| 1. |
- Alakangas, Lena, et al.
(författare)
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Norrbottens malm- och mineralresurs och dess potentiella betydelse för innovation, samhälle och miljö
- 2014
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Rapport (övrigt vetenskapligt/konstnärligt)abstract
- Gruvindustrins betydelse för samhällsutveckling och infrastruktur i Sverige och inte minst i Norrbottens län är mycket stor. De geologiska förutsättningarna att hitta nya brytvärda förekomster i Norrbotten är goda. Länet är tillsammans med Västerbotten en av Europas viktigaste regioner för utvinning av metaller. Det syns också i den nyligen framtagna regionala mineralstrategin för Norrbotten och Västerbotten. Visionen för den regionala mineralstrategin: ”Genom långsiktigt hållbart nyttjande av Norrbottens och Västerbottens läns mineralresurser har ytterligare tillväxt skapats i regionen och hela Sverige. Vi har utvecklat och stärkt vår ställning som ledande gruv- och mineralnation.”Eftersom framtidspotentialen för gruvnäringen är mycket god men okunnigheten hos både allmänhet och beslutsfattare om näringens betydelse för innovation och samhällsutveckling är stor, kopplat med en utbredd oro för miljöpåverkan, måste dessa viktiga framtidsfrågor belysas. Med finansiering från Länsstyrelsen i Norrbotten bedrevs därför under första hälften av 2014 en förstudie som syftade till att sammanfatta kunskapsläget om framtidens gruvindustri i Norrbotten. Resultaten av förstudien redovisas i den här rapporten. En viktig slutsats är att det under nästa strukturfondsperiod (med start 2015) behövs ett framtidsinriktat forskningsprogram för att belysa de möjligheter som finns. Denna förstudie utgör grund för en kommande ansökan till strukturfonderna. Kompetensen som finns vid Luleå tekniska universitet, Sveriges centrum för gruvrelaterad forskning och utbildning, bör användas för att studera troliga framtidsmöjligheter och hur de ska kunna användas för att få en så positiv utveckling som möjligt för länet. Projektet bör innehålla följande tre huvudinriktningar, som naturligtvis hör ihop:Vilka malm- och mineralresurser finns det potential för i Norrbotten, och vilka kommer sannolikt att exploateras i framtiden?Vad kommer den exploateringen att ha för betydelse för innovation och samhällsutveckling?Vad kommer den exploateringen att få för miljöeffekter och hur ska man göra för att minska miljöbelastningen?En annan slutsats är att nedlagda gruvområden inte måste ses som förstörd natur. Betydande mervärden som gruvturism skulle kunna skapas om vilja, kreativitet och beslutsamhet finns. Detta är ett givet utvecklingsområde där småföretag och entreprenörer kan göra stor insats om de politiska och myndighetsmässiga förutsättningarna finns. Dessa aspekter skulle också kunna belysas i det föreslagna forskningsprogrammet eller i ett eget projekt.
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| 2. |
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| 3. |
- Chlot, Sara, et al.
(författare)
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Effects on nutrient regime in two recipients of nitrogen-rich mine effluents in northern Sweden
- 2013
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Ingår i: Applied Geochemistry. - : Elsevier BV. - 0883-2927 .- 1872-9134. ; 31, s. 12-24
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Tidskriftsartikel (refereegranskat)abstract
- The question of the limiting nutrient(s) for production of phytoplankton and macrophytes was explored in two contrasting freshwater systems receiving N- and P-rich mine effluents from the Boliden and Kiruna mine sites, northern Sweden. For both sites, total N (TN), total P (TP) and TN:TP mass ratios in water, sediment and macrophytes were used to examine (1) spatial variations within the systems, (2) differences between the systems and (3) seasonal variations. The TN concentration from the discharge point at the Kiruna site was about seven times higher than at the Boliden discharge point, while the TP concentration was 10 times lower than in the discharge point at the Boliden site. The majority of the studied lakes showed elevated biomass of phytoplankton, with maximum values found in Lake Bruträsket (Boliden). Mining activities have affected the nutrient regime of the two recipients by contributing to elevated TN and TP concentrations and TN:TP mass ratios as well as elevated production of phytoplankton and macrophytes compared to the reference sites. Depending on the NH4 concentration in the effluent at the Boliden site, water column TN:TP mass ratios shifted from being >22, indicating P-deficiency, to between 9 and 22, indicating a transition from N- to P-deficiency (co-limitation). However, water column TN:TP mass ratios at the Kiruna site always indicated P-deficiency, while TN:TP mass ratios of macrophytes indicate that both sites may vary from N- to P-limitation. The study suggests that for the design of efficient monitoring programmes and remediation measures, it is important to consider the major N and P species in water, phytoplankton, sediment and macrophytes.
