| 1. |
- Zamecnikova, M., et al.
(författare)
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Formation of CO+ by radiative association
- 2019
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Ingår i: Monthly Notices of the Royal Astronomical Society. - : Oxford University Press (OUP). - 0035-8711 .- 1365-2966. ; 489:2, s. 2954-2960
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Tidskriftsartikel (refereegranskat)abstract
- We theoretically estimate formation rate coefficients for CO+ through the radiative association of C+(P-2) with O(P-3). In 1989, Petuchowski et al. claimed radiative association to be the most important route for CO+ formation in SN 1987A. In 1990, Dalgarno, Du and You challenged this claim. Therefore, in this study, we improve previous estimates of the radiative association rate coefficients for forming CO+ from C+(P-2) and O(P-3). To do this, we perform quantum mechanically based perturbation theory calculations as well as semiclassical calculations, which are combined with Breit-Wigner theory in order to add the effect of shape resonances. We explicitly include four electronic transitions. The required potential energy and transition dipole-moment curves are obtained through large basis set multireference configuration interaction electronic structure calculations. We report cross-sections and from these we obtain rate coefficients in the range of 10-10 000 K, finding that the CO+ formation rate coefficient is larger than the previous estimate by Dalgarno et al. Still our results support their claim that in SN 1987A, CO is mainly formed through radiative association and not through the charge transfer reaction CO+ + O -> CO + O+ as earlier suggested by Petuchowski et al.
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| 2. |
- Andersen, Torben, et al.
(författare)
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Image-based wavefront sensing for astronomy using neural networks
- 2020
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Ingår i: Journal of Astronomical Telescopes, Instruments, and Systems. - : SPIE - International Society for Optical Engineering. - 2329-4124. ; 6:3
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Tidskriftsartikel (refereegranskat)abstract
- Motivated by the potential of non-diffraction limited, real-time computational image sharpening with neu7 ral networks in astronomical telescopes, we have studied wavefront sensing with convolutional neural networks basedon a pair of in-focus and out-of-focus point spread functions. By simulation, we generated a large dataset for trainingand validation of neural networks, and trained several networks to estimate Zernike polynomial approximations forthe incoming wavefront. We included the effect of noise, guide star magnitude, blurring by wide band imagining, andbit depth. We conclude that the “ResNet” works well for our purpose, with a wavefront RMS error of 130 nm forr0 = 0.3 m, guide star magnitudes 4–8, and inference time of 8 ms. It can also be applied for closed-loop operation inan adaptive optics system. We also studied the possible use of a Kalman filter or a recurrent neural network and foundthat they were not beneficial to performance of our wavefront sensor
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| 3. |
- Zámečníková, Martina, et al.
(författare)
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Formation of CO+ by radiative association II
- 2020
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Ingår i: Monthly notices of the Royal Astronomical Society. - : Oxford University Press. - 0035-8711 .- 1365-2966. ; 492:3, s. 3794-3802
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Tidskriftsartikel (refereegranskat)abstract
- Radiative association of an oxygen atom with a carbon cation is investigated using quantal and semiclassical methods. The total rate coefficient for spontaneous radiative association of O(2s22p4, 3P) with C+(2s22p, 2P) on the doublet manifold is determined from the corresponding cross-sections. The cross-sections for the 12 Σ - → A2 II, 22 Σ - → A2II, and C2 Δ → A2II continuum-bound processes are calculated either semiclassically, in combination with the Breit-Wigner approach, or fully quantum mechanically. In the temperature range 10-10 000 K, our recommended total rate coefficient, obtained from these calculations and the data of Zámecniková et al. (2019), slowly increases from 7.5 × 10-18 cm3s-1 to 2.1 × 10-17 cm3s-1. Corresponding aspects of the CO+ and CO formations in SN 1987A are discussed
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| 4. |
- Waara, Martin, 1980-, et al.
