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Sökning: WFRF:(Umair Muhammad) > (2020-2023)

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1.
  • Bhatti, Adeel Liaquat, et al. (författare)
  • An Efficient and Functional Fe3O4/Co3O4 Composite for Oxygen Evolution Reaction
  • 2021
  • Ingår i: Journal of Nanoscience and Nanotechnology. - : AMER SCIENTIFIC PUBLISHERS. - 1533-4880 .- 1533-4899. ; 21:4, s. 2675-2680
  • Tidskriftsartikel (refereegranskat)abstract
    • The design of efficient, stable, durable and noble metal free electro catalysts for oxygen evolution reaction (OER) are of immediate need, but very challenging task. In this study, iron induction into cobalt oxide (Co3O4) has resulted composite structure by wet chemical method. The iron impurity has brought an electronic disorder into Fe3O4/cobalt oxide composite thereby efficient oxygen evolution reaction is demonstrated. An addition of iron content into composite resulted the alternation of morphology from Nano rods to clusters of nanoparticles. The successive addition of iron into composite system reduced the onset potential of OER as compared to the pristine cobalt oxide. A Tafel slope of 80 mVdec(-1) indicates the favorable oxygen evolution reaction kinetics on the sample 4. An over-potential of 370 mV is required to reach a 10 mAcm(-2) current density which is acceptable for a nonprecious catalyst. The catalyst is highly durable and stable for 30 hours. Electrochemical impedance spectroscopy further provided a deeper insight on charge transfer resistance and sample 4 has low charge transfer resistance that supported the OER polarization curves. The sample 4 has more electrochemical active surface area of 393.5 cm(2). These obtained results are exciting and highlighting the importance of composite structure and leave a huge space for the future investigations on composite materials for energy related applications.
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2.
  • Arslan, Muhammad, et al. (författare)
  • Impact of Varying Load Conditions and Cooling Energy Comparison of a Double-Inlet Pulse Tube Refrigerator
  • 2020
  • Ingår i: Processes. - : MDPI. - 2227-9717. ; 8:3
  • Tidskriftsartikel (refereegranskat)abstract
    • Modeling and optimization of a double-inlet pulse tube refrigerator (DIPTR) is very difficult due to its geometry and nature. The objective of this paper was to optimize-DIPTR through experiments with the cold heat exchanger (CHX) along the comparison of cooling load with experimental data using different boundary conditions. To predict its performance, a detailed two-dimensional DIPTR model was developed. A double-drop pulse pipe cooler was used for solving continuity, dynamic and power calculations. External conditions for applicable boundaries include sinusoidal pressure from an end of the tube from a user-defined function and constant temperature or limitations of thermal flux within the outer walls of exchanger walls under colder conditions. The results of the system's cooling behavior were reported, along with the connection between the mass flow rates, heat distribution along pulse tube and cold-end pressure, the cooler load's wall temp profile and cooler loads with varied boundary conditions i.e. opening of 20% double-inlet and 40-60% orifice valves, respectively. Different loading conditions of 1 and 5W were applied on the CHX. At 150 K temperature of the cold-end heat exchanger, a maximum load of 3.7 W was achieved. The results also reveal a strong correlation between computational fluid dynamics modeling results and experimental results of the DIPTR.
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3.
  • Bhatti, Adeel Liaquat, et al. (författare)
  • Facile doping of nickel into Co3O4 nanostructures to make them efficient for catalyzing the oxygen evolution reaction
  • 2020
  • Ingår i: RSC Advances. - : Royal Society of Chemistry. - 2046-2069. ; 10:22, s. 12962-12969
  • Tidskriftsartikel (refereegranskat)abstract
    • Designing a facile and low-cost methodology to fabricate earth-abundant catalysts is very much needed for a wide range of applications. Herein, a simple and straightforward approach was developed to tune the electronic properties of cobalt oxide nanostructures by doping them with nickel and then using them to catalyze the oxygen evolution reaction (OER) in an aqueous solution of 1.0 M KOH. The addition of a nickel impurity improved the conductivity of the cobalt oxide, and further increased its activity towards the OER. Analytical techniques such as scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and powder X-ray diffraction (XRD) were used to investigate, respectively, the morphology, composition and crystalline structure of the materials used. The nickel-doped cobalt oxide material showed randomly oriented nanowires and a high density of nanoparticles, exhibited the cubic phase, and contained cobalt, nickel and oxygen as its main elements. The nickel-doped cobalt oxide also yielded a Tafel slope of 82 mV dec(-1) and required an overpotential of 300 mV to reach a current density of 10 mA cm(-2). As an OER catalyst, it was shown to be durable for 40 h. Electrochemical impedance spectroscopy (EIS) analysis showed a low charge-transfer resistance of 177.5 ohms for the nickel-doped cobalt oxide, which provided a further example of its excellent OER performance. These results taken together indicated that nickel doping of cobalt oxide can be accomplished via a facile approach and that the product of this doping can be used for energy and environmental applications.
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4.
  • Hanan, Abdul, et al. (författare)
  • PdO@CoSe2 composites: efficient electrocatalysts for water oxidation in alkaline media
  • 2022
  • Ingår i: RSC Advances. - : ROYAL SOC CHEMISTRY. - 2046-2069. ; 13:1, s. 743-755
  • Tidskriftsartikel (refereegranskat)abstract
    • In this study, we have prepared cobalt selenide (CoSe2) due to its useful aspects from a catalysis point of view such as abundant active sites from Se edges, and significant stability in alkaline conditions. CoSe2, however, has yet to prove its functionality, so we doped palladium oxide (PdO) onto CoSe2 nanostructures using ultraviolet (UV) light, resulting in an efficient and stable water oxidation composite. The crystal arrays, morphology, and chemical composition of the surface were studied using a variety of characterization techniques, including X-ray diffraction (XRD), scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared (FTIR) spectroscopy. It was also demonstrated that the composite systems were heterogeneous in their morphology, undergoing a shift in their diffraction patterns, suffering from a variety of metal oxidation states and surface defects. The water oxidation was verified by a low overpotential of 260 mV at a current density of 20 mA cm(-2) with a Tafel Slope value of 57 mV dec(-1). The presence of multi metal oxidation states, rich surface edges of Se and favorable charge transport played a leading role towards water oxidation with a low energy demand. Furthermore, 48 h of durability is associated with the composite system. With the use of PdO and CoSe2, new, low efficiency, simple electrocatalysts for water catalysis have been developed, enabling the development of practical energy conversion and storage systems. This is an excellent alternative approach for fostering growth in the field.