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| 4. |
- Chlot, Sara, et al.
(författare)
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Interaction between nitrogen and phosphorus cycles in mining-affected aquatic systems-experiences from field and laboratory measurements
- 2013
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Ingår i: Environmental Science and Pollution Research. - : Springer Science and Business Media LLC. - 0944-1344 .- 1614-7499. ; 20:8, s. 5722-5736
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Tidskriftsartikel (refereegranskat)abstract
- The main objectives of this study were to (a) study the interaction between N and P cycles in mining-affected aquatic systems and (b) to quantify release rates of sedimentary soluble reactive phosphorus (SRP) that may be related to this interaction. Sediment cores and water from Lake Bruträsket (Boliden, northern Sweden) were collected and a time series of water sampling and flow measurements was conducted in the Brubäcken stream connected to the lake. Factors affecting SRP release were studied in a sediment incubation experiment and water column experiments. Field and laboratory measurements indicated that pH and dissolved oxygen are two important factors for SRP release. At the end of the low-oxygen incubation, an SRP concentration of 56 μg L-1 resulted in a sedimentary flux of 1.1 mg SRP m-2 day-1. This is ∼10 times higher than the flux of 0.12 mg SRP m-2 day-1 obtained from depth integration of vertical SRP profiles measured in the lake, and ∼100 times higher than the external flux of 0.014 mg SRP m-2 d-1 into the lake (based on catchment area). Field measurements indicated that oxidation of organic matter and mining-related chemicals (ammonium and thiosulphates) may result in increased internal SRP flux from the sediment. Increased P loading in the lake as a result of low-oxygen conditions could change water column total nitrogen/total phosphorus ratios from 27 to 17, consequently changing the lake from being P-limited to be co-limited by N and P. The obtained findings point to possible interaction between the cycles of nitrogen (oxygen consumption) and P (flux from sediment) that may be important for nutrient regulation in mine water recipients.
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| 5. |
- Chlot, Sara, et al.
(författare)
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Modelling nitrogen transformations in waters receiving mine effluents
- 2011
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Ingår i: Science of the Total Environment. - : Elsevier BV. - 0048-9697 .- 1879-1026. ; 409:21, s. 4585-4595
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Tidskriftsartikel (refereegranskat)abstract
- This paper presents a biogeochemical model developed for a clarification pond receiving ammonium nitrogen rich discharge water from the Boliden concentration plant located in northern Sweden. Present knowledge about nitrogen (N) transformations in lakes is compiled in a dynamic model that calculates concentrations of the six N species (state variables) ammonium-N (Nam), nitrate-N (Nox), dissolved organic N in water (Norg), N in phytoplankton (Npp), in macrophytes (Nmp) and in sediment (Nsed). It also simulates the rate of 16 N transformation processes occurring in the water column and sediment as well as water–sediment and water–atmosphere interactions. The model was programmed in the software Powersim using 2008 data, whilst validation was performed using data from 2006 to 2007. The sensitivity analysis showed that the state variables are most sensitive to changes in the coefficients related to the temperature dependence of the transformation processes. A six-year simulation of Nam showed stable behaviour over time. The calibrated model rendered coefficients of determination (R2) of 0.93, 0.79 and 0.86 for Nam, Nox and Norg, respectively. Performance measures quantitatively expressing the deviation between modelled and measured data resulted in values close to zero, indicating a stable model structure. The simulated denitrification rate was on average five times higher than the ammonia volatilisation rate and about three times higher than the permanent burial of Nsed and, hence, the most important process for the permanent removal of N. The model can be used to simulate possible measures to reduce the nitrogen load and, after some modification and recalibration, it can be applied at other mine sites affected by N rich effluents.
