| 1. |
- Andersson, Håkan, 1970-
(author)
-
A Co-Simulation Approach for Hydraulic Percussion Units
- 2018
-
Licentiate thesis (other academic/artistic)abstract
- This Licentiate of Engineering thesis concerns modelling and simulation of hydraulic percussion units. These units are often found in equipment for breaking or drilling in rock and concrete, and are also often driven by oil hydraulics, in which complex fluid-structure couplings are essential for their operation.Current methodologies used today when developing hydraulic percussion units are based on decoupled analyses, which are not correctly capturing the important coupled mechanisms. Hence, an efficient method for coupled simulations is of high importance, since these mechanisms are critical for the function of these units. Therefore, a co-simulation approach between a 1D system simulation model representing the fluid system and a structural 3D FE-model is proposed.This approach is presented in detail, implemented for two well-known simulation tools and evaluated for a simple but relevant model. The Hopsan simulation tool was used for the fluid system and the FE-simulation software LS-DYNA was used for the structural mechanics simulation. The co-simulation interface was implemented using the Functional Mock-up Interface-standard.The approach was further developed to also incorporate multiple components for coupled simulations. This was considered necessary when models for the real application are to be developed. The use of two components for co-simulation was successfully evaluated for two models, one using the simple rigid body representation, and a second where linear elastic representations of the structural material were implemented.An experimental validation of the co-simulation approach applied to an existing hydraulic hammer was performed. Experiments on the hydraulic hammer were performed using an in-house test rig, and responses were registered at four different running conditions. The co-simulation model was developed using the same approach as before. The corresponding running conditions were simulated and the responses were successfully validated against the experiments. A parameter study was also performed involving two design parameters with the objective to evaluate the effects of a parameter change.This thesis consists of two parts, where Part I gives an introduction to the application, the simulation method and the implementation, while Part II consists of three papers from this project.
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| 2. |
- Andersson, Håkan, et al.
(author)
-
A co-simulation method for system-level simulation of fluid-structure couplings in hydraulic percussion units
- 2017
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In: Engineering with Computers. - : SPRINGER. - 0177-0667 .- 1435-5663. ; 33:2, s. 317-333
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Journal article (peer-reviewed)abstract
- This paper addresses a co-simulation method for fluid power driven machinery equipment, i.e. oil hydraulic machinery. In these types of machinery, the fluid-structure interaction affects the end-product performance to a large extent, hence an efficient co-simulation method is of high importance. The proposed method is based on a 1D system model representing the fluid components of the hydraulic machinery, within which structural 3D Finite Element (FE) models can be incorporated for detailed simulation of specific sub-models or complete structural assemblies. This means that the fluid system simulation will get a more accurate structural response, and that the structural simulation will get more correct fluid loads at every time step, compared to decoupled analysis. Global system parameters such as fluid flow, performance and efficiency can be evaluated from the 1D system model simulation results. From the 3D FE-models, it is possible to evaluate displacements, stresses and strains to be used in stress analysis, fatigue evaluation, acoustic analysis, etc. The method has been implemented using two well-known simulation tools for fluid power system simulations and FE-simulations, respectively, where the interface between the tools is realised by use of the Functional Mock-up Interface standard. A simple but relevant model is used to validate the method.
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| 3. |
- Andersson, Håkan, 1970-, et al.
(author)
-
Simulation of wear in hydraulic percussion units using a co-simulation approach
- 2023
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In: International Journal of Modelling and Simulation. - : Taylor & Francis. - 0228-6203 .- 1925-7082. ; 43:3, s. 265-281
-
Journal article (peer-reviewed)abstract
- In this study, a developed co-simulation method, which couples 1D-fluid and 3D-structural models, has been utilised to simulate wear in a hydraulic percussion unit. The effect of wear is generally detrimental on performance and lifetime for such units, but can also cause catastrophic failure and breakdown, requiring a total overhaul and replacement of core components. One experiment of standard straight impact was performed to investigate the tolerance against seizure. The percussion unit was operated at successively increasing operating pressures, and the level of wear was registered at each step, until seizure occurred. The co-simulation model was used to replicate the running conditions from the experiment to simulate the structural response to be used as input for the wear routine to calculate the wear depth. The wear pattern from the simulations corresponds well to the wear pattern from the experiment. Further, the effect of a misaligned impact on wear development was also studied, as this is a loading situation that typically occurs for hydraulic percussion units. The study demonstrates that the simulation method used has a potential for simulating wear and predicting seizure in hydraulic percussion units.
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| 4. |
- Andersson, Håkan, 1970-, et al.
(author)
-
System level co-simulation of a control valve and hydraulic cylinder circuit in a hydraulic percussion unit
- 2017
-
In: Proceedings of 15:th Scandinavian International Conference on Fluid Power, June 7-9, 2017, Linköping, Sweden. - Linköping : Linköping University Electronic Press. - 9789176853696 ; , s. 225-235
-
Conference paper (peer-reviewed)abstract
- In this study a previously developed co-simulation method that is based on a 1D system model representing the fluid components of a hydraulic machinery, within which structural 3D Finite Element (FE) models can be incorporated for detailed simulation of specific sub-models or complete structural assemblies, is further developed. The fluid system model consists of ordinary differential equation sub-models that are computationally very inexpensive, but still represents the fluid dynamics very well. The co-simulation method has been shown to work very well for a simple model representing a hydraulic driven machinery. A more complex model was set up in this work, in which two cylinders in the hydraulic circuit were evaluated. Such type of models, including both the main piston and control valves, are necessary as they represent the real application to a further extent than the simple model, of only one cylinder. Two models have been developed and evaluated, from the simple rigid body representation of the structural mechanics model, to the more complex model using linear elastic representation. The 3D FE-model facilitates evaluation of displacements, stresses, and strains on a local level of the model. The results can be utilised for fatigue assessment, wear analysis and for predictions of noise radiation.
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| 5. |
- Ewest, Daniel, et al.
(author)
-
COMPARISON BETWEEN LINEAR AND NON-LINEAR FRACTURE MECHANICS ANALYSIS OF EXPERIMENTAL DATA FOR THE DUCTILE SUPERALLOY HAYNES 230
- 2015
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In: PROCEEDINGS OF THE ASME TURBO EXPO: TURBINE TECHNICAL CONFERENCE AND EXPOSITION, 2015, VOL 7A. - : ASME Press. - 9780791856765
-
Conference paper (peer-reviewed)abstract
- Vith increasing use of renewable energy sources, an industrial us turbine is often a competitive solution to balance the power rid. However, life robustness approaches for gas turbine corn9nents operating under increasingly cyclic conditions, is a chalmging task. Ductile superalloys, as Haynes 230, are often used n stationary gas turbine hot parts such as combustors. The main cad for such components is due to non -homogeneous thermal xpansion within or between parts. As the material is ductile Jere is considerable redistribution of stresses and strains due to nelastic deformations during the crack initiation phase. There ore, the subsequent crack growth occurs through a material with :gnificant residual stresses and strains. In this work, fatigue ack propagation experiments, including the initiation phase, ave been performed on a single edge notched specimen under train controlled conditions. The test results are compared to -acture mechanics analyses using the linear AK and the non near AJ approaches, and an attempt to quantify the difference 2 terms of a life prediction is made. For the tested notched gemetry, material and strain ranges, the difference in the results using AKeff or ATeff are larger than the scatter seen when fitting the model to the experimental data. The largest differences can be found for short crack lengths, when the cyclic plastic work is the largest. The AJ approach clearly shows better agreement with the experimental results in this regime.
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| 6. |
- Ewest, Daniel, et al.