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5.
  • Adelani, David, et al. (författare)
  • A Few Thousand Translations Go A Long Way! Leveraging Pre-trained Models for African News Translation
  • 2022
  • Ingår i: NAACL 2022. - Stroudsburg : Association for Computational Linguistics. - 9781955917711 ; , s. 3053-3070
  • Konferensbidrag (refereegranskat)abstract
    • Recent advances in the pre-training of language models leverage large-scale datasets to create multilingual models. However, low-resource languages are mostly left out in these datasets. This is primarily because many widely spoken languages are not well represented on the web and therefore excluded from the large-scale crawls used to create datasets. Furthermore, downstream users of these models are restricted to the selection of languages originally chosen for pre-training. This work investigates how to optimally leverage existing pre-trained models to create low-resource translation systems for 16 African languages. We focus on two questions: 1) How can pre-trained models be used for languages not included in the initial pre-training? and 2) How can the resulting translation models effectively transfer to new domains? To answer these questions, we create a new African news corpus covering 16 languages, of which eight languages are not part of any existing evaluation dataset. We demonstrate that the most effective strategy for transferring both to additional languages and to additional domains is to fine-tune large pre-trained models on small quantities of high-quality translation data.
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6.
  • Aftab, Umair, et al. (författare)
  • Mixed CoS2@Co3O4 composite material: An efficient nonprecious electrocatalyst for hydrogen evolution reaction
  • 2020
  • Ingår i: International journal of hydrogen energy. - : PERGAMON-ELSEVIER SCIENCE LTD. - 0360-3199 .- 1879-3487. ; 45:27, s. 13805-13813
  • Tidskriftsartikel (refereegranskat)abstract
    • Hydrogen evolution reaction (HER) has been identified as a sustainable and environment friendly technology for a wide range of energy conversion and storage applications. The big barrier in realizing this green technology requires a highly efficient, earth-abundant, and low-cost electrocatalyst for HER. Various HER catalysts have been designed and reported, still, their performance is not up to the mark of Pt. Among them, cobalt-based, especially cobalt disulfide (CoS2) has shown significant HER activity and found suitable candidature for HER due to its low cost, simple to prepare, and exhibits good stability. Herein, we synthesized various nanostructured materials including pure CoS2, Co3O4 and their composites by wet chemical methods and found them active for HER. The scanning electron microscopy (SEM) has revealed a morphology of composite as a mixture of nanowires and round shape spherical nanoparticles with several microns in dimension. The X-ray diffraction (XRD) confirmed the cubic phase of CoS2 and cubic phase of Co3O4 in the composite materials. The chemical deposition of CoS2 onto Co3O4 has tailored the HER activity of CoS2@Co3O4 composite material. Two CoS2@Co3O4 composite materials were produced with varying amounts of Co3O4 and labeled as samples 1 and 2. The Co3O4 reduced the adsorption energy for hydrogen, decreased the aggregation of CoS2 and uplifted the stability of CoS2@Co3O4 a composite material in alkaline media. Sample 1 requires an overpotential of 320 mV to reach a current density of 10 mA/cm(2) and it exhibits a Tafel slope of 42 mVdec(-1) which is the key indicator for the fast HER kinetics on sample 1. The sample 1 is highly durable for 50 h and also it has excellent stability. The electrochemical impedance spectroscopy (EIS) revealed a small charge transfer resistance of 28.81 Ohms for the sample 1 with high capacitance double-layer value of 0.81 mF. EIS has supported polarization and Tafel slope results. Based on the partial physical characterization and the electrochemical results, the as-obtained sample 1 (CoS2@Co3O4 composite material) will find potential applications in an extended range of energy conversion and storage devices owing to its low cost, high abundance, and excellent efficiency. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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7.
  • Aftab, Umair, et al. (författare)
  • Nickel-cobalt bimetallic sulfide NiCo(2)S(4)nanostructures for a robust hydrogen evolution reaction in acidic media
  • 2020
  • Ingår i: RSC Advances. - : Royal Society of Chemistry. - 2046-2069. ; 10:37, s. 22196-22203
  • Tidskriftsartikel (refereegranskat)abstract
    • There are many challenges associated with the fabrication of efficient, inexpensive, durable and very stable nonprecious metal catalysts for the hydrogen evolution reaction (HER). In this study, we have designed a facile strategy by tailoring the concentration of precursors to successfully obtain nickel-cobalt bimetallic sulfide (NiCo2S4) using a simple hydrothermal method. The morphology of the newly prepared NiCo(2)S(4)comprised a mixture of microparticles and nanorods, which were few microns in dimension. The crystallinity of the composite sample was found to be excellent with a cubic phase. The sample that contained a higher amount of cobalt compared to nickel and produced single-phase NiCo(2)S(4)exhibited considerably improved HER performance. The variation in the salt precursor concentration during the synthesis of a material is a simple methodology to produce a scalable platinum-free catalyst for HER. The advantageous features of the multiple active sites of cobalt in the CN-21 sample as compared to that for pristine CoS and NiS laid the foundation for the provision of abundant active edges for HER. The composite sample produced a current density of 10 mA cm(-2)at an overpotential of 345 mV. Also, it exhibited a Tafel value of 60 mV dec(-1), which predominantly ensured rapid charge transfer kinetics during HER. CN-21 was highly durable and stable for 30 hours. Electrochemical impedance spectroscopy showed that the charge transfer resistance was 21.88 ohms, which further validated the HER polarization curves and Tafel results. CN-21 exhibited a double layer capacitance of 4.69 mu F cm(-2)and a significant electrochemically active surface area of 134.0 cm(2), which again supported the robust efficiency for HER. The obtained results reveal that our developed NiCo(2)S(4)catalyst has a high density of active edges, and it is a non-noble metal catalyst for the hydrogen evolution reaction. The present findings provide an alternative strategy and an active nonprecious material for the development of energy-related applications.