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| 6. |
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| 7. |
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| 8. |
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| 9. |
- Ingri, Johan, et al.
(författare)
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Changes in trace metal sedimentation during freshening of a coastal basin
- 2014
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Ingår i: Marine Chemistry. - : Elsevier BV. - 0304-4203 .- 1872-7581. ; 167, s. 2-12
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Tidskriftsartikel (refereegranskat)abstract
- Holocene freshening has turned the Bothnian Bay, northern Baltic Sea into an oligotrophic basin. Sequestering of trace elements has changed significantly during the oligotrophication process. In principle, trace metals have been transferred from permanently buried sulfides to Fe–Mn-oxyhydroxides in the top layers of the sediment. The oxyhydroxide layers restrict the flux of trace metals from the sediment to the oxic bottom water. Hence, Fe–Mn cycling in the suboxic sediment enriches a number of trace metals in the surface sediment. Arsenic, Sn, Ge and Bi show enrichment in the Fe-oxyhydroxide layer, whereas Mo, Cd, Ni, Co, Cu, and Sb are enriched in the uppermost Mn-oxyhydroxide layer. This natural redox cycling in the sediment obscures pollution effects.The oligotrophication process started approximately 3500 years ago, reflected in decreasing deposition of Zn, a proxy for phytoplankton production, and formation of Mn oxyhydroxide layers. Similarly, Ba/Al data indicate a decrease in the pelagic input of plankton. Barium data also suggest that dissolved sulfide in the sediment never reached high concentrations. Germanium is closely related to Ba, suggesting that Ge can be used as a proxy for phytoplankton production. Vanadium, U, Re, and Mo all indicate that the bottom water never has been significantly sulfidic during the last 5500 years. Rhenium data indicate that the organic carbon oxidation rate has decreased during the last 5500 years. Cadmium follows the organic matter distribution, but started to increase 1000 YBP (years before present). The reason for this enhanced input of Cd is unclear.
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| 10. |
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| 11. |
- Kløve, Bjørn, et al.
(författare)
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Groundwater dependent ecosystems : Part I: Hydroecological status and trends
- 2011
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Ingår i: Environmental Science and Policy. - : Elsevier BV. - 1462-9011 .- 1873-6416. ; 14:7, s. 770-781
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Tidskriftsartikel (refereegranskat)abstract
- Groundwater dependent ecosystems (GDEs) include valuable ecosystems such as springs, wetlands, rivers, lakes and lagoons. The protection of these systems and services they provide is highlighted by international agreements, i.e. Ramsar convention on wetlands, and regional legislation, i.e. the European Water Framework Directive. Groundwater provides water, nutrients and a relatively stable temperature. However, the role of groundwater in surface ecosystems is not fully understood. The ecosystem can depend on groundwater directly or indirectly, and the reliance can be continuous, seasonal or occasional. This has implications for the vulnerability of ecosystems, as some may be easily affected by external pressure. Conceptual models and quantitative assessments of how groundwater interacts with the environment are needed. GDEs are also threatened by different land use activities and climate change. Hence, we need to understand how GDEs are affected by changes in groundwater quantity and quality, as severe groundwater changes have been observed in many regions. This study examines key aspects of GDEs (hydrogeology, geochemistry and biodiversity) in order to improve conceptual understanding of the role of groundwater in such ecosystems. The status and baseline of different types of GDEs are discussed, with particular emphasis on past evidence of environmental change and potential thresholds and threats in GDEs in various parts of Europe with different land use, climate and geology
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| 12. |
- Rentz, Ralf, et al.
