),European XFEL GmbH
Rouzee, Arnaud (author)
Max Born Inst, D-12489 Berlin, Germany.,Max Born Institute for Nonlinear Optics and Short Pulse Spectroscopy
Ruchon, Thierry (author)
Univ Paris Saclay, CEA, CNRS, LIDYL, F-91191 Gif Sur Yvette, France.,University of Paris-Saclay
Rudenko, Artem (author)
Kansas State Univ, Dept Phys, JR Macdonald Lab, Manhattan, KS 66506 USA.,Kansas State University
Schirmel, Nora (author)
Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany.,German Electron Synchrotron (DESY)
Simon, Marc (author)
Sorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, F-75005 Paris, France.,Paris-Sorbonne University
Techert, Simone (author)
Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany.,German Electron Synchrotron (DESY)
Travnikova, Oksana (author)
Sorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, F-75005 Paris, France.,Paris-Sorbonne University
Trippel, Sebastian (author)
Deutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci, D-22607 Hamburg, Germany.;Univ Hamburg, Ctr Ultrafast Imaging, D-22761 Hamburg, Germany.,University of Hamburg
Vallance, Claire (author)
Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England.,University of Oxford
Wang, Enliang (author)
Kansas State Univ, Dept Phys, JR Macdonald Lab, Manhattan, KS 66506 USA.,Kansas State University
Wiese, Joss (author)
Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany.;Deutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci, D-22607 Hamburg, Germany.;Univ Hamburg, Dept Chem, D-20146 Hamburg, Germany.,University of Hamburg
Ziaee, Farzaneh (author)
Kansas State Univ, Dept Phys, JR Macdonald Lab, Manhattan, KS 66506 USA.,Kansas State University
Marchenko, Tatiana (author)
Sorbonne Univ, CNRS, Lab Chim Phys Matiere & Rayonnement, F-75005 Paris, France.,Paris-Sorbonne University
Rolles, Daniel (author)
Kansas State Univ, Dept Phys, JR Macdonald Lab, Manhattan, KS 66506 USA.,Kansas State University
Boll, Rebecca (author)
Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany.;European XFEL, D-22869 Schenefeld, Germany.,German Electron Synchrotron (DESY),European XFEL GmbH
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Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England University of Oxford (creator_code:org_t)
2022-02-11
2022
English.
In: JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 55:1
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • The ultraviolet (UV)-induced dissociation and photofragmentation of gas-phase CH2BrI molecules induced by intense femtosecond extreme ultraviolet (XUV) pulses at three different photon energies are studied by multi-mass ion imaging. Using a UV-pump-XUV-probe scheme, charge transfer between highly charged iodine ions and neutral CH2Br radicals produced by C-I bond cleavage is investigated. In earlier charge-transfer studies, the center of mass of the molecules was located along the axis of the bond cleaved by the pump pulse. In the present case of CH2BrI, this is not the case, thus inducing a rotation of the fragment. We discuss the influence of the rotation on the charge transfer process using a classical over-the-barrier model. Our modeling suggests that, despite the fact that the dissociation is slower due to the rotational excitation, the critical interatomic distance for charge transfer is reached faster. Furthermore, we suggest that charge transfer during molecular fragmentation may be modulated in a complex way.

Subject headings

NATURVETENSKAP  -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)

Keyword

free-electron lasers
charge transfer
ultrafast molecular dynamics
free-electron lasers

Publication and Content Type

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art (subject category)

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