(author)
-
Comparison between linear and non-linear fracture mechanics analysis of experimental data for the ductile superalloy Haynes 230
- 2016
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In: Journal of engineering for gas turbines and power. - : ASME Press. - 0742-4795 .- 1528-8919. ; 138:6, s. 062101-1-062101-7
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Journal article (peer-reviewed)abstract
- With increasing use of renewable energy sources, an industrial gas turbine is often a competitive solution to balance the power grid. However, life robustness approaches for gas turbine components operating under increasingly cyclic conditions are a challenging task. Ductile superalloys, as Haynes 230, are often used in stationary gas turbine hot parts such as combustors. The main load for such components is due to nonhomogeneous thermal expansion within or between parts. As the material is ductile, there is considerable redistribution of stresses and strains due to inelastic deformations during the crack initiation phase. Therefore, the subsequent crack growth occurs through a material with significant residual stresses and strains. In this work, fatigue crack propagation experiments, including the initiation phase, have been performed on a single edge notched specimen under strain controlled conditions. The test results are compared to fracture mechanics analyses using the linear ΔK and the nonlinear ΔJ approaches, and an attempt to quantify the difference in terms of a life prediction is made. For the tested notched geometry, material, and strain ranges, the difference in the results using ΔKeff or ΔJeff is larger than the scatter seen when fitting the model to the experimental data. The largest differences can be found for short crack lengths, when the cyclic plastic work is the largest. The ΔJ approach clearly shows better agreement with the experimental results in this regime.
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| 7. |
- Ewest, Daniel, et al.
(author)
-
Fatigue crack propagation in a ductile superalloy at room temperature and extensive cyclic plastic flow
- 2015
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In: International Journal of Fatigue. - : ELSEVIER SCI LTD. - 0142-1123 .- 1879-3452. ; 80, s. 40-49
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Journal article (peer-reviewed)abstract
- Fatigue crack propagation experiments under both force and displacement control have been performed on the wrought superalloy Haynes 230 at room temperature, using a single edge notched specimen. The force controlled tests are nominally elastic, and the displacement controlled tests have nominally large plastic hysteresis at the beginning of the tests, but saturates towards linear elastic conditions as the crack grows. As some tests are in the large scale yielding regime, a non-linear fracture mechanics approach is used to correlate crack growth rates versus the fracture parameter Delta J. It is shown that crack closure must be accounted for, to correctly model the crack growth seen in all the tests in a unified manner. For the force controlled small scale yielding tests the Newman crack closure model was used. The Newman equation is however not valid for large nominal cyclic plasticity, instead the crack closure in the displacement controlled tests is extracted from the test data. A good agreement between all tests is shown, when closure is accounted for and effective values of Delta J are used.
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| 8. |
- Ewest, Daniel, et al.
(author)
-
Isothermal and thermomechanical fatigue crack propagation in both virgin and thermally aged Haynes 230
- 2019
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In: International Journal of Fatigue. - : ELSEVIER SCI LTD. - 0142-1123 .- 1879-3452. ; 120, s. 96-106
-
Journal article (peer-reviewed)abstract
- Fatigue crack propagation tests under both isothermal and non-isothermal thermomechanical fatigue conditions have been performed on wrought Haynes 230, a ductile combustor material. A number of specimens were thermally aged by pre-straining and subsequent furnace exposure for 3000 h at 600 degrees C. The tests were performed both under load and strain control, between room temperature and 600 degrees C. The thermally aged notched specimens show a decrease in the crack initiation life, similar to results previously reported for smooth test specimens at room temperature. For the crack growth rates, the effects of thermal ageing were less pronounced than for crack initiation. Further, the tests have been simulated using the finite element method to calculate the crack driving force, where the plasticity induced crack closure is handled with a full history description. A temperature dependent linear kinematic hardening plasticity law has been adopted for describing the material behaviour between room temperature and 600 degrees C. A post-processing tool was used in which the plasticity induced crack opening level was calculated, followed by a calculation of the effective Delta J range for each crack length. The adopted procedure yields good correlation between the different tests, under both isothermal and non-isothermal conditions.
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| 9. |
- Ewest, Daniel
(author)
-
Modelling and experimental evaluation of non-linear fatigue crack propagation in a ductile superalloy
- 2016
-
Licentiate thesis (other academic/artistic)abstract
- Fatigue life evaluation is an important part in the design process of an industrial gas turbine. The fatigue life can be divided into crack initiation and crack propagation, and not to address the crack propagation part usually yields a non-conservative and overcomplicated design. Historically a lot of attention has been directed towards the crack initiation, but the crack propagation part in an industrial gas turbine context has not been given the same attention due to limitations in theoretical modelling, lack of test possibilities and that the design requirements have been fulfilled within the initiation life. However, with the need to reduce service down time and to improve performance, the crack propagation life needs to be further accounted for. As an example, cracks that emerge from notches or other stress concentrations grow under non-elastic conditions, which cannot be modelled with linear theories.In this Licentiate of Engineering thesis a non-linear approach is put forward in which the plastic contribution in fatigue crack propagation is addressed and accounted for. The theoretical background is not new, but the finite element implementation done was, to the author knowledge, not available. This numerical post processing tool can calculate the non-linear ΔJ value for an arbitrary 2D-geometry. It was used to produce an expression for a non-linear geometry factor used in a simple expression for estimation of ΔJ in a test evaluation context. Room temperature tests were performed on a single notch specimen, under both displacement and force control. The latter were carried out in order to show the behaviour under small scale yielding conditions, while the displacement controlled testing was to show large scale yielding at the beginning of the tests. It was shown that all the test results could be collected in a Paris law type plot with ΔJ if the crack closure effect is taken into account. Furthermore, a study was performed where both a linear and a non-linear approach are applied on the displacement controlled tests. It was concluded that for the studied test series, the linear fatigue fracture parameter ΔK underestimates the crack growth behaviour if the elasto-plastic stresses from the tests are used, hence yielding non-conservative results.Since this project focuses on non-linear crack propagation at thermo-mechanical conditions a crack length description is put forward, which simplifies and increases the accuracy of crack length measurements in fatigue crack propagation tests. It has also been shown that irrespectively of the crack initiation location in a single edge notch specimen the data fall on one curve, meaning that no care has to be taken regarding this aspect when evaluating crack length with the modified compliance method put forward in Paper III.This Licentiate of Engineering thesis consists of two parts, where Part I gives an introduction to the subject, while Part II consists of three papers.
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| 10. |
- Grossmann, Igor, et al.
(author)
-
Insights into the accuracy of social scientists' forecasts of societal change
- 2023
-
In: Nature Human Behaviour. - : Springer Nature. - 2397-3374. ; 7, s. 484-501
-
Journal article (peer-reviewed)abstract
- How well can social scientists predict societal change, and what processes underlie their predictions? To answer these questions, we ran two forecasting tournaments testing the accuracy of predictions of societal change in domains commonly studied in the social sciences: ideological preferences, political polarization, life satisfaction, sentiment on social media, and gender-career and racial bias. After we provided them with historical trend data on the relevant domain, social scientists submitted pre-registered monthly forecasts for a year (Tournament 1; N = 86 teams and 359 forecasts), with an opportunity to update forecasts on the basis of new data six months later (Tournament 2; N = 120 teams and 546 forecasts). Benchmarking forecasting accuracy revealed that social scientists' forecasts were on average no more accurate than those of simple statistical models (historical means, random walks or linear regressions) or the aggregate forecasts of a sample from the general public (N = 802). However, scientists were more accurate if they had scientific expertise in a prediction domain, were interdisciplinary, used simpler models and based predictions on prior data. How accurate are social scientists in predicting societal change, and what processes underlie their predictions? Grossmann et al. report the findings of two forecasting tournaments. Social scientists' forecasts were on average no more accurate than those of simple statistical models.
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| 11. |
- Lindström, Thomas, 1991-, et al.
(author)
-
Accounting for anisotropic, anisothermal, and inelastic effects in crack initiation lifing of additively manufactured components
- 2023
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In: Fatigue & Fracture of Engineering Materials & Structures. - : Wiley. - 8756-758X .- 1460-2695. ; 46:2, s. 396-415
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Journal article (peer-reviewed)abstract
- The crack initiation life of a ductile additively manufactured nickel-based superalloy is studied and modeled for low-cycle fatigue and thermomechanical fatigue conditions up to 600 degrees C. Isothermal experiments were performed on smooth specimens at temperatures up to 600 degrees C with different applied strain ranges. Additionally, thermomechanical fatigue experiments at 100-450 degrees C and 100-600 degrees C were performed on smooth specimens under in-phase and out-of-phase conditions. A life prediction model accounting for the anisotropy was developed, where the temperature cycle is accounted with a Delta T$$ \Delta T $$-functionality, generating good agreements with the experiments. The model was also validated on notched specimens undergoing thermomechanical fatigue conditions at 100-500 degrees C using simplified notch correction methods.