(författare)
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Statistical evidence for O+ energization and outflow caused by wave-particle interaction in the high altitude cusp and mantle
- 2011
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Ingår i: Annales Geophysicae. - Göttingen : Copernicus Gesellschaft. - 0992-7689 .- 1432-0576. ; 29, s. 945-954
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Tidskriftsartikel (refereegranskat)abstract
- We present a statistical study of the low (<1 Hz) frequency electric and magnetic field spectral densities observed by Cluster spacecraft in the high altitude cusp and mantle region. At the O+ gyrofrequency (0.02–0.5 Hz) for this region the electric field spectral density is on average 0.2–2.2 (mV m−1)2 Hz−1, implying that resonant heating at the gyrofrequency can be intense enough to explain the observed O+ energies of 20–1400 eV. The relation between the electric and magnetic field spectral densities results in a large span of phase velocities, from a few hundred km s−1 up to a few thousand km s−1. In spite of the large span of phase velocity, the ratio between the calculated local Alfvén velocity and the estimated phase velocity is close to unity. We provide average values of a coefficient describing diffusion in ion velocity space at different altitudes, which can be used in studies of ion energization and outflow. The observed average waves can explain the average O+ energies measured in the high altitude (8–15 RE) cusp/mantle region of the terrestrial magnetosphere according to our test particle calculations.
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| 5. |
- Gustafsson, Magnus
(författare)
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Diatom-diatom interactions with light : Applications and line shape theoretical aspects
- 2008
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Ingår i: Spectral line shapes, volume 15. - Melville, NY : American Institute of Physics (AIP). - 9780735405882 ; 15, s. 297-301
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Konferensbidrag (refereegranskat)abstract
- Recent advances in calculations of collision-induced absorption- and Raman-spectra in pure diatomic gases are presented. An extensive calculation of H2-H2 absorption from 40 K to 400 K has provided improved understanding of the atmosphere of Uranus. A highly advanced close-coupling calculation of H2-H2 light scattering has verified that the line shapes are affected by interference between the permanent H2 and the H2-H2 interaction-induced polarizabilities. A few directions that the research in astrophysical applications of collision-induced absorption is taking are also described. For instance, H2-H 2 dipole and potential surfaces for vibrations higher than v = 1 are currently being developed to enable simulations of collision-induced absorption at temperatures relevant for white dwarf atmospheres. For low temperature N 2-N2 absorption there is unresolved discrepancy between measurement and simulation. A possible solution to this puzzle is suggested
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| 6. |
- Schultheis, M., et al.
(författare)
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Gaia Data Release 3: Exploring and mapping the diffuse interstellar band at 862 nm
- 2023
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Ingår i: Astronomy and Astrophysics. - : EDP Sciences. - 0004-6361 .- 1432-0746. ; 674
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Tidskriftsartikel (refereegranskat)abstract
- Context. Diffuse interstellar bands (DIBs) are common interstellar absorption features in spectroscopic observations but their origins remain unclear. DIBs play an important role in the life cycle of the interstellar medium (ISM) and can also be used to trace Galactic structure.Aims. Here, we demonstrate the capacity of the Gaia-Radial Velocity Spectrometer (RVS) in Gaia DR3 to reveal the spatial distribution of the unknown molecular species responsible for the most prominent DIB at 862 nm in the RVS passband, exploring the Galactic ISM within a few kiloparsecs from the Sun.Methods. The DIBs are measured within the GSP-Spec module using a Gaussian profile fit for cool stars and a Gaussian process for hot stars. In addition to the equivalent widths and their uncertainties, Gaia DR3 provides their characteristic central wavelength, width, and quality flags.Results. We present an extensive sample of 476 117 individual DIB measurements obtained in a homogeneous way covering the entire sky. We compare spatial distributions of the DIB carrier with interstellar reddening and find evidence that DIB carriers are present in a local bubble around the Sun which contains nearly no dust. We characterised the DIB equivalent width with a local density of 0.19 ± 0.04 kpc1 and a scale height of 98.60 8.46+11.10 pc. The latter is smaller than the dust scale height, indicating that DIBs are more concentrated towards the Galactic plane. We determine the rest-frame wavelength with unprecedented precision (?0 = 8620.86 ± 0.019 in air) and reveal a remarkable correspondence between the DIB velocities and the CO gas velocities, suggesting that the 862 nm DIB carrier is related to macro-molecules. Conclusions. We demonstrate the unique capacity of Gaia to trace the spatial structure of the Galactic ISM using the 862 nm DIB.
