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| 2. |
- Nicholls, Ian A., et al.
(författare)
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Rational design of biomimetic molecularly imprinted materials : theoretical and computational strategies for guiding nanoscale structured polymer development
- 2011
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Ingår i: Analytical and Bioanalytical Chemistry. - : Springer Science and Business Media LLC. - 1618-2642 .- 1618-2650. ; 400:6, s. 1771-1786
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Forskningsöversikt (refereegranskat)abstract
- In principle, molecularly imprinted polymer science and technology provides a means for ready access to nano-structured polymeric materials of predetermined selectivity. The versatility of the technique has brought it to the attention of many working with the development of nanomaterials with biological or biomimetic properties for use as therapeutics or in medical devices. Nonetheless, the further evolution of the field necessitates the development of robust predictive tools capable of handling the complexity of molecular imprinting systems. The rapid growth in computer power and software over the past decade has opened new possibilities for simulating aspects of the complex molecular imprinting process. We present here a survey of the current status of the use of in silico-based approaches to aspects of molecular imprinting. Finally, we highlight areas where ongoing and future efforts should yield information critical to our understanding of the underlying mechanisms sufficient to permit the rational design of molecularly imprinted polymers.
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| 3. |
- Tehrani, Ali, 1976, et al.
(författare)
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Solubilization of hydrophobic dyes in surfactant solutions
- 2013
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Ingår i: Materials. - : MDPI AG. - 1996-1944. ; 6:2, s. 580-608
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Forskningsöversikt (refereegranskat)abstract
- In this paper, the use of surfactants for solubilization of hydrophobic organic dyes (mainly solvent and disperse dyes) has been reviewed. The effect of parameters such as the chemical structures of the surfactant and the dye, addition of salt and of polyelectrolytes, pH, and temperature on dye solubilization has been discussed. Surfactant self-assemble into micelles in aqueous solution and below the concentration where this occurs-the critical micelle concentration (CMC)-there is no solubilization. Above the CMC, the amount of solubilized dye increases linearly with the increase in surfactant concentration. It is demonstrated that different surfactants work best for different dyes. In general, nonionic surfactants have higher solubilization power than anionic and cationic surfactants. It is likely that the reason for the good performance of nonionic surfactants is that they allow dyes to be accommodated not only in the inner, hydrocarbon part of the micelle but also in the headgroup shell. It is demonstrated that the location of a dye in a surfactant micelle can be assessed from the absorption spectrum of the dye-containing micellar solution.
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| 4. |
- Hyvonen, R., et al.
(författare)
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The likely impact of elevated [CO2], nitrogen deposition, increased temperature and management on carbon sequestration in temperate and boreal forest ecosystems: a literature review
- 2007
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Ingår i: New Phytologist. - Cambridge : Wiley. - 0028-646X .- 1469-8137. ; 173:3, s. 463-480
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Forskningsöversikt (refereegranskat)abstract
- Temperate and boreal forest ecosystems contain a large part of the carbon stored on land, in the form of both biomass and soil organic matter. Increasing atmospheric [CO2], increasing temperature, elevated nitrogen deposition and intensified management will change this C store. Well documented single-factor responses of net primary production are: higher photosynthetic rate (the main [CO2] response); increasing length of growing season (the main temperature response); and higher leaf-area index (the main N deposition and partly [CO2] response). Soil organic matter will increase with increasing litter input, although priming may decrease the soil C stock initially, but litter quality effects should be minimal (response to [CO2], N deposition, and temperature); will decrease because of increasing temperature; and will increase because of retardation of decomposition with N deposition, although the rate of decomposition of high-quality litter can be increased and that of low-quality litter decreased. Single-factor responses can be misleading because of interactions between factors, in particular those between N and other factors, and indirect effects such as increased N availability from temperature-induced decomposition. In the long term the strength of feedbacks, for example the increasing demand for N from increased growth, will dominate over short-term responses to single factors. However, management has considerable potential for controlling the C store.
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| 5. |
- Kumar, M., et al.
(författare)
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Current research trends on micro- and nano-plastics as an emerging threat to global environment : A review
- 2021
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Ingår i: Journal of Hazardous Materials. - : Elsevier. - 0304-3894 .- 1873-3336. ; 409
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Forskningsöversikt (refereegranskat)abstract
- Micro-and nano-plastics (MNPs) (size < 5 mm/<100 nm) epitomize one of the emergent environmental pollutants with its existence all around the globe. Their high persistence nature and release of chemicals/additives used in synthesis of plastics materials may pose cascading impacts on living organism across the globe. Natural connectivity of all the environmental compartments (terrestrial, aquatic, and atmospheric) leads to migration/dispersion of MNPs from one compartment to others. Nevertheless, the information on dispersion of MNPs across the environmental compartments and its possible impacts on living organisms are still missing. This review first acquaints with dispersion mechanisms of MNPs in the environment, its polymeric/oligomeric and chemical constituents and then emphasized its impacts on living organism. Based on the existing knowledge about the MNPs’ constituent and its potential impacts on the viability, development, lifecycle, movements, and fertility of living organism via several potential mechanisms, such as irritation, oxidative damage, digestion impairment, tissue deposition, change in gut microbial communities’ dynamics, impaired fatty acid metabolism, and molecular damage are emphasized. Finally, at the end, the review provided the challenges associated with remediation of plastics pollutions and desirable strategies, policies required along with substantial gaps in MNPs research were recommended for future studies.