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8.
  • Aftab, Umair, et al. (författare)
  • Two step synthesis of TiO2–Co3O4 composite for efficient oxygen evolution reaction
  • 2021
  • Ingår i: International journal of hydrogen energy. - : Elsevier. - 0360-3199 .- 1879-3487. ; 46:13, s. 9110-9122
  • Tidskriftsartikel (refereegranskat)abstract
    • For an active hydrogen gas generation through water dissociation, the sluggish oxygen evolution reaction (OER) kinetics due to large overpotential is a main hindrance. Herein, a simple approach is used to produce composite material based on TiO2/Co3O4 for efficient OER and overpotential is linearly reduced with increasing amount of TiO2. The scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM) investigations reveal the wire like morphology of composite materials, formed by the self-assembly of nanoparticles. The titania nanoparticles were homogenously distributed on the larger Co3O4 nanoparticles. The powder x-ray diffraction revealed a tetragonal phase of TiO2 and the cubic phase of Co3O4 in the composite materials. Composite samples with increasing TiO2 content were obtained (18%, 33%, 41% and 65% wt.). Among the composites, cobalt oxide-titanium oxide with the highest TiO2 content (CT-20) possesses the lowest overpotential for OER with a Tafel slope of 60 mV dec−1 and an exchange current density of 2.98 × 10−3A/cm2. The CT-20 is highly durable for 45 h at different current densities of 10, 20 and 30 mA/cm2. Electrochemical impedance spectroscopy (EIS) confirmed the fast charge transport for the CT-20 sample, which potentially accelerated the OER kinetics. These results based on a two-step methodology for the synthesis of TiO2/Co3O4 material can be useful and interesting for various energy storage and energy conversion systems.
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9.
  • Amin, Muhammad Umair, et al. (författare)
  • Co-delivery of carbonic anhydrase IX inhibitor and doxorubicin as a promising approach to address hypoxia-induced chemoresistance
  • 2022
  • Ingår i: Drug Delivery. - : Informa UK Limited. - 1071-7544 .- 1521-0464. ; 29:1, s. 2072-2085
  • Tidskriftsartikel (refereegranskat)abstract
    • Hypoxia, an oxygen-deprived condition of the tumor, is one of the major reasons for resistance to chemotherapy. Carbonic anhydrases are generally involved in pH homeostasis in normal conditions, but in solid tumors having a strong relation with hypoxia, the carbonic anhydrase IX (CA-IX) enzyme is overexpressed and results in an extracellular acidic environment. For most weakly basic anticancer drugs, including doxorubicin (Dox), the ionization in an acidic environment limits their cellular uptake, and consequently, the tumor exposure to the drug at sub-therapeutic concentration comes out as chemoresistance. Herein, a combined drug delivery system of liposomes and mesoporous silica nanoparticles (MSNPs) was developed for the co-delivery of the CA-IX enzyme inhibitor and Dox in hypoxic condition. The unique structure of MSNPs with higher surface area was utilized for higher drug loading and sustained release of Dox. Additionally, the biocompatible nature of liposomal coating as a second loading site for the CA-IX enzyme inhibitor has provided gatekeeping effects at pore opening to avoid premature drug release. Lipid coated MSNPs as a co-delivery system for Dox and the CA-IX inhibitor have synergistic cytotoxic effects against MDA-MB 231 breast cancer cells in hypoxic conditions. These findings assure the potential of this drug delivery system to overcome hypoxia-related chemoresistance.
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10.
  • Amin, Muhammad Umair, et al. (författare)
  • Ultrasound-Responsive Smart Drug Delivery System of Lipid Coated Mesoporous Silica Nanoparticles
  • 2021
  • Ingår i: Pharmaceutics. - : MDPI. - 1999-4923. ; 13:9
  • Tidskriftsartikel (refereegranskat)abstract
    • The immediate release of chemotherapeutics at the target site, along with no premature release in circulation is always challenging. The purpose of this study was to develop a stimuli responsive drug delivery system, composed of lipid supported mesoporous silica nanoparticles (MSNPs) for triggered drug release at the target site and simultaneously avoiding the premature release. MSNPs with a higher drug loading capacity and very slow release were designed so as to enhance release by FDA approved US-irradiation. Doxorubicin, as a model drug, and perfluoropentane (PFP) as a US responsive material, were entrapped in the porous structure of MSNPs. Lipid coating enhanced the cellular uptake and in addition provided a gatekeeping effect at the pore opening to reduce premature release. The mechanical and thermal effects of US induced the conversion of liquid PFP to a gaseous form that was able to rupture the lipid layer, resulting in triggered drug release. The prolonged stability profile and non-toxic behavior made them suitable candidate for the delivery of anticancer drugs. This smart system, with the abilities of better cellular uptake and higher cytotoxic effects on US-irradiation, would be a good addition to the applied side of chemotherapeutic advanced drug delivery systems.
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11.