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| 7. |
- Tinetti, Giovanna, et al.
(författare)
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The EChO science case
- 2015
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Ingår i: Experimental astronomy. - : Springer Science and Business Media LLC. - 0922-6435 .- 1572-9508. ; 40:2-3, s. 329-391
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Tidskriftsartikel (refereegranskat)abstract
- The discovery of almost two thousand exoplanets has revealed an unexpectedly diverse planet population. We see gas giants in few-day orbits, whole multi-planet systems within the orbit of Mercury, and new populations of planets with masses between that of the Earth and Neptune-all unknown in the Solar System. Observations to date have shown that our Solar System is certainly not representative of the general population of planets in our Milky Way. The key science questions that urgently need addressing are therefore: What are exoplanets made of? Why are planets as they are? How do planetary systems work and what causes the exceptional diversity observed as compared to the Solar System? The EChO (Exoplanet Characterisation Observatory) space mission was conceived to take up the challenge to explain this diversity in terms of formation, evolution, internal structure and planet and atmospheric composition. This requires in-depth spectroscopic knowledge of the atmospheres of a large and well-defined planet sample for which precise physical, chemical and dynamical information can be obtained. In order to fulfil this ambitious scientific program, EChO was designed as a dedicated survey mission for transit and eclipse spectroscopy capable of observing a large, diverse and well-defined planet sample within its 4-year mission lifetime. The transit and eclipse spectroscopy method, whereby the signal from the star and planet are differentiated using knowledge of the planetary ephemerides, allows us to measure atmospheric signals from the planet at levels of at least 10(-4) relative to the star. This can only be achieved in conjunction with a carefully designed stable payload and satellite platform. It is also necessary to provide broad instantaneous wavelength coverage to detect as many molecular species as possible, to probe the thermal structure of the planetary atmospheres and to correct for the contaminating effects of the stellar photosphere. This requires wavelength coverage of at least 0.55 to 11 mu m with a goal of covering from 0.4 to 16 mu m. Only modest spectral resolving power is needed, with R similar to 300 for wavelengths less than 5 mu m and R similar to 30 for wavelengths greater than this. The transit spectroscopy technique means that no spatial resolution is required. A telescope collecting area of about 1 m(2) is sufficiently large to achieve the necessary spectro-photometric precision: for the Phase A study a 1.13 m(2) telescope, diffraction limited at 3 mu m has been adopted. Placing the satellite at L2 provides a cold and stable thermal environment as well as a large field of regard to allow efficient time-critical observation of targets randomly distributed over the sky. EChO has been conceived to achieve a single goal: exoplanet spectroscopy. The spectral coverage and signal-to-noise to be achieved by EChO, thanks to its high stability and dedicated design, would be a game changer by allowing atmospheric composition to be measured with unparalleled exactness: at least a factor 10 more precise and a factor 10 to 1000 more accurate than current observations. This would enable the detection of molecular abundances three orders of magnitude lower than currently possible and a fourfold increase from the handful of molecules detected to date. Combining these data with estimates of planetary bulk compositions from accurate measurements of their radii and masses would allow degeneracies associated with planetary interior modelling to be broken, giving unique insight into the interior structure and elemental abundances of these alien worlds. EChO would allow scientists to study exoplanets both as a population and as individuals. The mission can target super-Earths, Neptune-like, and Jupiter-like planets, in the very hot to temperate zones (planet temperatures of 300-3000 K) of F to M-type host stars. The EChO core science would be delivered by a three-tier survey. The EChO Chemical Census: This is a broad survey of a few-hundred exoplanets, which allows us to explore the spectroscopic and chemical diversity of the exoplanet population as a whole. The EChO Origin: This is a deep survey of a subsample of tens of exoplanets for which significantly higher signal to noise and spectral resolution spectra can be obtained to explain the origin of the exoplanet diversity (such as formation mechanisms, chemical processes, atmospheric escape). The EChO Rosetta Stones: This is an ultra-high accuracy survey targeting a subsample of select exoplanets. These will be the bright "benchmark" cases for which a large number of measurements would be taken to explore temporal variations, and to obtain two and three dimensional spatial information on the atmospheric conditions through eclipse-mapping techniques. If EChO were launched today, the exoplanets currently observed are sufficient to provide a large and diverse sample. The Chemical Census survey would consist of > 160 exoplanets with a range of planetary sizes, temperatures, orbital parameters and stellar host properties. Additionally, over the next 10 years, several new ground- and space-based transit photometric surveys and missions will come on-line (e.g. NGTS, CHEOPS, TESS, PLATO), which will specifically focus on finding bright, nearby systems. The current rapid rate of discovery would allow the target list to be further optimised in the years prior to EChO's launch and enable the atmospheric characterisation of hundreds of planets.
