| 1. |
- Rashid, Hayder M., et al.
(författare)
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Novel material from immobilization of magnesium oxide and cetyl trimethyl ammonium bromide nanoparticles onto waterworks sludge for removing methylene blue from aqueous solution
- 2023
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Ingår i: Journal of King Saud University - Science. - : Elsevier. - 1018-3647. ; 35:6
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Tidskriftsartikel (refereegranskat)abstract
- Utilizing the waterworks sludge byproduct in the treatment of wastewater contained methylene blue dye is one approach that has been taken in an effort to lessen the difficulties that are associated with managing such byproduct. The prime aim of this work is manufacturing of novel sorbent from co-precipitation of magnesium oxide nanoparticles on the surfaces of waterworks sludge in the existence of cetyl trimethyl ammonium bromide surfactant. Surfactant 0.04 g/50 mL, dose of sludge 2 g/50 mL, and pH 12 were the most efficient preparation parameters to remove 75.31% of adopted dye. The adsorption studies were conducted under various conditions of contact time (0–240 min), concentration of dye (10–300 mg/L), sorbent mass (0.05–1.5 g), and solution pH (3–12). The best values of batch parameters were identical to the highest percentages of contaminant removal. Results proved that the magnesium oxide nanoparticles are attached to the sludge surfaces. Freundlich and pseudo-second-order models have perfectly described sorption results with 59.92 mg/g maximum sorption capacity. The breakthrough curves can be accurately described by the Bohart-Adams model. The outputs of continuous tests have been paved the way for future usage of the prepared sorbent in the field permeable reactive barrier technology.
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| 2. |
- Faisal, Ayad A. H, et al.
(författare)
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Controlling metal ion migration in contaminated groundwater with Iraqi clay barriers for water resource protection
- 2023
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Ingår i: RSC Advances. - : Royal Society of Chemistry. - 2046-2069. ; 13:24, s. 16196-16205
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Tidskriftsartikel (refereegranskat)abstract
- This study investigates the effectiveness of using Iraqi clay as a low-permeability layer to prevent the migration of lead and nickel ions in groundwater-aquifers. Tests of batch operation have been conducted to determine the optimal conditions for removing Pb2+ ions, which were found to be 120 minutes of contact time, a pH of 5, 0.12 g of clay per 100 mL of solution, and an agitation of 250 rpm. These conditions resulted in a 90% removal efficiency for a 50 mg L−1 initial concentration of lead ions. To remove nickel ions with an efficiency of 80%, the optimal conditions were 60 minutes of contact time, a pH of 6, 12 g of clay per 100 mL of solution, and an agitation of 250 rpm. Several sorption models were evaluated, and the Langmuir formula was found to be the most effective. The highest sorption capacities were 1.75 and 137 mg g−1 for nickel and lead ions, respectively. The spread of metal ions was simulated using finite element analysis in the COMSOL multiphysics simulation software, taking into account the presence of a clay barrier. The results showed that the barrier creates low-discharge zones along the down-gradient of the barrier, reducing the rate of pollutant migration to protect the water sources.
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| 3. |
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| 4. |
- Hommadi, Ali H., et al.
(författare)
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Evaluation of Actual Evapotranspiration and Crop Coefficient in Carrot by Remote Sensing Methodology Using Drainage and River Water to Overcome Reduced Water Availability
- 2023
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Ingår i: Engineering. - : Scientific Research Publishing. - 1947-3931 .- 1947-394X. ; 15:05, s. 352-366
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Tidskriftsartikel (refereegranskat)abstract
- Searching for alternative methods for traditional irrigation is World trend at days due to a reduction in water and increased of drought due to climate changes therefore farmers need use modern methods of scheduling water and minimizing water losses while also increasing yield. To meet the future increasing demands water and food there is a need to utilize alternative methods to reduce evaporation, transpiration and deep percolation of water. Any countries use recycled water (drain and sewage) and desalination water from the sea or drains to irrigate crops plus computing actual crop evapotranspiration (ETc) so as to calculate the amount of water to apply to a crop.The paper aims to assess the actual evaporation and evaporation coefficient of carrots, by planting carrots in a field and the crop was exposed to several sources of water (DW and RW) and comparing ETc, Kc and production among plots of three sites (A, B and C). The study used two types of irrigation water (drain water (DW) and river water (RW)). The results were to monthly rate and accumulated actual evapotranspiration to C (irrigation by RW only) more than A (67% RW and 33% DW) and B (17% RW and 83%DW) via 7% and 58%, respectively. The yield to C more than A and B by 17% and 75%, respectively. In conclusion the use of DW can cause a reduction in crop consumptive of carrot crops also causes a reduction in yield, crop length, root length, root size, canopy of crop, number of leaves and biomass of the plant therefore, the drainage water needs to treated before irrigating crops And making use of it to irrigate the fields and fill the shortfall in the amount of water from the river. The drain water helped on filling the water shortage due to climate changes and giving production of carrot crop but less than river water.
