| 1. |
- Huang, Yajun, et al.
(författare)
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Flame-retardant polyvinyl alcohol/cellulose nanofibers hybrid carbon aerogel by freeze drying with ultra-low phosphorus
- 2019
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Ingår i: Applied Surface Science. - : Elsevier BV. - 0169-4332. ; 497
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Tidskriftsartikel (refereegranskat)abstract
- Polyvinyl alcohol/cellulose nanofibers hybrid aerogel was prepared under freeze drying method. To improve the aerogels' anti-combustion performance, 0.8 wt% microencapsulated ammonium polyphosphate (MCAPP) was loaded as the flame retardant. Aerogels with extremely low density (~0.06 g/cm3) and excellent mechanical performance (Young's modulus: 1.045 MPa) can be obtained. The resulted aerogel also exhibit considerable thermal insulation ability (thermal conductivity: ~0.04 W/m·K). Experimental results indicate that the value of limiting oxygen index increases from 19.5% to 37.5% when loading 0.8 wt% MCAPP. Accordingly, the aerogels' peak heat release rate decreased significantly from 222.44 to 107.84 kW/m2. The char residue rises when introducing MCAPP and the char's integrity improves a lot after combustion. The fire performance index and fire growth index increases and falls respectively, indicating improved anti-combustion performance. X-ray photoelectron spectroscopy results show C[dbnd]O bonds would be increased for the esterification of phosphoric acid from MCAPP. In addition, the production of carbonate can be prohibited while combustion when loading MCAPP.
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| 2. |
- Jiang, L., et al.
(författare)
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Experimental investigation on BOF slag oxidation in air
- 2019
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Ingår i: Ironmaking & steelmaking. - : Taylor and Francis Ltd.. - 0301-9233 .- 1743-2812. ; 46:8, s. 747-754
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Tidskriftsartikel (refereegranskat)abstract
- Basic oxygen furnace (BOF) slag contains a significant amount of iron-containing species, which is considered to be iron resources and therefore need to be recovered. In this work, the oxidation behaviour of BOF slag under air (at selected oxidation temperatures and holding time) was investigated to explore the potential of transforming non-magnetic wustite in the BOF slag into magnetic spinel, which may subsequently be recovered by magnetic separation. The experimental results show that the iron-containing spices in the BOF slag can be oxidised into magnetic spinel phases in the investigated temperature range of 1000–1150°C and thereafter be recovered by magnetic separation. The formation of these phases is closely related to the oxidation temperatures and holding time: a higher oxidation temperature and longer holding time lead to a larger amount of formed magnetic species; however, the amount of formed magnetic species decreases at elevated temperature (>1050°C) and with extended holding time (>40 min).
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