| 1. |
- Hrachowina, Lukas, et al.
(författare)
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Realization of axially defined GaInP/InP/InAsP triple-junction photovoltaic nanowires for high-performance solar cells
- 2022
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Ingår i: Materials Today Energy. - : Elsevier BV. - 2468-6069. ; 27
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Tidskriftsartikel (refereegranskat)abstract
- III-V semiconductor-based planar multi-junction solar cells synthesized to match the solar spectrum, increase absorption, and reduce thermalization loss are today's world-record efficiency solar cells. Realizing similarly performing multi-junction III-V nanowire (NW) solar cells would require significantly less material and is more sustainable at lower cost than planar solar cells. The NW geometry allows expanding the range of compatible material combinations along the NW axis far beyond current multi-junction solar cells and enables promising applications in, for example, space power technology and smart windows. However, multi-junction NW photovoltaics have been hampered by the inability to electrically connect different materials in an axial geometry. We report the design and proof-of-principle demonstration of axially defined GaInP/InP/InAsP triple-junction photovoltaic NWs optimized for light absorption exhibiting an open-circuit voltage of up to 2.37 V. The open-circuit voltage is twice as large as previously reported for tandem-junction photovoltaic NWs and amounts to 94% of the sum of the respective single-junction NWs. Our findings pave the way for realizing the next generation of scalable, high-performance, and ultra-high power-to-weight ratio multi-junction, NW-based solar cells.
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| 2. |
- Yang, Xianzhong, et al.
(författare)
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Plasmon-exciton coupling of monolayer MoS2-Ag nanoparticles hybrids for surface catalytic reaction
- 2017
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Ingår i: Materials Today Energy. - : Elsevier BV. - 2468-6069. ; 5, s. 72-78
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Tidskriftsartikel (refereegranskat)abstract
- The optical properties of monolayer molybdenum disulfide (MoS2)/Ag nanoparticle (NP) hybrids and their application to surface catalytic reactions were studied by transmission, photoluminescence (PL) and Raman spectroscopies. The local surface plasmon resonance (LSPR) of Ag nanoparticles was tuned to better match the exciton energy of monolayer MoS2. The PL of the hybrids was enhanced by more than 50 times when the local surface plasmon resonance (LSPR) peak was tuned systematically from 438 nm to 532 nm, indicating a stronger coupling and higher energy transfer rate between the plasmon of the Ag NPs and the excitons of the MoS2. Additionally, photocatalytic reactions of 4-nitrobenzenethiol (4NBT) were performed on the MoS2, the Ag nanoparticles, and the hybrid MoS2 with Ag nanoparticles. On the MoS2 substrate alone, there is no photocatalytic reaction. With a low laser intensity, the probability of a chemical reaction occurring for molecules directly adsorbed onto the Ag NPs is much lower than the probability of a reaction involving those molecules adsorbed onto the MoS2/Ag substrate. At a higher power, although the electric field was reduced by approximately 30% by the MoS2 layer, there is better efficiency for the plasmon-exciton co-driven surface catalytic reactions on the MoS2/Ag substrate compared to the Ag substrate alone. Our findings illustrate the potential to control hot carriers for better surface catalytic reactions by tuning the exciton-plasmon coupling between the 2D transition metal dichalcogenides (TMDCs) and Ag NPs.
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