  • Manzoor, Numair, et al. (författare)
  • RETRACTED: Experimental Study of CO2 Conversion into Methanol by Synthesized Photocatalyst (ZnFe2O4/TiO2) Using Visible Light as an Energy Source
  • 2020
  • Ingår i: Catalysts. - : MDPI. - 2073-4344. ; 10:2
  • Tidskriftsartikel (refereegranskat)abstract
    • Ozone layer depletion is a serious threat due to the extensive release of greenhouse gases. The emission of carbon dioxide (CO2) from fossil fuel combustion is a major reason for global warming. Energy demands and climate change are coupled with each other. CO2is a major gas contributing to global warming; hence, the conversion of CO2 into useful products such as methanol, formic acid, formaldehyde, etc., under visible light is an attractive topic. Challenges associated with the current research include synthesizing a photocatalyst that is driven by visible light with a narrow band gap range between 2.5 and 3.0 eV, the separation of a mixed end product, and the two to three times faster recombination rate of an electron–hole pair compared with separation over yield. The purpose of the current research is to convert CO2 into useful fuel i.e., methanol; the current study focuses on the photocatalytic reduction of CO2into a useful product. This research is based on the profound analysis of published work, which allows the selection of appropriate methods and material for this research. In this study, zinc ferrite (ZnFe2O4) is synthesized via the modified sol–gel method and coupled with titanium dioxide (TiO2). Thereafter, the catalyst is characterized by Fourier transform infrared (FTIR), FE-SEM, UV–Vis, and XRD characterization techniques. UV–Vis illustrates that the synthesized catalyst has a low band gap and utilizes a major portion of visible light irradiation. The XRD pattern was confirmed by the formation of the desired catalyst. FE-SEM illustrated that the size of the catalyst ranges from 50 to 500 nm and BET analysis determined the surface area, which was 2.213 and 6.453 m2/g for ZnFe2O4 and ZnFe2O4/TiO2, respectively. The continuous gas flow photoreactor was used to study the activity of the synthesized catalyst, while titanium dioxide (TiO2) has been coupled with zinc ferrite (ZnFe2O4) under visible light in order to obtain the maximum yield of methanol as a single product and simultaneously avoid the conversion of CO2 into multiple products. The performance of ZnFe2O4/TiO2was mainly assessed through methanol yield with a variable amount of TiO2 over ZnFe2O4 (1:1, 1:2, 2:1, 1:3, and 3:1). The synthesized catalyst recycling ability has been tested up to five cycles. Finally, we concluded that the optimum conditions for maximum yield were found to be a calcination temperature of ZnFe2O4at 900 °C, and optimum yield was at a 1:1 w/w coupling ratio of ZnFe2O4/TiO2. It was observed that due to the enhancement in the electron–hole pair lifetime, the methanol yield at 141.22 μmol/gcat·h over ZnFe2O4/TiO2was found to be 7% higher than the earlier reported data.
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12.
  • Solangi, Muhammad Yameen, et al. (författare)
  • In-situ growth of nonstoichiometric CrO0.87 and Co3O4 hybrid system for the enhanced electrocatalytic water splitting in alkaline media
  • 2023
  • Ingår i: International journal of hydrogen energy. - : PERGAMON-ELSEVIER SCIENCE LTD. - 0360-3199 .- 1879-3487. ; 48:93, s. 36439-36451
  • Tidskriftsartikel (refereegranskat)abstract
    • The development of electrocatalysts for electrochemical water splitting has received considerable attention in response to the growing demand for renewable energy sources and environmental concerns. In this study, a simple hydrothermal growth approach was developed for the in-situ growth of non-stoichiometric CrO0.87 and Co3O4 hybrid materials. It is apparent that the morphology of the prepared material shows a heterogeneous aggregate of irregularly shaped nanoparticles. Both CrO0.87 and Co3O4 have cubic crystal structures. Its chemical composition was governed by the presence of Co, Cr, and O as its main constituents. For understanding the role CrO0.87 plays in the half-cell oxygen evolu-tion reaction (OER) in alkaline conditions, CrO0.87 was optimized into Co3O4 nanostructures. The hybrid material with the highest concentration of CrO0.87 was found to be highly efficient at driving OER reactions at 255 mV and 20 mA cm(-2). The optimized material demonstrated excellent durability for 45 h and a Tafel slope of 56 mV dec(-1). Several factors may explain the outstanding performance of CrO0.87 and Co3O4 hybrid materials, including multiple metallic oxidation states, tailored surface properties, fast charge transport, and surface defects. An alternative method is proposed for the preparation of new generations of electrocatalysts for the conversion and storage of energy. (c) 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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13.
  • Abbasi, Amir Zaib, et al. (författare)
  • Engagement in educational games and quality of life in early and middle childhood : evidence from a developing country
  • 2023
  • Ingår i: Current Psychology. - : Springer. - 1046-1310 .- 1936-4733. ; 42, s. 19386-19400
  • Tidskriftsartikel (refereegranskat)abstract
    • Serious games (SGs), are gaining prominence as a tool for early education at home as well as in school settings. Given the mixed effects of gamification on various aspects of users' lives, it is pertinent to study its broader effects on a child's pre-school and school years. Given the lack of consensus on a comprehensive measure that encapsulates these effects on an individual's routine functioning, the present study examined whether various engagement states in SGs use influence a relatively broader measure of users' functioning across significant life domains such as Quality of Life (QoL). It is argued that it would serve scholars, teachers, and parents better to understand the broader implications of SGs on children's overall QoL rather than isolated physiological and behavioral effects. Consequently, utilizing structural equation modeling, results from 335 parents of 2-10-year-olds in a developing country showed that cognitive and behavioral engagement in gamified applications appear to influence the child's QoL, but not affective engagement. Results are discussed in terms of the consequences of using game-based technology for a child's development, with far-reaching academic, personal, physical, and social implications not only for the school-going ages, but also for early teenage years. The results are promising in relation to QoL. The findings indicate the role modern technology plays in improving individuals' lives. The findings provide scholars, parents, and creators of SGs important information for their plan of action regarding children's exposure to SGs and making SGs a frequent aspect of the learning experience early in life.