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| 8. |
- Jones, Daria, et al.
(författare)
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Formation of the CH/CD molecules through radiative association of C with H/D
- 2022
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Ingår i: Monthly Notices of the Royal Astronomical Society. - : Oxford University Press (OUP). - 0035-8711 .- 1365-2966. ; 517:4, s. 4892-4901
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Tidskriftsartikel (refereegranskat)abstract
- Reaction rate constants have been calculated for the formation of CH and CD molecules through radiative association of C and H/D atoms in their ground states. Quantum mechanical and semiclassical/classical methods were used to obtain the reaction cross-sections. Shape resonances and inverse pre-dissociation are accounted for with Breit-Wigner theory. The potential, permanent/transition dipole moment curves and experimental pre-dissociation widths are taken from the literature. The resulting reaction rate constants were fitted to the Kooij formula for use in astrochemical modelling. Our rate constant is 3.5 x 10(-17) cm(3) s(-1) at 100 K and it peaks at 20 K, where it is 8.0 x 10(-17) cm(3) s(-1). These values are larger than what has been obtained in earlier studies but not large enough to account for the interstellar abundance of CH.
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| 9. |
- Gustafsson, Magnus, et al.
(författare)
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Radiative association rate constant for the formation of CO: the importance of the first excited (1)Sigma(+) state
- 2015
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Ingår i: Monthly Notices of the Royal Astronomical Society. - : Oxford University Press (OUP). - 0035-8711 .- 1365-2966. ; 448:3, s. 2562-2565
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Tidskriftsartikel (refereegranskat)abstract
- The thermal rate constant for production of carbon monoxide, in its electronic ground state, through radiative association of carbon (C) and oxygen (O) atoms is computed. A combination of quantum and classical dynamics methods are employed. In particular, we investigate the importance of the mechanism where C and O approach each other on the 2(1)Sigma(+) potential energy curve. Accounting for this reaction turns out to add about 75 per cent to the rate constant at 10 000 K. We expect the results to be important for studies of the chemistry in interstellar gas, particularly in metal-rich ejecta of supernovae. Since a significant isotope effect has been predicted previously both stable carbon isotopes C-12 and C-13 are considered in the present study.
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| 10. |
- Kathir, R. K., et al.
(författare)
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The rate constant for formation of HCl through radiative association
- 2017
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Ingår i: Monthly Notices of the Royal Astronomical Society. - : Oxford University Press (OUP). - 0035-8711 .- 1365-2966. ; 470:3, s. 3068-3070
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Tidskriftsartikel (refereegranskat)abstract
- Formation of HCl in its electronic ground state through radiative association is studied. We ignore spin-orbit couplings and then the formation can happen through two dipole-allowed reactions, one involving an electronic transition and one where the H and Cl atoms approach and remain in the ground electronic molecular state. The radiative association rate constant is computed, through a combination of classical and quantum methods, for use in modelling of interstellar chemistry.
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