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| 12. |
- Lindström, Thomas, et al.
(author)
-
Constitutive model for thermomechanical fatigue conditions of an additively manufactured combustor alloy
- 2022
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In: Mechanics of materials. - : Elsevier. - 0167-6636 .- 1872-7743. ; 168
-
Journal article (peer-reviewed)abstract
- In this study, the mechanical response of an additively manufactured nickel-based combustor alloy, subjected to thermomechanical fatigue (TMF) loadings has been investigated and modelled. TMF tests were performed in both in-phase and out-of-phase conditions with different strain ranges and temperature ranges of 100 degrees C-450 degrees C and 100 degrees C-600 degrees C, respectively. The smooth specimens were manufactured in two different orientations to study the influence of anisotropy, and the specimens were machined to final dimensions with conventional techniques. A constitutive model with focus on describing the mid-life behaviour was developed where the total inelastic strain was divided into one plastic (rate-independent) and one creep (rate-dependent) part, to be able to describe both the rate-dependent effects from TMF conditions as well as rate-independent responses. A cycle jumping procedure was used, which enables to simulate the mid-life response of the material for TMF as well as low-cycle fatigue conditions within three simulated loading cycles.
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| 13. |
- Lindström, Thomas, et al.
(author)
-
Constitutive model of an additively manufactured combustor material at high-temperature load conditions
- 2024
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In: Materials at High Temperature. - : TAYLOR & FRANCIS LTD. - 0960-3409 .- 1878-6413.
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Journal article (peer-reviewed)abstract
- In this paper, the high-temperature constitutive behaviour of an additively manufactured ductile nickel-based superalloy is investigated and modelled, with application to thermomechanical fatigue, low-cycle fatigue and creep conditions at temperatures up to 800∘800∘C. Thermomechanical fatigue tests have been performed on smooth specimens in both in-phase and out-of-phase conditions at a temperature range of 100−800∘100−800∘C, and creep tests at 625∘625∘C, 700∘700∘C, 750∘750∘C and 800∘800∘C. Additionally, low-cycle fatigue tests at different strain ranges and load ratios have been performed at 700∘700∘C, and tensile tests have been performed at 600∘600∘C, 700∘700∘C and 800∘800∘C. A clear anisotropic mechanical response is obtained in the experiments, where the anisotropic effects are larger at high stress levels in creep loadings. To capture this behaviour, a rate-dependent strain based on a double-Norton model has been adopted in the model, by which the creep and mid-life response of the thermomechanical fatigue tests can be simulated with good accuracy.
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| 14. |
- Lindström, Thomas, et al.
(author)
-
Constitutive model of an additively manufactured ductile nickel-based superalloy undergoing cyclic plasticity
- 2020
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In: International journal of plasticity. - : PERGAMON-ELSEVIER SCIENCE LTD. - 0749-6419 .- 1879-2154. ; 132
-
Journal article (peer-reviewed)abstract
- In this paper, a transversely isotropic elasto-plastic model based on the multilinear Ohno-Wang model was developed to simulate the cyclic behaviour of an additively manufactured ductile nickel-based superalloy. The transverse isotropy was taken into account by the incorporation of a structural tensor in the modelling framework. To calibrate the model, a number of uniaxial isothermal low-cycle fatigue tests were carried out on smooth specimens manufactured in three different orientations with respect to the building platform. The test specimens were subjected to different strain ranges and load ratios, as well as four different temperatures, namely room temperature, 400 degrees C, 500 degrees C and 600 degrees C. By using a cycle jumping procedure, where the material properties are changed from virgin parameters to mid-life parameters, the mid-life behaviour, commonly used for fatigue life predictions, of the concerned material could be simulated with good agreements to the performed experiments. To validate the results, the maximum and minimum stress, as well as the plastic strain range and hysteresis area from the simulated mid-life hysteresis loops were compared to the values obtained from the experiments.
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| 15. |
- Lindström, Thomas, et al.
(author)
-
Crack initiation prediction of additive manufactured ductile nickel-based superalloys
- 2018
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In: 12TH INTERNATIONAL FATIGUE CONGRESS (FATIGUE 2018). - : E D P SCIENCES.
-
Conference paper (peer-reviewed)abstract
- A model to predict crack initiation life of an additive manufactured nickel-based superalloy similar to Hastelloy X subjected to low-cycle fatigue loading at room temperature has been developed, taking material anisotropy into account. An anisotropic constitutive model based on the Hill yield criterion was developed, with linear kinematic hardening up to a saturation value of the back stress, above which the material behaves perfectly plastic. Low-cycle fatigue experiments has been performed on additive manufactured smooth bars with two different build orientations, with an angle of 0 degrees and 90 degrees relative to the building platform. A total of 20 experiments at room temperature were conducted with different strain ranges and R-values. To predict the crack initiation life of the specimens, a model based on the Smith-Watson-Topper (SWT) parameter has been established, where ten of the specimens were used to calibrate the initiation model, and the remaining specimens were used for validation. Using this model, the obtained crack initiation life agrees well with the experiments.
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| 16. |
- Nilsson, Daniel, 1982-
(author)
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A ΔJ approach for nonlinear fatigue crack propagation : Experimental and numerical investigation of a ductile superalloy
- 2024
-
Doctoral thesis (other academic/artistic)abstract
- This dissertation is a product of an academic-industrial collaboration between the Division of Solid Mechanics at Linköping University and Siemens Energy AB. The focus is on enhancing the design optimisation procedures for high-temperature components in industrial gas turbines (IGT). The research is centred around the behaviour of the nickelbased high-temperature superalloy Haynes 230 under service-like conditions with predominant thermal loads. The aim is to improve fatigue crack propagation life predictions for nonlinear conditions.The research findings validate the thermal ageing fatigue effects on Haynes 230 as seen in existing literature, especially on constitutive properties and crack initiation. Additionally, it was observed that thermal ageing has a minor effect on the crack growth rate up to 600 °C, which can be managed by updating the crack driving force with thermally aged properties.The project mainly focused on nonlinear crack propagation at isothermal and thermomechanical fatigue conditions. A new method for crack length description, using a modified compliance method, is introduced. This method simplifies and enhances the accuracy of crack length measurements and has become an established method for evaluating the single edge notch specimen used in the project under thermo-mechanical fatigue conditions.The nonlinear fatigue parameter ΔJ was incorporated into both Finite element method (FEM) computations and test evaluations, revealing linear trends with crack growth rates in loglog. The research highlights the crucial role of crack opening in establishing a correlation between ΔJ and crack growth rate. It was also concluded that the linear fatigue fracture parameter ΔK tends to underestimate the crack growth behaviour, resulting in non-conservative outcomes if the elasto-plastic stresses from the tests are considered.Lastly, a constitutive description of Haynes 230, based on the Ohno-Wang theory, under negligible viscoplastic effects, and an extension of the cycle jumping procedure that takes into account the significant hardening between the initial and midlife stages of the material, is presented. By this the notched geometry in 3D could be simulated with satisfying accuracy.
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| 17. |
- Adediran, Gbotemi, et al.