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14.
  • Ahmed Khand, Aftab, et al. (författare)
  • Synthesis of Sheet Like Nanostructures of NiO Using Potassium Dichromate as Surface Modifying Agent for the Sensitive and Selective Determination of Amlodipine Besylate (ADB) Drug
  • 2021
  • Ingår i: Electroanalysis. - : WILEY-V C H VERLAG GMBH. - 1040-0397 .- 1521-4109. ; 33:5, s. 1121-1128
  • Tidskriftsartikel (refereegranskat)abstract
    • The monitoring of hypertension drugs is very critical and important to sustain a healthy life. In this study, we have synthesized nickel oxide (NiO) nanostructures using potassium dichromate as surface modifying agent by hydrothermal method. These NiO nanostructures were found highly active for the oxidation of ADB besylate (ADB). The unit cell structure and morphology were investigated by scanning electron microscopy (SEM) and powder X-ray diffraction (XRD) techniques. The SEM study has confirmed the nano sheet like morphology and XRD analysis has described the cubic unit arrays of NiO. After the physical characterization, NiO nanostructures were used to modify the surface of glassy carbon electrode (GCE) by drop casting method. Then cyclic voltammetry (CV) was used to characterize the electrochemical activity of NiO nanostructures in the0.1 M phosphate buffer solution of pH 10.0 and a well resolved oxidation peak was identified at 0.70 V. The linear range for the NiO nanostructures was observed from 20-90 nM with a regression coefficient of 0.99 using CV. The calculated limit of detection (LOD) was 2.125 nM and the limit of quantification (LOQ) was 4.08 nM. Further to validate the CV calibration plot, an amperometry experiment was performed on the NiO nanostructures and sensors exhibited a linear range of 10 nM to 115 nM with LOD of 1.15 nM. The proposed approach was successfully used for the determination of ADB from commercial tablets and it reveals that the sensor could be capitalized to monitor ADB concentrations from pharmaceutical products. The use of potassium dichromate as a surface modifying agent for the metal oxide nanostructures may be of great interest to manipulate their crystal and surface properties for the extended range of biomedical and energy related applications.
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15.
  • Alfaras, Miquel, et al. (författare)
  • Biosensing and Actuation-Platforms Coupling Body Input-Output Modalities for Affective Technologies
  • 2020
  • Ingår i: Sensors. - : MDPI AG. - 1424-8220. ; 20:21
  • Tidskriftsartikel (refereegranskat)abstract
    • Research in the use of ubiquitous technologies, tracking systems and wearables within mental health domains is on the rise. In recent years, affective technologies have gained traction and garnered the interest of interdisciplinary fields as the research on such technologies matured. However, while the role of movement and bodily experience to affective experience is well-established, how to best address movement and engagement beyond measuring cues and signals in technology-driven interactions has been unclear. In a joint industry-academia effort, we aim to remodel how affective technologies can help address body and emotional self-awareness. We present an overview of biosignals that have become standard in low-cost physiological monitoring and show how these can be matched with methods and engagements used by interaction designers skilled in designing for bodily engagement and aesthetic experiences. Taking both strands of work together offers unprecedented design opportunities that inspire further research. Through first-person soma design, an approach that draws upon the designer's felt experience and puts the sentient body at the forefront, we outline a comprehensive work for the creation of novel interactions in the form of couplings that combine biosensing and body feedback modalities of relevance to affective health. These couplings lie within the creation of design toolkits that have the potential to render rich embodied interactions to the designer/user. As a result we introduce the concept of "orchestration". By orchestration, we refer to the design of the overall interaction: coupling sensors to actuation of relevance to the affective experience; initiating and closing the interaction; habituating; helping improve on the users' body awareness and engagement with emotional experiences; soothing, calming, or energising, depending on the affective health condition and the intentions of the designer. Through the creation of a range of prototypes and couplings we elicited requirements on broader orchestration mechanisms. First-person soma design lets researchers look afresh at biosignals that, when experienced through the body, are called to reshape affective technologies with novel ways to interpret biodata, feel it, understand it and reflect upon our bodies.
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16.
  • Alfaras, Miquel, et al. (författare)
  • From Biodata to Somadata
  • 2020
  • Konferensbidrag (refereegranskat)abstract
    • Biosensing technologies are increasingly available as off-the-shelf products, yet for many designers, artists and non-engineers, these technologies remain difficult to design with. Through a soma design stance, we devised a novel approach for exploring qualities in biodata. Our explorative process culminated in the design of three artefacts, coupling biosignals to tangible actuation formats. By making biodata perceivable as sound, in tangible form or directly on the skin, it became possible to link qualities of the measurements to our own somatics - our felt experience of our bodily bioprocesses - as they dynamically unfold, spurring somatically-grounded design discoveries of novel possible interactions. We show that making biodata attainable for a felt experience - or as we frame it: turning biodata into somadata - enables not only first-person encounters, but also supports collaborative design processes as the somadata can be shared and experienced dynamically, right at the moment when we explore design ideas.
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17.
