| 1. |
- Li, Youbing, et al.
(author)
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Single-Atom-Thick Active Layers Realized in Nanolaminated Ti-3(AlxCu1-x)C-2 and Its Artificial Enzyme Behavior
- 2019
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In: ACS Nano. - : AMER CHEMICAL SOC. - 1936-0851 .- 1936-086X. ; 13:8, s. 9198-9205
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Journal article (peer-reviewed)abstract
- A Ti-3(AlxCu1-x)C-2 phase with Cu atoms with a degree of ordering in the A plane is synthesized through the A site replacement reaction in CuCl2 molten salt. The weakly bonded single -atom -thick Cu layers in a Ti-3(AlxCu1-x)C-2 MAX phase provide actives sites for catalysis chemistry. As -synthesized Ti-3(AlxCu1-x)C-2 presents unusual peroxidase-like catalytic activity similar to that of natural enzymes. A fabricated Ti-3(AlxCu1-x)C-2/chitosan/glassy carbon electrode biosensor prototype also exhibits a low detection limit in the electrochemical sensing of H2O2. These results have broad implications for property tailoring in a nanolaminated MAX phase by replacing the A site with late transition elements.
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| 2. |
- Ding, Haoming, et al.
(author)
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Synthesis of MAX phases Nb2CuC and Ti2(Al0.1Cu0.9)N by A-site replacement reaction in molten salts
- 2019
-
In: Materials Research Letters. - : Taylor & Francis. - 2166-3831. ; 7:12, s. 510-516
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Journal article (peer-reviewed)abstract
- New MAX phases Ti2(AlxCu1−x)N and Nb2CuC were synthesized by A-site replacement by reacting Ti2AlN and Nb2AlC, respectively, with CuCl2 or CuI molten salt. X-ray diffraction, scanning electron microscopy, and atomically resolved scanning transmission electron microscopy showed complete A-site replacement in Nb2AlC, which lead to the formation of Nb2CuC. However, the replacement of Al in Ti2AlN phase was only close to complete at Ti2(Al0.1Cu0.9)N. Density-functional theory calculations corroborated the structural stability of Nb2CuC and Ti2CuN phases. Moreover, the calculated cleavage energy in these Cu-containing MAX phases are weaker than in their Al-containing counterparts.The preparation of MAX phases Nb2CuC and Ti2(Al0.1Cu0.9)N were realized by A-site replacement in Ti2AlN and Nb2AlN, respectively.
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| 3. |
- Liang, Jiamin, et al.
(author)
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Synthesis of Zr2Al3C4 coatings on zirconium-alloy substrates with Al-C/Si interlayers as diffusion barriers
- 2019
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In: Vacuum. - : PERGAMON-ELSEVIER SCIENCE LTD. - 0042-207X .- 1879-2715. ; 160, s. 128-132
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Journal article (peer-reviewed)abstract
- Zr2Al3C4 coatings are potential candidates to prevent claddings of traditional Zr-based alloys from severe oxidation in water steam at high temperature. However, the diffusion of aluminum between coating and substrates at high temperature results in a coating composition deviating from the compositional domain for formation of the Zr2Al3C4 phase. Thus, synthesis of Zr2Al3C4 coatings on zirconium-alloy substrates is challenging. Here, we report that the Zr2Al3C4 phase can be obtained on zirconium alloy (ZIRLO) substrates where an Al-C/Si interlayer deposited by magnetron sputtering is introduced. The Al-C/Si interlayer prevented elemental diffusion of aluminum between the Zr-Al-C coating and the substrates during a post-annealing process at 800 degrees C for 3 h. The Al/Zr ratio of the Zr-Al-C coating after annealing was 0.96 and 0.59 in the cases of with and without Al-C/Si interlayer, respectively. Hence, the Al-C/Si interlayer acts as diffusion barrier and greatly decreases the deviation from the standard stoichiometric ratio of the Zr2Al3C4 phase, which facilitates the formation of the Zr2Al3C4 phase in the final coating.
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| 4. |
- Thomas, Manu Anna, et al.
(author)
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Snowfall distribution and its response to the Arctic Oscillation : an evaluation of HighResMIP models in the Arctic using CPR/CloudSat observations
- 2019
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In: Geoscientific Model Development. - : Copernicus GmbH. - 1991-959X .- 1991-9603. ; 12:8, s. 3759-3772
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Journal article (peer-reviewed)abstract
- A realistic representation of snowfall in general circulation models (GCMs) of global climate is important to accurately simulate snow cover, surface albedo, high-latitude precipitation and thus the surface radiation budget. Hence, in this study, we evaluate snowfall in a range of climate models run at two different resolutions by comparing to the latest estimates of snowfall from the CloudSat Cloud Profiling Radar over the northern latitudes. We also evaluate whether the finer-resolution versions of the GCMs simulate the accumulated snowfall better than their coarse-resolution counterparts. As the Arctic Oscillation (AO) is the prominent mode of natural variability in the polar latitudes, the snowfall variability associated with the different phases of the AO is examined in both models and in our observational reference. We report that the statistical distributions of snowfall differ considerably between the models and CloudSat observations. While CloudSat shows an exponential distribution of snowfall, the models show a Gaussian distribution that is heavily positively skewed. As a result, the 10th and 50th percentiles, representing the light and median snowfall, are overestimated by up to factors of 3 and 1.5, respectively, in the models investigated here. The overestimations are strongest during the winter months compared to autumn and spring. The extreme snowfall represented by the 90th percentiles, on the other hand, is positively skewed, underestimating the snowfall estimates by up to a factor of 2 in the models in winter compared to the CloudSat estimates. Though some regional improvements can be seen with increased spatial resolution within a particular model, it is not easy to identify a specific pattern that holds across all models. The characteristic snow- fall variability associated with the positive phase of AO over Greenland Sea and central Eurasian Arctic is well captured by the models.
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