| 261. |
- Svagan, Anna, 1979-, et al.
(författare)
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Biomimetic Foams of High Mechanical Performance Based on Nanostructured Cell Walls Reinforced by Native Cellulose Nanofibrils
- 2008
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Ingår i: Advanced Materials. - Weinheim : Wiley-VCH Verlag GmbH. - 0935-9648 .- 1521-4095. ; 20:7, s. 1263-1269
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Tidskriftsartikel (refereegranskat)abstract
- A bioinspired foam in which cellulose nanofibrils are used to reinforce cell walls (ca. 3 mu m) is presented. The nanocomposite foams are prepared by a lyophilization technique and show composite structure at the cell-wall scale. The nanocellulosic network shows remarkable mechanical performance, expressed in much-improved modulus and yield strength compared with the neat starch foam.
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| 262. |
- Svanstrom, C. M. B., et al.
(författare)
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Device Performance of APFO-3/PCBM Solar Cells with Controlled Morphology
- 2009
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Ingår i: Advanced Materials. - Weinheim : Wiley. - 0935-9648 .- 1521-4095. ; 21:43, s. 4398-
-
Tidskriftsartikel (refereegranskat)abstract
- Polymer/fullerene solar cells with three different device structures: A) diffuse bilayer, B) spontaneously formed multilayer and C) vertically homogeneous thin films, are fabricated. The photocurrent/voltage performance is compared and it is found that the self-stratified structure (B) yields the highest energy conversion efficiency.
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| 263. |
- Svensson, M., et al.
(författare)
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High-performance polymer solar cells of an alternating polyfluorene copolymer and a fullerene derivative
- 2003
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Ingår i: Advanced Materials. - : Wiley. - 0935-9648 .- 1521-4095. ; 15:12, s. 988-991
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Tidskriftsartikel (refereegranskat)abstract
- High-performance polymer solar cells of an alternating polyfluorene copolymer, PFDTBT, and a fullerene derivative were studied. It was shown that PFDTBT is a promising candidate for obtaining high energy conversion efficiency when combined with a suitable electron acceptor. Results showed that high-performance solar cells with extended spectral coverage and increased open-circuit voltage could be prepared from composites prepared from electron acceptor.
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| 264. |
- Tan, Fangchang, et al.
(författare)
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Assembly of AIEgen-Based Fluorescent Metal–Organic Framework Nanosheets and Seaweed Cellulose Nanofibrils for Humidity Sensing and UV-Shielding
- 2022
-
Ingår i: Advanced Materials. - : Wiley. - 0935-9648 .- 1521-4095. ; 34:28, s. 2201470-
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Tidskriftsartikel (refereegranskat)abstract
- Integrating synthetic low-dimensional nanomaterials such as metal–organic framework (MOF) nanosheets with a sustainable biopolymer is a promising strategy to endow composites with attractive structural and functional properties for expanded applications. Herein, aggregation-induced-emission luminogen (AIEgen)-based MOF bulk crystals are successfully exfoliated into ultrathin 2D nanosheets. Seaweed cellulose nanofibrils (CNFs) are assembled with low amounts (0.3 to 4.0 wt%) of the 2D nanosheets to generate luminescent composites. The 2D nanosheets are adsorbed onto the CNFs in dilute water suspensions owing to the flexibility of the MOF nanosheets and the high aspect ratio of the CNFs. Transparent films are prepared by solution casting from a water suspension of the CNF-MOF assembly. The fluorescence emission of the composite films is enhanced because of the favored affinity between MOF nanosheets and CNFs. Remarkably, these films demonstrate excellent UV-shielding capacity and high optical transmittance at the visible wavelength range. The composite films also show reversible changes in fluorescence emission intensity in response to ambient humidity. The tensile strength and modulus of the composite films are also enhanced owing to the increased adhesion between CNFs through the adsorbed MOF nanosheets. This work provides a novel pathway to fabricate luminescent CNFs-based composites with tunable optical properties for functional materials.
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| 265. |
- Tang, Hu, et al.
(författare)
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A Transparent, Hazy, and Strong Macroscopic Ribbon of Oriented Cellulose Nanofibrils Bearing Poly(ethylene glycol)
- 2015
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Ingår i: Advanced Materials. - : Wiley. - 0935-9648 .- 1521-4095. ; 27:12, s. 2070-2076
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Tidskriftsartikel (refereegranskat)abstract
- A macroscopic ribbon of oriented cellulose nanofibrils bearing polyethylene glycol is fabricated by stretching the cellulose nanofibrils network structure in the hydrogel state. The covalently grafted polyethylene glycol on the nanofibril surface facilitates the alignment and compartmentalization of individual nanofibrils in the ribbon. The ribbon has ultrahigh tensile strength (576 +/- 54 MPa), modulus (32.3 +/- 5.7 GPa), high transparency, and haze.
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| 266. |
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| 267. |
- Tang, Zheng, et al.
(författare)
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Interlayer for Modified Cathode in Highly Efficient Inverted ITO-Free Organic Solar Cells
- 2012
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Ingår i: Advanced Materials. - : Wiley. - 0935-9648 .- 1521-4095. ; 24:4, s. 554-
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Tidskriftsartikel (refereegranskat)abstract
- Inverted polymer solar cells with a bottom metal cathode modified by a conjugated polymer interlayer show considerable improvement of photocurrent and fill factor, which is due to hole blocking at the interlayer, and a modified surface energy which affects the nanostructure in the TQ1/[70]PCBM blend.
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| 268. |
- Taylor, Jay M, et al.
(författare)
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Biomimetic and Biologically Compliant Soft Architectures via 3D and 4D Assembly Methods : A Perspective
- 2022
-
Ingår i: Advanced Materials. - : Wiley. - 0935-9648 .- 1521-4095. ; 34:16, s. 2108391-
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Tidskriftsartikel (refereegranskat)abstract
- Recent progress in soft material chemistry and enabling methods of 3D and 4D fabrication—emerging programmable material designs and associated assembly methods for the construction of complex functional structures—is highlighted. The underlying advances in this science allow the creation of soft material architectures with properties and shapes that programmably vary with time. The ability to control composition from the molecular to the macroscale is highlighted—most notably through examples that focus on biomimetic and biologically compliant soft materials. Such advances, when coupled with the ability to program material structure and properties across multiple scales via microfabrication, 3D printing, or other assembly techniques, give rise to responsive (4D) architectures. The challenges and prospects for progress in this emerging field in terms of its capacities for integrating chemistry, form, and function are described in the context of exemplary soft material systems demonstrating important but heretofore difficult-to-realize biomimetic and biologically compliant behaviors.
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| 269. |
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| 270. |
- Thorsmolle, Verner K., et al.
(författare)
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Conduction Through Viscoelastic Phase in a Redox-Active Ionic Liquid at Reduced Temperatures
- 2012
-
Ingår i: Advanced Materials. - : Wiley. - 1521-4095 .- 0935-9648. ; 24:6, s. 781-781
-
Tidskriftsartikel (refereegranskat)abstract
- The phase diagram of the redox active ionic liquid 1-methyl-3-propylimidazolium iodide (PMII) is examined as a function of temperature and iodine concentration. Beyond a threshold concentration of 3.9 M, the formation of higher polyiodides gives rise to a viscoelastic phase upon cooling. Despite of the very high viscosity of such polyiodide-containing PMII melts a strikingly high conductivity is maintained through Grotthuss-type bond exchange and ionic conduction.
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