  • Bhatti, Adeel Liaquat, et al. (författare)
  • Nanostructured Co3O4 electrocatalyst for OER : The role of organic polyelectrolytes as soft templates
  • 2021
  • Ingår i: Electrochimica Acta. - : Elsevier. - 0013-4686 .- 1873-3859. ; 398
  • Tidskriftsartikel (refereegranskat)abstract
    • Designing an efficient electrocatalyst for the oxygen evolution reaction (OER) in alkaline media is highly needed but very challenging task. Herein, we used organic polyelectrolytes such as (carboxymethyl cellulose) CMC and polyacrylamide polymers for the growth of Co3O4 nanostructures by aqueous chemical growth method. The morphology and composition studies were performed on scanning electron microscopy (SEM), energy dispersive X-ray (EDX), powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and high-resolution transmission electron microscopy (HRTEM) techniques. The structural properties and the surface chemistry of the Co3O4 electrocatalysts were correlated to the OER performance, and the enhancement mechanism with respect to pristine Co3O4 was observed to be specifically related to the polyelectrolyte templating role.Co3O4@CMC composites displayed reduced crystallite size, producing OER overpotential as low as 290 mV at 10 mAcm−2 in 1.0 KOH and Tafel slope of 71 mVdec−1, suggesting fast transfer of intermediates and electrons during water electrolysis. On the other hand, the use of polyacrylamide and its different templating mechanism resulted in similar crystallite size, but preferential exposed faces and larger surface vacancies content, as demonstrated by HR-TEM and XPS, respectively. Consistently, this material displays cutting-edge OER performance, such as overpotential of 260 mV at 10 mAcm−2 and a low Tafel slope of 63 mVdec−1. The proposed strategy for the preparation of Co3O4 nanostructures in the presence of CMC and polyacrylamide is facile, mass production, thus it could equally contributed towards the realization of hydrogen energy. Therefore, these nanostructures of Co3O4 can be regarded as an alternative and promising materials for the different electrochemical applications including fuel cells, metal air batteries, overall water electrolysis and other energy storage devices.
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18.
  • Claisse, Caroline, et al. (författare)
  • Tangible Interaction for Supporting Well-being
  • 2022
  • Ingår i: CHI EA '22. - New York, NY, USA : Association for Computing Machinery (ACM). - 9781450391566
  • Konferensbidrag (refereegranskat)abstract
    • Our workshop aims to bring together researchers and practitioners across disciplines in HCI who share an interest in promoting well-being through tangible interaction. The workshop forms an impassioned response to the worldwide push towards more digital and remote interaction in nearly all domains of our lives in the context of the COVID-19 pandemic. One question we raise is: to what extent will measures like remote interaction remain in place post-pandemic, and to what extent these changes may influence future agendas for the design of interactive products and services to support living well? We aim to ensure that the workshop serves as a space for diverse participants to share ideas and engage in cooperative discussions through hands-on activities resulting in the co-creation of a Manifesto to demonstrate the importance of embodied and sensory interaction for supporting well-being in a post-pandemic context. All the workshop materials will be published online on the workshop website and disseminated through ongoing collaboration.
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19.
  • Höök, Kristina, 1964-, et al. (författare)
  • Unpacking Non-Dualistic Design : The Soma Design Case
  • 2021
  • Ingår i: ACM Transactions on Computer-Human Interaction. - : Association for Computing Machinery (ACM). - 1073-0516 .- 1557-7325. ; 28:6
  • Tidskriftsartikel (refereegranskat)abstract
    • We report on a somaesthetic design workshop and the subsequent analytical work aiming to demystify what is entailed in a non-dualistic design stance on embodied interaction and why a first-person engagement is crucial to its unfoldings. However, as we will uncover through a detailed account of our process, these first-person engagements are deeply entangled with second- and third-person perspectives, sometimes even overlapping. The analysis furthermore reveals some strategies for bridging the body-mind divide by attending to our inner universe and dissolving or traversing dichotomies between inside and outside; individual and social; body and technology. By detailing the creative process, we show how soma design becomes a process of designing with and through kinesthetic experience, in turn letting us confront several dualisms that run like fault lines through HCI's engagement with embodied interaction.
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20.
  • Khokhar, Shams Parveen, et al. (författare)
  • An Efficient Nickel Sulfide@NiO Nanocomposite Catalyst with High Density of Active Sites for the Hydrogen Evolution Reaction in Alkaline Media
  • 2021
  • Ingår i: Journal of Nanoscience and Nanotechnology. - : AMER SCIENTIFIC PUBLISHERS. - 1533-4880 .- 1533-4899. ; 21:4, s. 2520-2528
  • Tidskriftsartikel (refereegranskat)abstract
    • Efficient hydrogen evolution reaction (HER) catalysts based on the earth-abundant materials are highly vital to design practical and environmentally friendly water splitting devices. In this study, we present an optimized strategy for the development of active catalysts for hydrogen evolution reaction HER. The composite catalysts are prepared with the nanosurface of NiO for the deposition of NiS by hydrothermal method. In alkaline electrolyte, the NIS/NiO nanocomposite has shown excellent catalytic HER properties at the low onset potential and small Tafel slope of 72 mV dec(-1). A current density of 10 mA/cm(2) is achieved by the nanocomposite obtained with 0.4 gram of NiO as nanosurface for the deposition of NiS (sample 4) at the cost of 429 mV versus RHE. The sample 4 carries more active sites that allow it to act as excellent HER catalyst. Based on this study, we conclude that increasing the nickel oxide content into composite sample facilitates the HER process. Additionally, a long term HER stability for 10 hours and good durability is also demonstrated by the sample 4. Our findings reveal that the optimization of nickel oxide content in the preparation of catalyst leads to the excellent HER activity for the design of practical water splitting devices and other related applications.
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21.
