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- Yang, Jiaojiao, et al.
(författare)
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Electrochemically Active, Compressible, and Conducting Silk Fibroin Hydrogels
- 2020
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Ingår i: Industrial & Engineering Chemistry Research. - : AMER CHEMICAL SOC. - 0888-5885 .- 1520-5045. ; 59:19, s. 9310-9317
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Tidskriftsartikel (refereegranskat)abstract
- Silk fibroin-based conducting hydrogels possess hierarchical structural motifs featuring unique properties, but the development of such materials has proven to be challenging. Herein, we develop a novel strategy for the fabrication of a conducting silk fibroin hydrogel based on an interpenetrated network of poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) and silk fibroin. The hydrogel possesses good electrical conductivity and considerable capacitance and cycling stability due to the existence of the PEDOT conducting network, as well as enhanced mechanical properties such as compressibility due to beta-sheets in the silk fibroin network and Ca2+ cross-linking of the PSS components. A symmetric charge storage device based on conductive silk fibroin hydrogel electrodes exhibited a remarkable areal capacitance of 1.1 F cm(-2) at 0.5 mA cm(-2), as well as a good capacitive response under a compressed state. This combination of compression strength and electrochemical properties makes this conducting silk hydrogel a potential material for unconventional energy storage applications.
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| 2. |
- Yang, Jiaojiao, et al.
(författare)
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Multifunctional Polymer-Free Mineral Plastic Adhesives Formed by Multiple Noncovalent Bonds
- 2020
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Ingår i: ACS Applied Materials and Interfaces. - : American Chemical Society (ACS). - 1944-8244 .- 1944-8252. ; 12:6, s. 7403-7410
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Tidskriftsartikel (refereegranskat)abstract
- Supramolecular adhesives have attracted a great deal of attention in recent years, resulting in their development for different applications. However, creating supramolecular adhesives with reversible and reusable properties is still a challenge. Here, a synthesis route to obtain supramolecular adhesives is presented in which no polymeric compounds are involved in the preparation. The adhesive is formed by intermolecular coulomb forces between amorphous magnesium carbonate nanoparticles and the low-molecular-weight drug ibuprofen, which results in an amorphous composite material that is transparent, shapeable, stretchable, and self-healing, making it reusable. It is demonstrated that this hybrid material provides a simple means of gluing a wide variety of materials, including metals, glass, paper, and plastics, and that is reversible and possesses reusability. The material disrupts the traditional concept of polymer-based adhesives and may be used as a sustainable mineral plastic in applications such as 3D printing.
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