(author)
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Micro and nano sized particles in leachates from agricultural soils: Phosphorus and sulfur speciation by X-ray micro-spectroscopy
- 2021
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In: Water Research. - : Elsevier BV. - 0043-1354 .- 1879-2448. ; 189
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Journal article (peer-reviewed)abstract
- Colloids and nanoparticles leached from agricultural land are major carriers of potentially bioavailable nutrients with high mobility in the environment. Despite significant research efforts, accurate knowledge of macronutrients in colloids and nanoparticles is limited. We used multi-elemental synchrotron X-ray fluorescence (XRF) microscopy with multivariate spatial analysis and X-ray atomic absorption near-edge structure (XANES) spectroscopy at the P and S K-edges, to study the speciation of P and S in two fractions of leached particles, >0.45 and <0.45 mu m respectively, collected from four tile-drained agricultural sites in Sweden. P K-edge XANES showed that organic P, followed by P adsorbed to surfaces of aluminum-bearing particles were the most common forms of leached P. Iron-bound P (Fe-P) forms were generally less abundant (0-30 % of the total P). S K-edge XANES showed that S was predominantly organic, and a relatively high abundance of reduced S species suggests that redox conditions were adverse to the persistence of P bound to Fe-bearing colloids in the leachates. Acid ammonium-oxalate extractions suggested that P associated with Al and Fe (Al-P and Fe-P) in most cases could be explained by the adsorption capacity of non-crystalline (oxalate-extractable) oxides of Al and Fe. These results improve our understanding of particulate P and S speciation in the vadose zone and helps in developing effective technologies for mitigating colloidal driven eutrophication of water bodies near agricultural land. (C) 2020 The Author(s). Published by Elsevier Ltd.
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| 18. |
- Andersson, Håkan, 1970-
(author)
-
A Co-Simulation Tool Applied to Hydraulic Percussion Units
- 2022
-
Doctoral thesis (other academic/artistic)abstract
- In this dissertation, a co-simulation tool is presented that is meant to comprise a more comprehensive environment for modelling and simulation of hydraulic percussion units, which are used in hydraulic hammers and rock drills. These units generates the large impact forces, which are needed to demolish concrete structures in the construction industry or to fragment rock when drilling blast holes in mine drifting. This type of machinery is driven by fluid power and is by that dependent of coupled fluid-structure mechanisms for their operation. This tool consists of a 1D fluid system model, a 3D structural mechanic model and an interface to establish the fluid-structure couplings, which has in this work been applied to a hydraulic hammer. This approach will enable virtual prototyping during product development with an ambition to reduce the need for testing of physical prototypes, but also to facilitate more detailed studies of internal mechanisms. The tool has been implemented for two well-known simulation tools, and a co-simulation interface to enable communication between them has been devel-oped. The fluid system is simulated using the Hopsan simulation tool and the structural parts are simulated using the FE-simulation software LS-DYNA. The implementation of the co-simulation interface is based on the Functional Mock-up Interface standard in Hopsan and on the User Defined Feature module in LS-DYNA. The basic functions of the tool were first verified for a simple but relevant model comprising co-simulation of one component, and secondly co-simulation of two components were verified. These models were based on rigid body and linear elastic representation of the structural components. Further, it was experimentally validated using an existing hydraulic hammer product, where the responses from the experiments were compared to the corresponding simulated responses. To investigate the effects from a parameter change, the hammer was operated and simulated at four different running conditions. Dynamic simulation of the sealing gap, which is a fundamental mechanism used for controlling the percussive motion, was implemented to further enhance the simulated responses of the percussion unit. This implementation is based on a parametrisation of the deformed FE-model, where the gap height and the eccentric position are estimated from the deformed geometry in the sealing gap region, and then the parameters are sent to the fluid simulation for a more accurate calculation of the leakage flow. Wear in percussion units is an undesirable type of damage, which may cause significant reduction in performance or complete break-down, and today there are no methodology available to evaluate such damages on virtual prototypes. A method to study wear was developed using the co-simulation tool to simulate the fundamental behaviour of the percussion unit, and the wear routines in LS-DYNA were utilised for the calculation of wear.
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| 19. |
- Andersson, Håkan, et al.
(author)
-
Simulation of leakage flow through dynamic sealing gaps in hydraulic percussion units using a co-simulation approach
- 2021
-
In: Simulation (San Diego, Calif.). - : Elsevier B.V.. - 1569-190X .- 1878-1462. ; 111
-
Journal article (peer-reviewed)abstract
- In this study, a previously developed co-simulation method has been expanded to also simulate the dynamic behaviour of sealing gap regions in hydraulic percussion units. This approach is based on a 1D system model representing the fluid components and a 3D finite element model representing the structural parts of a hydraulic hammer. The sealing gap is a fundamental feature of a percussion unit, where the reciprocating motion of the piston is generated by the valve mechanism of the sealing gap. When the gap is closed it will prevent fluid flow between regions of different pressure levels. However, a small leakage flow through the gap will always occur which size depends on the clearance and the position of the piston. The method proposed here will take the structural motion and deformation into consideration when calculating the leakage flow. The deformed state of the structure is approximated by a cylindrical surface, in a least square manner, and communicated through the co-simulation interface to the fluid simulation module, and then used when calculating the leakage flow. This method aims at a more accurate simulation of the leakage flow that will not only yield a more realistic description of the mechanism on the local level, but also a more accurate estimation of global parameters such as overall performance and efficiency. The results indicate that the simulated leakage flow will decrease when dynamic gaps are used in comparison to static gaps, which is a consequence of the deformed structure that will generate smaller clearances. The leakage flow for the dynamic gaps will even be lower than for the static perfectly concentric case, mainly due to the reduction of clearances. The results also indicate that the dynamic eccentricity does not have a major influence on the leakage flow. The outcome from this study highlights the potentials of the described co-simulation approach for analysing the dynamics of the sealing gaps in a hydraulic percussion unit (i.e. gap heights, eccentricity ratios, etc.) including the evaluation of leakage flows and its impact on the overall performance. © 2021
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| 20. |
- Andersson, Håkan, et al.
(author)
-
Validation of a co-simulation approach for hydraulic percussion units applied to a hydraulic hammer
- 2019
-
In: Advances in Engineering Software. - : ELSEVIER SCI LTD. - 0965-9978 .- 1873-5339. ; 131, s. 102-115
-
Journal article (peer-reviewed)abstract
- In this study, a previously developed co-simulation approach has been adopted to simulate the responses of an existing hydraulic hammer product. This approach is based on a 1D system model representing the fluid components and a 3D finite element model representing the structural parts of the hydraulic hammer. The simulation model was validated against four experiments with different running conditions. The corresponding set-ups were analysed using the co-simulation method in order to evaluate the overall responses. A parameter study was also performed involving the working pressure and the restrictor diameter, with the objective to validate that a parameter change in the simulation model will affect the input and output power in the same direction as in the experiments. The experimental responses used in the validation were time history data of fluid pressure, component position and acceleration, and structural stresses. The experiments result in high frequency and high amplitude excitations of the hydraulic hammer and thus require a model with a high resolution of the model dynamics. The conclusion of the validation is that the simulation model is able to replicate the experimental responses with high accuracy including the high frequency dynamics. The favourable outcome of the validation makes the described co-simulation approach promising as an efficient tool for a wide range of other applications where short time duration mechanisms need to be studied.