  • Lim, Yeong Jer, et al. (författare)
  • COVID‐19 outcomes in haematopoietic cell transplant recipients : A systematic review and meta‐analysis
  • 2022
  • Ingår i: eJHaem. - USA : John Wiley & Sons. - 2688-6146. ; 3:3, s. 862-872
  • Tidskriftsartikel (refereegranskat)abstract
    • Up-to-date information on coronavirus disease 2019 (COVID-19) outcomes and risk factors in haematopoietic cell transplantation (HCT) recipients is required to inform on decisions about cancer treatment and COVID-19 mitigation strategies. We performed a meta-analysis to address this knowledge gap. All studies with at least five patients who reported COVID-19-related deaths in HCT recipients were included. The primary outcome was COVID-19-related death. Secondary outcomes were COVID-19-related mechanical ventilation (MV) and intensive care unit (ITU) admission. The cumulative COVID-19-related death rate among HCT recipients was 21% (95% confidence interval [CI] 18%–24%), while MV and ITU admission rates were 14% (95% CI 11%–17%) and 18% (95% CI 14%–22%), respectively. Subgroup analysis showed higher death rates in patients who developed COVID-19 within 12 months of HCT (risk ratio [RR] 1.82, 95% CI 1.09–3.03), within 6 months of receiving immunosuppressant drugs (RR 2.11, 95% CI 1.38–3.20) or in the context of active graft-versus-host disease (RR 2.38, 95% CI 1.10–5.16). Our findings support the idea that HCT should remain an integral part of cancer treatment during the COVID-19 pandemic but also highlight the need to prioritise preventative measures in those patients who are at increased risk of adverse COVID-19 outcomes.
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22.
  • Mugheri, Abdul Qayoom, et al. (författare)
  • A Low Charge Transfer Resistance CuO Composite for Efficient Oxygen Evolution Reaction in Alkaline Media
  • 2021
  • Ingår i: Journal of Nanoscience and Nanotechnology. - : AMER SCIENTIFIC PUBLISHERS. - 1533-4880 .- 1533-4899. ; 21:4, s. 2613-2620
  • Tidskriftsartikel (refereegranskat)abstract
    • An efficient, simple, environment-friendly and inexpensive cupric oxide (CuO) electrocatalyst for oxygen evolution reaction (OER) is demonstrated. CuO is chemically deposited on the porous carbon material obtained from the dehydration of common sugar. The morphology of CuO on the porous carbon material is plate-like and monoclinic crystalline phase is confirmed by powder X-ray diffraction. The OER activity of CuO nanostructures is investigated in 1 M KOH aqueous solution. To date, the proposed electrocatalyst has the lowest possible potential of 1.49 V versus RHE (reversible hydrogen electrode) to achieve a current density of 20 mA/cm(2) among the. CuO based electrocatalysts and has Tafel slope of 115 mV dec(-1). The electrocatalyst exhibits an excellent long-term stability for 6 hours along with significant durability. The enhanced catalytic active centers of CuO on the carbon material are due to the porous structure of carbon as well as strong coupling between CuO-C. The functionalization of metal oxides or other related nanostructured materials on porous carbon obtained from common sugar provides an opportunity for the development of efficient energy conversion and energy storage systems.
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23.
  • Mugheri, Abdul Qayoom, et al. (författare)
  • Chemically Coupled Cobalt Oxide Nanosheets Decorated onto the Surface of Multiwall Carbon Nanotubes for Favorable Oxygen Evolution Reaction
  • 2021
  • Ingår i: Journal of Nanoscience and Nanotechnology. - : AMER SCIENTIFIC PUBLISHERS. - 1533-4880 .- 1533-4899. ; 21:4, s. 2660-2667
  • Tidskriftsartikel (refereegranskat)abstract
    • Cobalt oxide has been widely investigated among potential transition metal oxides for the electrochemical energy conversion, storage, and water splitting. However, they have inherently low electronic conductivity and high corrosive nature in alkaline media. Herein, we propose a promising and facile approach to improve the conductivity and charge transport of cobalt oxide Co3O4 through chemical coupling with well-dispersed multiwall carbon nanotubes (MWCNTs) during hydrothermal treatment. The morphology of prepared composite material consisting of nanosheets which are anchored on the MWCNTs as confirmed by scanning electron microscopy (SEM). A cubic crystalline system is exhibited by the cobalt oxide as confirmed by the X-ray diffraction study. The Co, O, and C are the only elements present in the composite material. FTIR study has indicated the successful coupling of cobalt oxide with MWCNTs. The chemically coupled cobalt oxide onto the surface of MWCNTs composite is found highly active towards oxygen evolution reaction (OER) with a low onset potential 1.44 V versus RHE, low overpotential 262 mV at 10 mAcm(-2) and small Tafel slope 81 mV dec(-1). For continuous operation of 40 hours during durability test, no decay in activity was recorded. Electrochemical impedance study further revealed a low charge transfer resistance of 70.64 Ohms for the composite material during the electrochemical reaction and which strongly favored OER kinetics. This work provides a simple, low cost, and smartly designing electrocatalysts via hydrothermal reaction for the catalysis and energy storage applications.
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24.
  • Nguyen, Thanh N, et al. (författare)
  • Global Impact of the COVID-19 Pandemic on Stroke Volumes and Cerebrovascular Events: A 1-Year Follow-up.