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| 6. |
- Larsson, Åke, 1944, et al.
(författare)
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Kustfisk - hälsa
- 2012
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Ingår i: HAVET 2012 - Om miljötillståndet i svenska havsområden. - 1654-6741. ; år 2012
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Forskningsöversikt (refereegranskat)
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| 7. |
- Singh, Deobrat, et al.
(författare)
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Harnessing the unique properties of MXenes for advanced rechargeable batteries
- 2021
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Ingår i: JPhys Energy. - : IOP Publishing. - 2515-7655. ; 3:1
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Forskningsöversikt (refereegranskat)abstract
- In recent years, two-dimensional MXenes have been emerged as potential electrode materials for rechargeable batteries due to their unique properties such as exceptional safety, significant interlayer spacing, environmental flexibility, large surface area, high electrical conductivity, and excellent thermal stability. This review examined all of the recent advances in the field of MXenes and their composites (hybrid structures), which are found to be useful for the electrochemical applications of advanced rechargeable batteries. The main focus of this review is on metal-ion batteries and lithium-sulfur (Li-S) batteries. It is intended to show that the combination of recent improvements in the synthesis and characterization, greater control of the interlayer distance, and new MXene composites, together serve as an emerging and potential way for energy storage applications.
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| 8. |
- Havenhand, Jonathan N., 1959, et al.
(författare)
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Ecological and functional consequences of coastal ocean acidification : Perspectives from the Baltic-Skagerrak System
- 2019
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Ingår i: Ambio. - : Springer Science and Business Media LLC. - 0044-7447 .- 1654-7209. ; 48:8, s. 831-854
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Forskningsöversikt (refereegranskat)abstract
- Ocean temperatures are rising; species are shifting poleward, and pH is falling (ocean acidification, OA). We summarise current understanding of OA in the brackish Baltic-Skagerrak System, focussing on the direct, indirect and interactive effects of OA with other anthropogenic drivers on marine biogeochemistry, organisms and ecosystems. Substantial recent advances reveal a pattern of stronger responses (positive or negative) of species than ecosystems, more positive responses at lower trophic levels and strong indirect interactions in food-webs. Common emergent themes were as follows: OA drives planktonic systems toward the microbial loop, reducing energy transfer to zooplankton and fish; and nutrient/food availability ameliorates negative impacts of OA. We identify several key areas for further research, notably the need for OA-relevant biogeochemical and ecosystem models, and understanding the ecological and evolutionary capacity of Baltic-Skagerrak ecosystems to respond to OA and other anthropogenic drivers.
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| 9. |
- Öhrström, Lars, 1963
(författare)
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Now you see me too Attaching chiral molecules to a chiral framework allows their molecular structures to be determined
- 2016
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Ingår i: Science. - : American Association for the Advancement of Science (AAAS). - 0036-8075 .- 1095-9203. ; 353:6301, s. 754-755
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Forskningsöversikt (refereegranskat)abstract
- Knowledge of three-dimensional (3D) molecular structures is crucial for scientific advances in fields ranging from materials chemistry to medicine. For solar cell materials, human proteins, or new drugs, the revelation of the exact arrangement of atoms and bonds vastly advances understanding of their properties. On page 808 of this issue, Lee et al. (1) report an approach that allows better structural data to be obtained for large, complex organic molecules that are difficult to crystallize on their own.
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| 10. |
- Hanson, Niklas, 1976, et al.
(författare)
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Förändringar i fiskhälsa - orsaker söks på bred front
- 2012
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Ingår i: HAVET 2012 - Om miljötillståndet i svenska havsområden. - 1654-6741. ; år 2012, s. 85-87
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Forskningsöversikt (refereegranskat)abstract
- Kustfiskens hälsa har blivit allt mer påverkad under de senaste 20–25 åren. Mycket tyder på att det beror på miljögifter. Samtidigt minskar halterna av de miljögifter som övervakas i samma fiskar. Det tyder på att det är andra, kanske okända, miljögifter som ligger bakom. I ett nytt samverkansprojekt ska man försöka ta reda på orsakerna.
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