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| 21. |
- Azeez, Ahmed, 1991-
(author)
-
High-Temperature Durability Prediction of Ferritic-Martensitic Steel
- 2023
-
Doctoral thesis (other academic/artistic)abstract
- Materials used for high-temperature steam turbine sections are generally subjected to harsh environments with temperatures up to 625 °C. The superior creep resistance of 9–12 % Cr ferritic-martensitic steels makes them desirable for those critical steam turbine components. Additionally, the demand for fast and frequent steam turbine start-ups, i.e. flexible operations, causes accelerated fatigue damage in critical locations, such as grooves and notches, at the high-temperature inner steam turbine casing. A durability assessment is necessary to understand the material behaviour under such high temperatures and repeated loading, and it is essential for life prediction. An accurate and less conservative fatigue life prediction approach is achieved by going past the crack initiation stage and allowing controlled growth of cracks within safe limits. Besides, beneficial load-temperature history effects, i.e. warm pre-stressing, must be utilised to enhance the fracture resistance to cracks. This dissertation presents the high-temperature durability assessment of FB2 steel, a 9-12 % Cr ferritic-martensitic steam turbine steel.Initially, isothermal low-cycle fatigue testing was performed on FB2 steel samples. A fatigue life model based on finite element strain range partitioning was utilised to predict fatigue life within the crack initiation phase. Two fatigue damage regimes were identified, i.e. plastic- and creep-dominated damage, and the transition between them depended on temperature and applied total strain. Cyclic deformation and stress relaxation behaviour were investigated to produce an elastic-plastic and creep material model that predicts the initial and mid-life cyclic behaviour of the FB2 steel.Furthermore, the thermomechanical fatigue crack growth behaviour of FB2 steel was studied. Crack closure behaviour was observed and accounted for numerically and experimentally, where crack growth rate curves collapsed into a single curve. Interestingly, the collapsed crack growth curves coincided with isothermal crack growth tests performed at the minimum temperature of the thermomechanical crack growth tests. In addition, hold times and changes in the minimum temperature of the thermomechanical fatigue cycle did not influence crack closure behaviour.Finally, warm pre-stressing effects were explored for FB2 steel. A numerical prediction model was produced to predict the increase in the apparent fracture toughness. Warm pre-stressing effects can benefit the turbine life by enhancing fracture resistance and allowing longer fatigue cracks to grow within safe limits.
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| 22. |
- Azeez, Ahmed, 1991-
(author)
-
High-Temperature Fatigue in a Steam Turbine Steel : Modelling of Cyclic Deformation and Crack Closure
- 2021
-
Licentiate thesis (other academic/artistic)abstract
- Existing conventional thermal power plants are retrofitted for flexible operations to assist the transition toward more renewable energies. The deployment of many renewable energy power plants is necessary to achieve a clean environment with less pollution. However, the intermittent nature of renewable energies, due to weather changes, and the lack of efficient large energy storage systems put renewables at a disadvantage. Flexible operations of power plants imply fast and frequent start-ups. Thus, retrofitted power production plants can be utilised as an energy backup to satisfy the immediate demand during peak energy times or when renewable energies are suddenly limited. Large thermal power plants generally employ steam turbines with high inlet temperature and pressure steam conditions. Materials used for components at the high-temperature turbine sections are expected to withstand harsh environments. The use of 9-12 % Cr martensitic steels is desirable due to, among other things, their superior resistance to creep for temperatures up to 625 °C. Retrofitting for flexible operations put steam turbine components under high-temperature fatigue loading conditions different from how they were designed before. The flexible operations could lead to fatigue cracking at critical locations, such as grooves and notches at the inner steam turbine casing. Thus, fatigue behaviour understanding of steam turbine materials under such loading conditions is essential for components life prediction. Accurate and less conservative fatigue life prediction approach is necessary to extend the turbine components life, which reduces waste and provides economic benefits. This can be done by extending operations past crack initiation phase and allowing controlled propagation of cracks in the components. Within the 9-12 % Cr steel class, the martensitic steam turbine steel called FB2 is studied under high-temperature fatigue. This includes investigating high-temperature fatigue life behaviour, cyclic deformation behaviour, stress relaxation behaviour, and crack propagation behaviour along with crack closure behaviour. This was achieved by experimentally testing samples made from FB2 steel under isothermal low cycle fatigue, isothermal fatigue crack propagation, and thermomechanical fatigue crack propagation.
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| 23. |
- Behm, Mårten, et al.
(author)
-
Electrochemical production of polysulfides and sodium hydroxide from while liquor .2. Electrolysis in a laboratory scale flow cell
- 1997
-
In: Journal of Applied Electrochemistry. - 0021-891X .- 1572-8838. ; 27:5, s. 519-528
-
Journal article (peer-reviewed)abstract
- Electrochemical production of polysulfide-containing white liquor and pure sodium hydroxide solution was investigated at 90 degrees C in a laboratory scale flow cell. A mixed iridium-tantalum oxide coated titanium electrode was used as the anode and the two electrolyte compartments were separated by a cation-exchange membrane. The process was demonstrated at current densities up to 5 kA m(-2), resulting in high current efficiencies for both products. The previously reported autocatalytic effect of polysulfide ions was confirmed, and its technical implications on the use of three-dimensional electrodes were demonstrated and discussed. The current efficiency was found to depend strongly on the degree of conversion of sulfur(-II) to sulfur(0). The anode material showed favourable properties, with respect to activity and selectivity, but suffered from limited durability.
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| 24. |
- Behm, Mårten, et al.
(author)
-
Electrochemical production of polysulfides and sodium hydroxide from white liquor .1. Experiments with rotating disc and ring-disc electrodes
- 1997
-
In: Journal of Applied Electrochemistry. - 0021-891X .- 1572-8838. ; 27:5, s. 507-518
-
Journal article (peer-reviewed)abstract
- Electrochemical oxidation of white liquor in a membrane cell is a process of great potential for the pulp and paper industry. The process produces polysulfide-containing white liquor in the anode chamber, and pure sodium hydroxide solution in the cathode chamber. The anode reaction has been investigated using cyclic voltammetry at temperatures between 25 and 90 degrees C on rotating disc and ring-disc electrodes. It was further investigated using chronoamperometry on rotating disc electrodes at 90 degrees C. The experiments, which were mainly run in dilute alkaline sulfide solutions, using platinum electrodes, show that the electrochemical production of polysulfide ions, at lower anode potentials (-0.1 to +0.1 V vs SCE), proceeds via formation of elemental sulfur on the electrode surface. The sulfur is dissolved by hydrosulfide and polysulfide ions producing (longer-chain) polysulfide ions. The rate of dissolution, and thus the overall reaction rate, increases strongly with temperature. Polysulfide ions have an autocatalytic effect on the anode reaction due to their ability to dissolve adsorbed sulfur. At higher anode potentials (greater than or equal to 0.2 V vs SCE), a change of reaction mechanism is observed. In this region the reaction rate depends on electrode potential and is not catalysed by polysulfide ions.
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| 25. |
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| 26. |
- Behm, Mårten, et al.
(author)
-
Nickel as anode material for the electrochemical production of polysulfides in white liquor
- 1999
-
In: Journal of New Materials for Electrochemical Systems. - 1480-2422. ; 2:1, s. 11-18
-
Journal article (peer-reviewed)abstract
- This paper is concerned with new anode materials for the electrochemical oxidation of white liquor. This electrosynthesis process is run in a membrane cell where polysulfide ions are produced in the white liquor of the anode chamber, while a pure sodium hydroxide solution is generated in the cathode chamber: If the noble metal oxide coated anodes that were used in a previous investigation could be successfully replaced by nickel, important reductions in investment costs would be possible. The stability and catalytic activity of nickel as anode material were investigated using cyclic voltammetry and chronoamperometry on rotating disc electrodes, combined with surface analysis. Furthermore, porous nickel was tested in a flow cell, with galvanostatic electrolysis. The results show that nickel has good activity for sulfide oxidation, but a nickel oxide/sulfide surface layer is formed which deactivates the electrode at E greater than or equal to -0.2 V, probably due to the increasing proportion of poorly conducting Ni(II) oxide. Carbon precipitation, and peeling of a thin film of the metal were observed with SEM. High current efficiency and an overpotential of less than 0.2 V were obtained with a porous nickel electrode at a geometric current density of 3 kA m(-2). Corrosion did not appear to be a problem, and nickel should also be suitable as substrate material for more active anode coatings.
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| 27. |
- Bogot, Alon, et al.
(author)
-
The mutual neutralization of hydronium and hydroxide
- 2024
-
In: Science. - 0036-8075 .- 1095-9203. ; 383:6680, s. 285-289
-
Journal article (peer-reviewed)abstract
- Mutual neutralization of hydronium (H3O+) and hydroxide (OH−) ions is a very fundamental chemical reaction. Yet, there is only limited experimental evidence about the underlying reaction mechanisms. Here, we report three-dimensional imaging of coincident neutral products of mutual-neutralization reactions at low collision energies of cold and isolated ions in the cryogenic double electrostatic ion-beam storage ring (DESIREE). We identified predominant H2O + OH + H and 2OH + H2 product channels and attributed them to an electron-transfer mechanism, whereas a minor contribution of H2O + H2O with high internal excitation was attributed to proton transfer. The reported mechanism-resolved internal product excitation, as well as collision-energy and initial ion-temperature dependence, provide a benchmark for modeling charge-transfer mechanisms.