(författare)
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Impact of urban stormwater on sediment quality in an enclosed bay of the Lule river, northern Sweden
- 2011
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Ingår i: Water, Air and Soil Pollution. - : Springer Science and Business Media LLC. - 0049-6979 .- 1573-2932. ; 218:1-4, s. 651-666
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Tidskriftsartikel (refereegranskat)abstract
- Sediment and porewater samples from an enclosed bay receiving stormwater discharge (Skutviken) near the centre of Luleå, northern Sweden were analysed for major and trace elements and 16 polycyclic aromatic hydrocarbons (PAHs). Among the studied metals Cd, Cu, Pb and Zn were enriched at Skutviken. Also, the PAH content was enriched, in particular for phenantrene, anthracene, fluoranthene and pyrene which are regarded as common constituents in stormwater. The use of trace metal ratios provided indications about pollutant sources for the sediment. Cs-137 dating was used to determine historical changes in metal and PAH fixation in the sediment. The bay Skutviken is enclosed through the construction of a road bank since 1962. The enclosure led to reduced water circulation in the bay that promotes the occurrence of anoxic conditions with sulphate reduction within the bay. As a consequence of these conditions, metals are trapped in the sediments as sulphides. This study suggests that enclosed bays with restricted water circulation may be efficient traps for urban pollutants, reducing the present-day input of pollutants to the sea. In areas with postglacial land uplift, where such bays are common, bay sediments are a potential future source of pollutants when uplift results in erosion and oxidation of the sedi
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| 13. |
- Siergieiev, Dmytro, et al.
(författare)
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“Clogging layer” at regulated river beds - implications for river-groundwater exchange
- 2013
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- Within the EU-project GENESIS (2013), aiming to provide scientific basis and technical guidance for the update of the EU Groundwater Directive, Luleå University of Technology is investigating possible effects of hydropower regulation on surface water (SW)- groundwater (GW) exchange. The study compares SW, GW and hyporheic processes for the unregulated Kalix River and the regulated Lule River. Hydropower has long been regarded a fairly green energy source but today negative effects have become obvious (Renöfält et al. 2010).The hyporheic zone (HZ) accommodates most of the SW-GW exchange of solutes just beneath and along a river, dampens heat fluxes, processes pollutants and is essential for ecosystems.The study observes SW and GW (in wells orthogonal to the river) at one site in each river. In these, hydrological (water level, hydraulic conductivity, tracer test) and geochemical (temperature, electrical conductivity, water/soil chemistry) measurements were performed during several seasons.The presence of natural high-flow events in the Kalix River removes fines from the river bed, maintaining good SW-GW connectivity that favours hyporheic exchange (Brunke and Gonser 1997). Altered discharge of the regulated river (reduced flow peaks and velocity, daily discharge fluctuations) facilitated deposition of fine sediments at the river bed forming a “clogging layer” (Blaschke et al. 2003). The bed in the regulated river has two orders of magnitude lower hydraulic conductivity than that at the unregulated site and restricts the SW-GW exchange.Reduced hydraulic connectivity between SW and GW at the regulated Lule River site suggests decreased fluxes across the river-aquifer interface (Siergieiev et al. 2013), and thus reduced size of the HZ which is not always the case in regulated rivers (Sawyer et al. 2009).Decreased hyporheic velocities led to increased residence time and favored prolonged contact between water and soil matrix that stimulated biogeochemical transformations. As a result, the electrical conductivity of hyporheic water of the Lule River was higher than that of the surrounding water.Deteriorated connectivity and extended travel time reduced the dissolved oxygen concentration, which is functionally ecologically essential for hyporheic habitat. In addition, complete consumption of nitrate found at the regulated site, suggests formation of a suboxic zone extending several meters inland which promotes metals release reflected in high dissolved Fe and Mn in the HZ. The conditions of SW-GW exchange control nutrients processing and their export to SW. Thus, the HZ in the Lule River acts as a source of dissolved metals, while in the Kalix River much of the metals are removed by hyporheic processes due to good SW-GW connectivity.SW-GW connectivity plays an important role for hyporheic exchange and hyporheic water quality. Hydropower regulation in the Lule River has altered this connectivity, which may have far reaching implications for biogeochemical processes in the river.