  • 2023
  • Ingår i: Neurology. - 1526-632X. ; 100:4
  • Tidskriftsartikel (refereegranskat)abstract
    • Declines in stroke admission, IV thrombolysis (IVT), and mechanical thrombectomy volumes were reported during the first wave of the COVID-19 pandemic. There is a paucity of data on the longer-term effect of the pandemic on stroke volumes over the course of a year and through the second wave of the pandemic. We sought to measure the effect of the COVID-19 pandemic on the volumes of stroke admissions, intracranial hemorrhage (ICH), IVT, and mechanical thrombectomy over a 1-year period at the onset of the pandemic (March 1, 2020, to February 28, 2021) compared with the immediately preceding year (March 1, 2019, to February 29, 2020).We conducted a longitudinal retrospective study across 6 continents, 56 countries, and 275 stroke centers. We collected volume data for COVID-19 admissions and 4 stroke metrics: ischemic stroke admissions, ICH admissions, IVT treatments, and mechanical thrombectomy procedures. Diagnoses were identified by their ICD-10 codes or classifications in stroke databases.There were 148,895 stroke admissions in the 1 year immediately before compared with 138,453 admissions during the 1-year pandemic, representing a 7% decline (95% CI [95% CI 7.1-6.9]; p < 0.0001). ICH volumes declined from 29,585 to 28,156 (4.8% [5.1-4.6]; p < 0.0001) and IVT volume from 24,584 to 23,077 (6.1% [6.4-5.8]; p < 0.0001). Larger declines were observed at high-volume compared with low-volume centers (all p < 0.0001). There was no significant change in mechanical thrombectomy volumes (0.7% [0.6-0.9]; p = 0.49). Stroke was diagnosed in 1.3% [1.31-1.38] of 406,792 COVID-19 hospitalizations. SARS-CoV-2 infection was present in 2.9% ([2.82-2.97], 5,656/195,539) of all stroke hospitalizations.There was a global decline and shift to lower-volume centers of stroke admission volumes, ICH volumes, and IVT volumes during the 1st year of the COVID-19 pandemic compared with the prior year. Mechanical thrombectomy volumes were preserved. These results suggest preservation in the stroke care of higher severity of disease through the first pandemic year.This study is registered under NCT04934020.
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25.
  • Rafique, Umair, et al. (författare)
  • Uni-Planar MIMO Antenna for Sub-6 GHz 5G Mobile Phone Applications
  • 2022
  • Ingår i: Applied Sciences. - : MDPI AG. - 2076-3417. ; 12:8
  • Tidskriftsartikel (refereegranskat)abstract
    • This article presents the design of a uni-planar MIMO antenna system for sub-6 GHz 5G-enabled smartphones. The MIMO antenna designed comprises four loop-shaped radiators placed at each corner of the mobile phone board, which follows the principle of pattern diversity. The single-antenna element resonates at 3.5 GHz, its impedance bandwidth is noted to be 1.28 GHz (3-4.28 GHz) for S-11 <= -6 dB, and it is equal to 720 MHz (3.18-3.9 GHz) for S-11 <= -10 dB. For a single-antenna element, a peak gain of 3.64 dBi is observed with an antenna efficiency of >90%. The isolation of >10 dB between antenna elements is achieved for the MIMO configuration. Furthermore, the MIMO antenna designed provides enough radiation coverage to support different sides of the mobile phone board, which is an important feature for future 5G-enabled handsets. In addition, the impacts of human hands and heads on MIMO antenna performance are investigated, and acceptable performance in the data and conversation modes is observed.
  •  
26.
  • Salama, Suzy, et al. (författare)
  • Royal Jelly : Beneficial Properties and Synergistic Effects with Chemotherapeutic Drugs with Particular Emphasis in Anticancer Strategies
  • 2022
  • Ingår i: Nutrients. - : MDPI. - 2072-6643. ; 14:19
  • Forskningsöversikt (refereegranskat)abstract
    • Cancer is one of the major causes of death globally. Currently, various methods are used to treat cancer, including radiotherapy, surgery, and chemotherapy, all of which have serious adverse effects. A healthy lifestyle, especially a nutritional diet, plays a critical role in the treatment and prevention of many disorders, including cancer. The above notion, plus the trend in going back to nature, encourages consumers and the food industry to invest more in food products and to find potential candidates that can maintain human health. One of these agents, and a very notable food agent, is royal jelly (RJ), known to be produced by the hypopharyngeal and mandibular salivary glands of young nurse honeybees. RJ contains bioactive substances, such as carbohydrates, protein, lipids, peptides, mineral salts and polyphenols which contribute to the appreciated biological and pharmacological activities. Antioxidant, anticancer, anti-inflammatory, antidiabetic, and antibacterial impacts are among the well-recognized benefits. The combination of RJ or its constituents with anticancer drugs has synergistic effects on cancer disorders, enhancing the drug's effectiveness or reducing its side effects. The purpose of the present review is to emphasize the possible interactions between chemotherapy and RJ, or its components, in treating cancer illnesses.
  •  
27.
  • Zahid, Muhammad Noaman, et al. (författare)
  • H-Shaped Eight-Element Dual-Band MIMO Antenna for Sub-6 GHz 5G Smartphone Applications
  • 2022
  • Ingår i: IEEE Access. - : Institute of Electrical and Electronics Engineers (IEEE). - 2169-3536. ; 10, s. 85619-85629
  • Tidskriftsartikel (refereegranskat)abstract
    • The design of an eight-element H-shaped dual-band multiple-input multiple-output (MIMO) antenna system for sub-6 GHz fifth-generation (5G) smartphone applications is presented in this work. The radiating elements are designed on the side edge frame of the smartphone, placed on both sides of the main printed circuit board (PCB). Each side edge consists of four radiating elements, which ensures low mutual coupling between antenna elements. The total size of the main PCB is 150 x 75 mm(2), while the size of the side edge frame is 150 x 7 mm(2). A single antenna consists of an H-shaped radiating element fed using a 50 Omega microstrip feeding line designed on the main board of the smartphone. The results show that, according to -6 dB impedance bandwidth criteria, the designed MIMO antenna radiates at two different frequency ranges within the allocated 5G spectrums, i.e., 3.1-3.78 GHz and 5.43-6.21 GHz with 680 MHz and 780 MHz bandwidths, respectively. It is also observed that the antenna elements are able to provide pattern diversity for both the frequency bands. Furthermore, an isolation of >12 dB is observed between any two given radiating elements. Numerous MIMO critical performance characteristics are assessed, including diversity gain (DG), envelope correlation coefficient (ECC), and channel capacity (CC). A prototype is built, measured, and it is observed that the measured and simulated data correspond well. On the basis of performance characteristics, it can be claimed that the suggested MIMO system may be used in 5G communication networks.
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