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| 28. |
- Busse, Christian, et al.
(author)
-
A FINITE ELEMENT STUDY OF THE EFFECT OF CRYSTAL ORIENTATION AND MISALIGNMENT ON THE CRACK DRIVING FORCE IN A SINGLE-CRYSTAL SUPERALLOY
- 2016
-
In: PROCEEDINGS OF THE ASME TURBO EXPO: TURBINE TECHNICAL CONFERENCE AND EXPOSITION, 2016, VOL 7A. - : AMER SOC MECHANICAL ENGINEERS. - 9780791849835
-
Conference paper (peer-reviewed)abstract
- The elastic and plastic anisotropy of the single-crystal materials bring many difficulties in terms of modeling, evaluation and prediction of fatigue crack growth. In this paper a single-crystal material model has been adopted to a finite element-environment, which is paired with a crack growth tool. All simulations are performed in a three-dimensional context. This methodology makes it possible to analyze complex finite element-models, which are more application-near than traditional two-dimensional models. The influence of the crystal orientation, as well as the influence of misalignments of the crystal orientation due to the casting process are investigated. It is shown that both the crystal orientation and the misalignment from the ideal crystal orientation are important for the crack driving force. The realistic maximum limit of 10 degrees misalignment is considered. It can be seen that crack growth behavior is highly influenced by the misalignment. This knowledge is of great interest for the industry in order to evaluate the crack growth in single-crystal components more accurately.
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| 29. |
- Busse, Christian, 1989-
(author)
-
Aspects of Crack Growth in Single-Crystal Nickel-Base Superalloys
- 2017
-
Licentiate thesis (other academic/artistic)abstract
- This Licentiate of Engineering thesis is a product of the results generated in the research project KME-702, which comprises modelling, microstructure investigations and material testing of cast nickel-base superalloys.The main objective of this work is to model the fatigue crack propagation behaviour in single-crystal nickel-base superalloys. To achieve this, the influence of the crystal orientations on the cracking behaviour is assessed. The results show that the crystal orientation is strongly affecting the material response and must be accounted for. Furthermore, a linear elastic crack driving force parameter suitable for describing crystallographic cracking has been developed. This parameter is based on resolved anisotropic stress intensity factors and is able to predict the correct crystallographic cracking plane after a transition from a Mode I crack. Finally, a method to account for inelastic deformations in a linear elastic fracture mechanics context was investigated. A residual stress field is extracted from an uncracked finite-element model with a perfectly plastic material model and superimposed on the stress field from the cracked model with a linear elastic material model to account for the inelastic deformations during the determination of the crack driving force. The modelling work is validated by material testing on two different specimen geometries at different temperatures.This Licentiate of Engineering thesis consists of two parts, where Part I gives an introduction and background to the research area, while Part II consists of three papers.
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| 30. |
- Busse, Christian, et al.
(author)
-
Criteria evaluation for the transition of cracking modes in a single-crystal nickel-base superalloy
- 2020
-
In: Theoretical and applied fracture mechanics (Print). - : ELSEVIER. - 0167-8442 .- 1872-7638. ; 106
-
Journal article (peer-reviewed)abstract
- Single-crystal nickel-base superalloys frequently experience two distinct fatigue crack growth modes. It has been observed that, under certain conditions, cracks transition from a path perpendicular to the loading direction to a crystallographic slip plane. As crystallographic cracking is associated with an increased fatigue crack growth rate, it is important to be able to predict when this transition occurs. In this work three different criteria for crystallographic cracking based on resolved anisotropic stress intensity factors are evaluated in a three-dimensional finite element context. The criteria were calibrated and evaluated using isothermal fatigue experiments on two different specimen geometries. It is suggested by the results, that a threshold value of a resolved shear stress intensity factor can act as a conservative criterion indicating cracking mode transition. Further, a trend hinting towards a loading frequency dependency could be observed.
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| 31. |
- Busse, Christian, et al.
(author)
-
Evaluation of the crystallographic fatigue crack growth rate in a single-crystal nickel-base superalloy
- 2019
-
In: International Journal of Fatigue. - : ELSEVIER SCI LTD. - 0142-1123 .- 1879-3452. ; 127, s. 259-267
-
Journal article (peer-reviewed)abstract
- Cracks in single-crystal nickel-base superalloys have been observed to switch cracking mode from Mode I to crystallographic cracking. The crack propagation rate is usually higher on the crystallographic planes compared to Mode I, which is important to account for in crack growth life predictions. In this paper, a method to evaluate the crystallographic fatigue crack growth rate, based on a previously developed crystallographic crack driving force parameter, is presented. The crystallographic crack growth rate was determined by evaluating heat tints on the fracture surfaces of the test specimens from the experiments. Complicated crack geometries including multiple crystallographic crack fronts were modelled in a three dimensional finite element context, The data points of the crystallographic fatigue crack growth rate collapse on a narrow scatter band for the crystallographic cracks indicating a correlation with the previously developed crystallographic crack driving force.
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| 32. |
- Busse, Christian, 1989-
(author)
-
Modelling of Crack Growth in Single-Crystal Nickel-Base Superalloys
- 2019
-
Doctoral thesis (other academic/artistic)abstract
- This dissertation was produced at the Division of Solid Mechanics at Linköping University and is part of a research project, which comprises modelling, microstructure investigations and material testing of cast nickel-base superalloys. The main objective of this work was to deepen the understanding of the fracture behaviour of single-crystal nickel-base superalloys and to develop a model to predict the fatigue crack growth behaviour. Frequently, crack growth in these materials has been observed to follow one of two distinct cracking modes; Mode I like cracking perpendicular to the loading direction or crystallographic crack growth on the octahedral {111}-planes, where the latter is associated with an increased fatigue crack growth rate. Thus, it is of major importance to account for this behaviour in component life prediction. Consequently, a model for the prediction of the transition of cracking modes and the correct active crystallographic plane, i.e. the crack path, and the crystallographic crack growth rate has been developed. This model is based on the evaluation of appropriate crack driving forces using three-dimensional finite-element simulations. A special focus was given towards the influence of the crystallographic orientation on the fracture behaviour. Further, a model to incorporate residual stresses in the crack growth modelling is presented. All modelling work is calibrated and validated by experiments on different specimen geometries with different crystallographic orientations. This dissertation consists of two parts, where Part I gives an introduction and background to the field of research, while Part II consists of six appended papers.
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| 33. |
- Busse, Christian, 1989-, et al.
(author)
-
Prediction of crystallographic cracking planes in single-crystal nickel-base superalloys
- 2018
-
In: Engineering Fracture Mechanics. - : Elsevier. - 0013-7944 .- 1873-7315. ; 196, s. 206-223
-
Journal article (peer-reviewed)abstract
- The inherent anisotropy of single-crystal nickel-base superalloys brings many difficulties in terms of modelling, evaluation and prediction of fatigue crack growth. Two models to predict on which crystallographic plane cracking will occur is presented. The models are based on anisotropic stress intensity factors resolved on crystallographic slip planes calculated in a three-dimensional finite-element context. The developed models have been compared to experiments on two different test specimen geometries. The results show that a correct prediction of the crystallographic cracking plane can be achieved. This knowledge is of great interest for the industry and academia to better understand and predict crack growth in single-crystal materials.
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| 34. |
- Busse, Christian, et al.