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| 14. |
- Siergieiev, Dmytro, et al.
(författare)
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Flow regulation effects on the hydrogeochemistry of the hyporheic zone in boreal rivers
- 2014
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Ingår i: Science of the Total Environment. - : Elsevier BV. - 0048-9697 .- 1879-1026. ; 499, s. 424-436
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Tidskriftsartikel (refereegranskat)abstract
- River-aquifer interfaces are essential for ecosystem functioning in terms of nutrient exchange and biological habitat, but are greatly threatened world-wide. This study examined geochemical aspects of river-aquifer interaction in one regulated and one unregulated boreal river in Northern Sweden to determine whether the geochemical functioning of the hyporheic zone is affected by hydrological alterations, e.g. regulated river discharge and river-aquifer connectivity. In the unregulated Kalix River, the hyporheic pore water was well-oxygenated with orthogonal fluxes (≈0.6-0.7 m d-1) and acted as a sink for Fe, Mn, Al, NH4, and Ca, with fractional losses of 95%, 92%, 45%, 31%, and 15%, respectively. A corresponding elevation in the concentrations of these elements in the hyporheic sediment was observed, with higher saturation indices of Fe-, Mn-, and Al-bearing secondary minerals in hyporheic waters. In the regulated Lule River, hydraulic connectivity at the river-aquifer interface was altered by the presence of a clogging layer (0.04 m d–1). In addition, the river discharge oscillated daily, severely reducing exchange flows across the riverbed (<0.01 m d-1). As a result, the hyporheic pore water was suboxic, with elevated concentrations of filtered Fe and Mn (fractional increase of ≈3700% and ≈2500%, respectively) and other solutes (NH4, Si, S, Ca). A conceptual model revealed functional differences between geochemical features of the hyporheic zone of regulated and unregulated rivers. Overall, the results showed that hyporheic processes are altered along regulated rivers, with resulting impacts on the geochemistry of riverine, riparian and related marine ecosystems.
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| 15. |
- Siergieiev, Dmytro, et al.
(författare)
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Hydropower regulation impact on river-groundwater interaction and the riparian zone : a geochemical approach
- 2010
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Konferensbidrag (refereegranskat)abstract
- Natural rivers, including their riparian zones, belong to the most diverse, dynamic, and complex ecosystems on the world’s continents, and they play key roles in the regulation and maintenance of biodiversity in the landscape (Dynesius and Nilsson, 1994). Hydropower has a major macro-economic impact since it supplies more than 50% of national electricity production in 65 countries (Koch, 2002). Today about two-thirds of the fresh water flowing to the oceans is obstructed by approximately 40,000 large dams and more than 900,000 smaller ones (Petts, 1984; McCully, 1996). Hydropower regulation of river bodies was for a long time considered to be an environmentally friendly source of energy (Renöfält et al., 2009). However, damming of rivers has later been recognized as one of the most dramatic anthropogenic impacts on the natural environment (Petts, 1984). A comparison between one regulated and one pristine river with similar features, both located in Northern Sweden, has been conducted (Collomp 2001). The Luleå River comprises 15 reservoirs and has been regulated for almost a century (72 % of the annual river runoff can be stored in its reservoirs) (Dynesius and Nilsson, 1994). The Kalix River, the last major unregulated river in Europe, is used as a reference for geochemical conditions in a pristine river.Water storage in reservoirs affects seasonal water discharge, water temperature, conductivity and concentrations of nutrients, dissolved oxygen, organic matter and metals. Spring peaks are truncated and postponed and average base flow is higher than that under pristine conditions. Due to increased sedimentation in the reservoirs, the transport of Fe, Si, Al, Mn, DOC, P and N has decreased (Drugge, 2003). The aim of the outlined study is to increase knowledge regarding the effect of river regulation on riparian groundwater geochemistry by:a) analysing river water measurements with respect to river-groundwater exchangeb) measuring riparian groundwater quality at one site in each of the two riversIn both rivers, sampling sites were chosen approximately 100 km upstream of the river mouth. The geological settings and climatic conditions are similar in the two chosen areas, with precipitation rates of about 400 mm/year. In the regulated Luleå River, frequent water level fluctuations cause continuous mixing of river water and groundwater. Land use in both areas is equally non-intensive, and hydropower exploitation of the Luleå River is the only notable difference in land use in the two areas. The monitoring program at each site includes installation of 2-3 groundwater wells, with data loggers continuously recording groundwater levels, temperature, pH, conductivity, DO and ORP. Water samples will be taken weekly or bi-weekly for metal and nutrient analyses, and the hydraulic conductivities at the sites will be determined in soil samples. Expected outcome: Improved knowledge regarding river regulation impact on riparian groundwater, based on comparison of a one-year cycle of seasonal variations in groundwater flow and quality in a heavily regulated and a nearby pristine river.
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| 16. |
- Siergieiev, Dmytro, et al.
(författare)
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Hyporheic water exchange in a large hydropower regulated boreal river : directions and rates
- 2014
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Ingår i: Hydrology Research. - : IWA Publishing. - 1998-9563 .- 0029-1277 .- 2224-7955. ; 45:3, s. 334-348
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Tidskriftsartikel (refereegranskat)abstract
- Widespread river regulation is known to modify river-aquifer interactions, influencing entire watersheds, but knowledge of the hyporheic flowpath along regulated rivers is limited. This study measured the hydraulic conductivity of the river bed and the aquifer, water levels and seepage fluxes in the heavily regulated Lule River in Northern Sweden, with the aim of characterising water exchange across the river-aquifer interface. While pristine rivers in the area are gaining, the Lule River was recharging the aquifer during 10% of the time. Daily river level fluctuations (typically ±0.25 m) directed ~3% of the total orthogonal flux across the river bed towards the aquifer, while during ~2% of the time the orthogonal fluxes were negligible (≤10–4 m d–1). A clogging layer on the river bed, most likely formed due to the modified river discharge, restricted river-aquifer exchange. The hyporheic zone had higher electrical conductivity than the river and the aquifer and electrical conductivity occasionally decreased following rising river water levels, with 3–5 hours delay. Overall, hydropower regulation has severely altered the hydrological regime of the hyporheic zone in the Lule River.
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| 17. |
- Siergieiev, Dmytro, et al.
(författare)
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Impact of Hydropower Regulation on River Water Composition in Northern Sweden
- 2014
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Ingår i: Aquatic geochemistry. - : Springer Science and Business Media LLC. - 1380-6165 .- 1573-1421. ; 20:1, s. 59-80
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Tidskriftsartikel (refereegranskat)abstract
- Using hydrogeochemical analysis of two large boreal rivers (pristine Kalix and hydropower regulated Lule) discharging into the Gulf of Bothnia, the major impacts of regulation on water discharge, element transport, and their seasonal redistribution have been assessed. The pre-regulation hydrogeochemical features were assumed to be similar for the two rivers. For the Lule River, the average maximum runoff was almost halved, while the average minimum was tripled as a result of the regulation. The fraction of winter transport of total organic carbon (TOC), Fe, Si, suspended Mn and P in the Lule River was, according to a conservative estimate, two to three times higher than in the pristine river. Longer residence time in the Lule River delayed arrival of the suspended Mn peak and dissolved Si decline to the river mouth. During summer, the suspended C/N ratio in the regulated river was 10-20 compared to <10 for the pristine, suggesting presence of predominantly old organic material. This was supported by a virtually constant suspended P/Fe ratio throughout the year in the Lule River, indicating low abundance of phytoplankton. TOC varied irregularly in the Lule River suggesting temporal disconnection between the river and the upper riparian zone. The disappearance of the spring flow maximum, a shift of element transport from spring to winter, and supply of mainly old organic material during the vegetation growth season may have a pronounced impact on the ecosystem of the Gulf of Bothnia and the river itself.