(author)
-
Three-Dimensional LEFM Prediction of Fatigue Crack Propagation in a Gas Turbine Disk Material at Component Near Conditions
- 2016
-
In: Journal of engineering for gas turbines and power. - : ASME. - 0742-4795 .- 1528-8919. ; 138:4
-
Journal article (peer-reviewed)abstract
- In this paper, the possibility to use linear elastic fracture mechanics (LEFM), with and without a superimposed residual stress field, to predict fatigue crack propagation in the gas turbine disk material Inconel 718 has been studied. A temperature of 400 degrees C and applied strain ranges corresponding to component near conditions have been considered. A three-dimensional crack propagation software was used for determining the stress intensity factors (SIFs) along the crack path. In the first approach, a linear elastic material behavior was used when analyzing the material response. The second approach extracts the residual stresses from an uncracked model with perfectly plastic material behavior after one loading cycle. As a benchmark, the investigated methods are compared to experimental tests, where the cyclic lifetimes were calculated by an integration of Paris law. When comparing the results, it can be concluded that the investigated approaches give good results, at least for longer cracks, even though plastic flow was taking place in the specimen. The pure linear elastic simulation overestimates the crack growth for all crack lengths and gives conservative results over all considered crack lengths. Noteworthy with this work is that the 3D-crack propagation could be predicted with the two considered methods in an LEFM context, although plastic flow was present in the specimens during the experiments.
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| 35. |
- Cornell, Ann, 1962-, et al.
(author)
-
Anodic Reactions in the Chlorate Process
- 2001. - 1
-
In: Energy and Electrochemical Processes for a Cleaner Environment. - Pennington, New Jersey, USA : The Electrochemical Scoiety, Inc.. - 1566773563 ; , s. 117-128
-
Book chapter (peer-reviewed)
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| 36. |
|
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| 37. |
- Cornell, Ann, et al.
(author)
-
Ruthenium Dioxide as Cathode Material for Hydrogen Evolution in Hydroxide and Chlorate Solutions
- 1993
-
In: Journal of The Electrochemical Society. - : The Electrochemical Society. - 0013-4651 .- 1945-7111. ; 140:11, s. 3123-3129
-
Journal article (peer-reviewed)abstract
- Ruthenium dioxide as electrocatalyst on an activated cathode for chlorate production was investigated with respect toits activity towards hydrogen evolution, hypochlorite reduction, and chlorate reduction, respectively. Investigations weremade in the presence, as well as in the absence, of a chromium hydroxide film in 1M NaOH and in typical chlorateelectrolyte. Low overvoltages for hydrogen evolution were found and, at technical current densities, an effect of catalystcoating thickness. Commercial DSA® electrodes with RuO2 as the active compound were tested as cathodes and were lessactive but more stable than the coatings produced by us. Hypochlorite and chlorate were reduced in the absence ofchromate, chlorate reduction being fast on ruthenium dioxide compared to the other electrode materials and by far thedominating cathodic reaction in chlorate electrolyte without chromate and hypochlorite at 70°C, 3 kA/m2
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| 38. |
- Cornell, Ann, et al.
(author)
-
The effect of addition of chromate on the hydrogen evolution reaction and on iron oxidation in hydroxide and chlorate solutions
- 1992
-
In: Electrochimica Acta. - 0013-4686 .- 1873-3859. ; 37:10, s. 1873-1881
-
Journal article (peer-reviewed)abstract
- The addition of chromate to the electrolyte has been shown in previous papers to hinder almost completely the electroreduction of hypochlorite, while the hydrogen evolution reaction can still proceed on the cathode surface. The effect of chromate on the latter reaction has been studied with cyclic voltammetry and by measuring polarization curves for iron electrodes in both chlorate and hydroxide electrolyte. For the sake of comparison, the investigations have also included the effects on the gold electrode in hydroxide solution. The results showed that the kinetics is changed in a way that decreases the differences in electrocatalytic activity between different electrode materials. Also, the innermost layer of the chromium hydroxide film seems to be the most active part in the HER. The chromate also affects the oxidation of the iron surface. A practical result of this is that the activity for the HER on corroded iron in chlorate electrolyte depends on whether the electrolyte contained chromate during the period of corrosion. The activation becomes much smaller if chromate is present.
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| 39. |
- Eklund, Gustav, 1990-
(author)
-
Experiments on mutual neutralization using storage rings with merged ion beams
- 2020
-
Doctoral thesis (other academic/artistic)abstract
- This thesis presents work on merged-beams experiments using the DESIREE facility, which consists of two electrostatic ion-storage rings operated at cryogenic temperatures of about 13 K. The two storage rings have a common straight section, where oppositely charged ions can interact at sub-eV collision energies. The work consists of development of the experimental method, tools for data analysis, and simulations for interpretation of the experimental results. This development has led to the first results from merged-beams experiments at DESIREE. The experiments are performed on mutual neutralization, a collision process where an electron is transferred from a negatively charged ion to a positively charged ion, resulting in two neutral products. This reaction is investigated for three systems: Li+ with D−, Na+ with D−, and Mg+ with D−. The reactions studied are of astrophysical interest, in particular for modeling of stellar atmospheres. The detection of the reaction products is done by using a position- and time-sensitive detector, and from this information it is possible to determine the quantum states involved in the reaction. The branching fractions of the reaction channels are measured and compared to theoretical modeling.
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| 40. |
- Ekqvist, David, et al.
(author)
-
Safety and pharmacokinetics-pharmacodynamics of a shorter tuberculosis treatment with high-dose pyrazinamide and rifampicin : a study protocol of a phase II clinical trial (HighShort-RP)
- 2022
-
In: BMJ Open. - : BMJ Publishing Group Ltd. - 2044-6055. ; 12:3
-
Journal article (peer-reviewed)abstract
- Introduction: Increased dosing of rifampicin and pyrazinamide seems a viable strategy to shorten treatment and prevent relapse of drug-susceptible tuberculosis (TB), but safety and efficacy remains to be confirmed. This clinical trial aims to explore safety and pharmacokinetics-pharmacodynamics of a high-dose pyrazinamide-rifampicin regimen.Methods and analysis: Adult patients with pulmonary TB admitted to six hospitals in Sweden and subjected to receive first-line treatment are included. Patients are randomised (1:3) to either 6-month standardised TB treatment or a 4-month regimen based on high-dose pyrazinamide (40 mg/kg) and rifampicin (35 mg/kg) along with standard doses of isoniazid and ethambutol. Plasma samples for measurement of drug exposure determined by liquid chromatography tandem-mass spectrometry are obtained at 0, 1, 2, 4, 6, 8, 12 and 24 hours, at day 1 and 14. Maximal drug concentration (C-max) and area under the concentration-time curve (AUC(0-24h)) are estimated by non-compartmental analysis. Conditions for early model-informed precision dosing of high-dose pyrazinamide-rifampicin are pharmacometrically explored. Adverse drug effects are monitored throughout the study and graded according to Common Terminology Criteria for Adverse Events V.5.0. Early bactericidal activity is assessed by time to positivity in BACTEC MGIT 960 of induced sputum collected at day 0, 5, 8, 15 and week 8. Minimum inhibitory concentrations of first-line drugs are determined using broth microdilution. Disease severity is assessed with X-ray grading and a validated clinical scoring tool (TBscore II). Clinical outcome is registered according to WHO definitions (2020) in addition to occurrence of relapse after end of treatment. Primary endpoint is pyrazinamide AUC(0-24h) and main secondary endpoint is safety.Ethics and dissemination: The study is approved by the Swedish Ethical Review Authority and the Swedish Medical Products Agency. Informed written consent is collected before study enrolment. The study results will be submitted to a peer-reviewed journal.
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| 41. |
|
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| 42. |
- Ekström, Daniel P T, 1976, et al.
(author)
-
Climate impact optimization in concrete bridge construction
- 2017
-
In: IABSE Conference, Vancouver 2017. - : International Association for Bridge and Structural Engineering (IABSE). - 9783857481536 ; , s. 1161-1168, s. 1161-1168
-
Conference paper (peer-reviewed)abstract
- Estimates indicate that the total climate impact, from a lifecycle perspective, generated by Swedish construction processes reaches the same magnitude as emissions from all passenger cars in Sweden. A large part of the emissions from construction of roads and railways arise from production of steel and concrete used in bridges and other infrastructure structures. In this research, several cases of existing concrete bridges have been investigated. The case studies are in a very firm way analyzed, and then opportunities for reducing climate gas emissions are described and elaborated upon. Accordingly, design and dimensioning through the use of today's technology and material selection are discussed. Without developing new ways to construct bridges, or comparing concrete with other materials, a useful guide on how to use technology and opportunities that are available for constructing climate smarter versions of standard bridges today is developed and described.