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| 18. |
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| 19. |
- Widerlund, Anders, et al.
(författare)
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Late Holocene freshening of the Baltic Sea derived from high-resolution strontium isotope analyses of mollusk shells
- 2011
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Ingår i: Geology. - 0091-7613 .- 1943-2682. ; 39:2, s. 187-190
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Tidskriftsartikel (refereegranskat)abstract
- Strontium isotopic composition (87Sr/86Sr) data from subfossil 14C-dated mollusk shells in raised beach sediments are used as a paleosalinity proxy in the brackish Baltic Sea, the precision (±5%) and accuracy (±0.7‰) of the method being judged from replicate analyses of modern shells. Paleosalinity data with an average time resolution of ~200 yr for the period 7130-2775 calibrated 14C yr B.P. indicate maximum surface salinities of 10‰-11‰, 11‰-12‰, and 12‰-13‰ for the Bothnian Bay, Bothnian Sea, and Baltic Proper (the three major Baltic subbasins). The relative salinity differences between the basins were small (≤30%) compared to the as much as eightfold present-day relative salinity differences (Bothnian Bay 1‰-3‰; Bothnian Sea 4‰-5‰; Baltic Proper 6‰-8‰). Late Holocene freshening (ca. 3000 calibrated 14C yr B.P. to present) is most pronounced in the northernmost subbasin, the Bothnian Bay, consistent with the absence of a permanent halocline, sequestering of phosphorus in well-oxygenated bottom sediments, and phosphorus limitation of primary production in the present-day Bothnian Bay. This study suggests that paleosalinity data may be crucial to improving our understanding of the possible effects of any future, climate-induced freshening of the Baltic Sea
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| 20. |
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| 21. |
- Widerlund, Anders, et al.
(författare)
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Sedimentary records of δ13C, δ15N and organic matter accumulation in lakes receiving nutrient-rich mine waters
- 2014
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Ingår i: Science of the Total Environment. - : Elsevier BV. - 0048-9697 .- 1879-1026. ; 485-486, s. 205-215
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Tidskriftsartikel (refereegranskat)abstract
- Organic C and total N concentrations, C/N ratios, δ15N and δ13C values in 210Pb-dated sediment cores were used to reconstruct historical changes in organic matter (OM) accumulation in three Swedish lakes receiving nutrient-rich mine waters. Ammonium-nitrate-based explosives and sodium cyanide (NaCN) used in gold extraction were the major N sources, while lesser amounts of P originated from apatite and flotation chemicals. The software IsoSource was used to model the relative contribution of soil, terrestrial and littoral vegetation, and phytoplankton detritus in the lake sediments. In one lake the IsoSource modelling failed, suggesting the presence of additional, unknown OM sources. In two of the lakes sedimentary detritus of littoral vegetation and phytoplankton had increased by 15–20% and 20–35%, respectively, since ~ 1950, when N- and P-rich mine waters began to reach the lakes. Today, phytoplankton is the dominating OM component in these lake sediments, which appears to be a eutrophication effect related to mining operations. Changes in the N isotopic composition of biota, lake water, and sediments related to the use of ammonium-nitrate-based explosives and NaCN were evident in the two studied systems. However, N isotope signals in the receiving waters (δ15N ~ + 9‰ to + 19‰) were clearly shifted from the primary signal in explosives (δ15N–NO3 = + 3.4 ± 0.3‰; δ15N–NH4 = − 8.0 ± 0.3‰) and NaCN (δ15N = + 1.1 ± 0.5‰), and direct tracing of the primary N isotope signals in mining chemicals was not possible in the receiving waters. Systems where mine waters with a well known discharge history are a major point source of N with well-defined isotopic composition should, however, be suitable for further studies of processes controlling N isotope signatures and their transformation in aquatic systems receiving mine waters.
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| 22. |
- Öhlander, Björn, et al.
(författare)
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Mobility and transport of Nd isotopes in the Vadose zone during weathering of granitic till in a boreal forest
- 2014
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Ingår i: Aquatic geochemistry. - : Springer Science and Business Media LLC. - 1380-6165 .- 1573-1421. ; 20:1, s. 1-17
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Tidskriftsartikel (refereegranskat)abstract
- There is a broad correlation between the εNd values for rivers (including both the water and the particulate material it carries) and the age of the source terrain. This paper presents Nd isotope distribution data for soil, soil water, groundwater, and stream water samples gathered in a small catchment in northern Sweden. The results show that the release of Nd and Sm from boreal forests into streams and, eventually, into the oceans is more complicated than previously realized. The weathering of till causes changes in both the Nd isotopic composition and Sm/Nd ratios. Both the Sm/Nd ratio and εNd were higher in strongly weathered soils horizons than in less weathered till, since minerals with high Sm/Nd ratios were, on average, more resistant to weathering than those with low Sm/Nd ratios. In contrast to the situation for the main minerals and the major elements, the weathering of rare earth elements (REE) was not restricted to the E-horizon: the measured REE concentrations continued to increase with depth in the C-horizon. In addition, REE released by weathering in the upper parts of the soil profile were partly secondarily retained at deeper levels. Therefore, the dissolved Nd released by weathering in the upper soil horizons was trapped and did not enter the groundwater directly. Rather, the Nd in the groundwater largely originated from weathering within the groundwater zone. However, this was not the only source of Nd in the stream water. The Nd isotope composition and Sm/Nd ratio were determined by the mixing between of Nd and Sm in the groundwater and REE-carrying organic material washed out of the soil profile. The groundwater close to the stream reaches the upper soil horizons during high discharge events such as snowmelts, and organic matter carrying Nd and Sm is washed out of the soils and thus released into the stream. Therefore, the Nd exported from catchment is derived from both the weathering within the groundwater zone, and the organic matter washed out from the soil. If longer timescales with more advanced weathering stages in the groundwater zone are considered, it cannot be ruled out that there will be a shift towards more radiogenic values in the exported Nd. Recorded shifts in the Nd isotopic composition in the ocean may thus not only reflect changed source regions, but also the weathering history of the same source region
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| 23. |
- Österlund, Helene, et al.
(författare)
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Simultaneous measurements of As, Mo, Sb, V and W using a ferrihydrite diffusive gradients in thin films (DGT) device
- 2010
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Ingår i: Analytica Chimica Acta. - : Elsevier BV. - 0003-2670 .- 1873-4324. ; 682:1-2, s. 59-65
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Tidskriftsartikel (refereegranskat)abstract
- The ferrihydrite-backed DGT (diffusive gradients in thin films), recently developed for arsenic and phosphate measurements was, for the first time, characterized with respect to molybdate, antimonate, vanadate and tungstate determination. Arsenate was included in the characterization to allow comparison with literature data and thus provide quality control of the measurements. In addition to laboratory experiments, field measurements were carried out in a natural stream in northern Sweden affected by mine drainage. It was shown that ferrihydrite-DGT is suitable for simultaneous determination of labile arsenic, molybdate, antimonate, vanadate and tungstate over a wide pH range. Diffusion coefficients were estimated using two different methods; diffusion cell and direct uptake to DGT devices in synthetic solutions. Estimations of the coefficients using the direct uptake method were performed between pH 4 and 8. The results from the two methods agreed well irrespective of pH, except for molybdate and antimonate that showed decreased values at pH 8. Adsorption of the analytes to ferrihydrite gel discs was rapid at all pH values. However, there was a tendency toward lower adsorption affinity for antimonate compared to the other anions. 100% recovery of accumulated analytes was achieved through complete dissolution of the ferrihydrite adsorbent using 1.4 mol L-1 HNO3 with 0.1 mol L-1 HF. From field sampling it was concluded that the opportunities for accurate antimonate and molybdate determination decrease at pH ≥8.7. DGT labile concentrations were generally lower than dissolved concentrations. Relatively lower DGT concentrations, compared to dissolved (<0.45 μm), were observed under a period when ferric oxide precipitations were detected on the DGT protective filter.
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