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| 43. |
- Ekström, Daniel P T, 1976, et al.
(author)
-
Integrated project teams in early design stages - Key variables influencing cost effectiveness in bridge building
- 2016
-
In: 19th IABSE Congress Stockholm, 21-23 September 2016, Challenges in Design and Construction of an Innovative and Sustainable Built Environment. ; , s. 598-606
-
Conference paper (peer-reviewed)abstract
- The construction industry is usually regarded as a complex, multidisciplinary and project focused environment. It is also regularly identified as a one-of-a-kind nature, hence focus is on the uniqueness of projects rather than in similarities. The results presented in this article are based on questionnaire addressed to clients, contractors, and designers, mainly active within the Swedish infrastructure sector. The purpose is to highlight key-variables influencing cost effectiveness for the organization of integrated project teams, designing of projects, and construction at site. The results indicate that more attention needs to be paid to the actual project setting if to fully gain the benefits from integrated project teams. Further, the results indicates that it is mainly project culture; collaboration and social relationships, and project competence, the ability to solve mutual issues, that needs to be developed.
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| 44. |
- Eriksson, Robert, et al.
(author)
-
Evaluation of notch effects in low cycle fatigue of alloy 718 using critical distances
- 2018
-
In: 12TH INTERNATIONAL FATIGUE CONGRESS (FATIGUE 2018). - : E D P SCIENCES.
-
Conference paper (peer-reviewed)abstract
- Gas turbine disks contain many notch-like features acting as stress raisers. The fatigue life based on the notch root stress may be overly conservative as the steep stress gradient in front of the notch may give rise to so-called notch support. In the current work, the theory of critical distances was applied to the prediction of the total fatigue life of low cycle fatigued, notched specimens made from alloy 718. The fatigue tests were performed at 450 degrees C and 550 degrees C. It was found that, for lives shorter than 5000-10000 cycles, the notched specimens had longer lives than would have been expected based on the notch root strain. For lives longer than 5000-10000 cycles, there were no notch support. The life prediction for notched specimens could be significantly improved by basing the prediction on the strain chosen some distance from the notch (the critical distance). An expression for calculating the critical distance based on the notch root strain was suggested.
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| 45. |
- Ewest, D., et al.
(author)
-
A modified compliance method for fatigue crack propagation applied on a single edge notch specimen
- 2016
-
In: International Journal of Fatigue. - London : ELSEVIER SCI LTD. - 0142-1123 .- 1879-3452. ; 92, s. 61-70
-
Journal article (peer-reviewed)abstract
- Crack length measurements with high accuracy are often difficult to achieve during fatigue crack propagation testing under non-isothermal conditions. In this work a modified approach to the compliance method defined in e.g. ASTM E647 is described, which is better suited for high loads, varying temperatures and for taking the scatter in Youngs modulus into account. A numerical finite element study is performed for a single edge notch specimen, to investigate the influence of initiation locations on the accuracy of the method. The change in cracked area versus change in stiffness for three different cases are numerically shown to collapse to one curve, i.e. the result is not significantly affected by how the crack is initiated. The numerical study is compared to results from two experiments using different materials, with heat tinting during the tests for extracting snapshots of the crack fronts. A good agreement between the experiments and the numerical study is shown. A new compliance curve and a new geometry function for the stress intensity factor is proposed for the single edge notch specimen. (C) 2016 Elsevier Ltd. All rights reserved.
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| 46. |
- Fontes, Eduardo, et al.
(author)
-
A heterogeneous model for the MCFC cathode
- 1995
-
In: Electrochimica Acta. - 0013-4686. ; 40:11, s. 1641-1651
-
Journal article (peer-reviewed)abstract
- A steady state agglomerate model for the MCFC cathode which takes into account the heterogeneous structure of this porous electrode is presented. The resulting model equations are solved by means of the finite element method. Calculations have been performed on two different test structures and include the influence of kinetics, porosity, outer surface area and distribution of electrolyte film. Comparisons with the filmed agglomerate model show that it is possible to obtain excellent agreement between the polarisation curves predicted by the two different models if a uniform film is used in the simulations. The tortuosity in the filmed agglomerate model is used as a fitting parameter. Other effects that evolve in the heterogeneous model due to variations in the local structure are not revealed in the pseudohomogeneous model. The effect of a non-uniform electrolyte film thickness was investigated by solving the problem for a structure with pore mouths filled by an electrolyte meniscus. Also the effect of an electrolyte meniscus between spherical agglomerates was investigated.
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| 47. |
- Fontes, Eduardo, et al.
(author)
-
Effects of different design parameters on the performance of MCFC cathodes
- 1996
-
In: Electrochimica Acta. - 0013-4686. ; 41:1, s. 1-13
-
Journal article (peer-reviewed)abstract
- The effects of electrode thickness, electrolyte filling and current collector geometry on the performance of MCFC cathodes are investigated by using a steady state mathematical model. A two-dimensional pseudo-homogeneous model for the three-phase system in the cathode is used, which includes the polarisation curves from the heterogeneous agglomerate model[1] as local source functions. The model takes into account the potential distribution in the electrolyte and catalyst phase but neglects mass transport limitations in the gas phase. The simulations show that, for cathodes with a finite electronic conductivity, there is a substantial potential distribution perpendicular to the depth of the electrode depending on the size of the gas holes in the current collector.
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| 48. |
- Fontes, Eduardo, et al.
(author)
-
Influence of gas phase mass transfer limitations on molten carbonate fuel cell cathodes
- 1997
-
In: Journal of Applied Electrochemistry. - 0021-891X .- 1572-8838. ; 27:10, s. 1149-1156
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Journal article (peer-reviewed)abstract
- The purpose of this paper is to elucidate to what extent mass transfer limitations in the gas phase affect the performance of porous molten carbonate fuel cell cathodes. Experimental data from porous nickel oxide cathodes and calculated data are presented. One and two-dimensional models for the current collector and electrode region have been used. Shielding effects of the current collector are taken into account. The mass balance in the gas phase is taken into account by using the Stefan-Maxwell equation. For standard gas composition and normal operating current density, the effect of gas-phase diffusion is small. The diffusion in the gaseous phase must be considered at operation at higher current densities. For low oxygen partial pressures, the influence of mass transfer limitations is large, even at low current densities. To eliminate the influence of conversion on polarization curves recorded on laboratory cell units, measurements should always be performed with a five to tenfold stoichiometric excess of oxygen. Two-dimensional calculations show rather large concentration gradients in directions parallel to the current collector. However, the influence on electrode performance is still small, which is explained by the fact that most of the current is produced close to the electrolyte matrix.
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- Fontes, Eduardo, et al.
(author)
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Mathematical modelling of the MCFC cathode : On the linear polarisation of the NiO cathode
- 1997
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In: Journal of Electroanalytical Chemistry. - 0022-0728 .- 1873-2569. ; 432:1-2, s. 121-128
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Journal article (peer-reviewed)abstract
- Experimental polarisation curves for the porous lithiated NiO cathode used in molten carbonate fuel cells very often exhibit a linear shape over a wide potential range. It is shown by means of mathematical modelling that this linear behaviour can be explained by the interplay of intrinsic electrode kinetics, diffusion of electroactive species through an electrolyte film and the effective ohmic resistance of the pore electrolyte, providing that the cathodic transfer coefficient has a value of about 1.5. In contrast, with the generally assumed value of 0.5 of this transfer coefficient and with reasonable values of the effective electrolyte conductivity, predicted polarisation curves will always bend downwards over the overvoltage region of interest. The evolution of the polarisation curves with increasing electrolyte fill can be simulated by a model according to which the electroactive surface area becomes gradually blocked with the increasing amount of electrolyte.
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