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| 5. |
- Naji, Laith A., et al.
(författare)
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Modification of Langmuir model for simulating initial pH and temperature effects on sorption process
- 2020
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Ingår i: Separation science and technology (Print). - UK : Taylor & Francis. - 0149-6395 .- 1520-5754. ; 55:15, s. 2729-2736
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Tidskriftsartikel (refereegranskat)abstract
- The present study modifies the sorption isothermfor simulating the influences of initial pH and temperature variations on thecadmium sorption from contaminated water using waste foundry sand based on Langmuir,Freundlich and Temkin models. Results proved that the Langmuir expression is ableto adopt these effects by relating sorption capacity and affinity constantswith pH and temperature of aqueous solution through exponential relationships (determinationcoefficient = 0.9375). The present model is assumed that the sorption process occursthrough acidic functional groups and this is consistent with FTIR outputs. Interactionof cadmium/WFS is found to be exothermic by thermodynamic analysis.
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| 6. |
- Tao, Hai, et al.
(författare)
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Machine learning algorithms for high-resolution prediction of spatiotemporal distribution of air pollution from meteorological and soil parameters
- 2023
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Ingår i: Environment International. - : Elsevier. - 0160-4120 .- 1873-6750. ; 175
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Tidskriftsartikel (refereegranskat)abstract
- This study uses machine learning (ML) models for a high-resolution prediction (0.1°×0.1°) of air fine particular matter (PM2.5) concentration, the most harmful to human health, from meteorological and soil data. Iraq was considered the study area to implement the method. Different lags and the changing patterns of four European Reanalysis (ERA5) meteorological variables, rainfall, mean temperature, wind speed and relative humidity, and one soil parameter, the soil moisture, were used to select the suitable set of predictors using a non-greedy algorithm known as simulated annealing (SA). The selected predictors were used to simulate the temporal and spatial variability of air PM2.5 concentration over Iraq during the early summer (May-July), the most polluted months, using three advanced ML models, extremely randomized trees (ERT), stochastic gradient descent backpropagation (SGD-BP) and long short-term memory (LSTM) integrated with Bayesian optimizer. The spatial distribution of the annual average PM2.5 revealed the population of the whole of Iraq is exposed to a pollution level above the standard limit. The changes in temperature and soil moisture and the mean wind speed and humidity of the month before the early summer can predict the temporal and spatial variability of PM2.5 over Iraq during May-July. Results revealed the higher performance of LSTM with normalized root-mean-square error and Kling-Gupta efficiency of 13.4% and 0.89, compared to 16.02% and 0.81 for SDG-BP and 17.9% and 0.74 for ERT. The LSTM could also reconstruct the observed spatial distribution of PM2.5 with MapCurve and Cramer's V values of 0.95 and 0.91, compared to 0.9 and 0.86 for SGD-BP and 0.83 and 0.76 for ERT. The study provided a methodology for forecasting spatial variability of PM2.5 concentration at high resolution during the peak pollution months from freely available data, which can be replicated in other regions for generating high-resolution PM2.5 forecasting maps.
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| 7. |
- Abbas, Nahlah, et al.
(författare)
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The Impacts of Sea Level Rise on Basrah City,Iraq : The Impacts of Sea Level Rise on Basrah City,Iraq
- 2020
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Ingår i: Open Journal of Geology. - USA : Scientific Research Publishing. - 2161-7570 .- 2161-7589. ; 10:12, s. 1189-1197
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Tidskriftsartikel (refereegranskat)abstract
- Sea Level Rise (SLR) above the Mean Sea Level (MSL) is more likely to cause a significant risk to the coastal regions. This research explores the potential impact of sea level rise, due to climate change, on coastal areas. It examines the impact of sea level rise on Basrah city and adjacent cities in Iraq. A digital elevation model (DEM) was used to create a model of Potentially Inundated Areas, manipulated and processed in Geographical Information System version 10.7 (ArcGIS 10.7). Through this model, the impact of sea level rise was assessed on the surface area. After the susceptible areas were delineated, it was estimated that at worst case scenario of 5 m sea level rise will impact Basrah city by losing 38 percent of its total surface area.
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| 8. |
- Abdulredha, Muhammad, et al.
(författare)
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Electrochemical defluorination of water: an experimental and morphological study
- 2022
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Ingår i: Journal of Water, Sanitation and Hygiene for Development. - : IWA Publishing. - 2043-9083 .- 2408-9362. ; 12:4, s. 394-404
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Tidskriftsartikel (refereegranskat)abstract
- This experimental study concerns the elimination of fluoride from water using an electrocoagulation reactor having a variable flow direction in favour of increasing the electrolysing time, saving the reactor area, and water mixing. The detention time of the space-saver EC reactor (S-SECR) was measured and compared to the traditional reactors using an inert dye (red drain dye). Then, the influence of electrical current (1.5 ≤ δ ≤ 3.5 mA cm−2), pH of water (4 ≤ pH ≤ 10), and distance between electrodes (5 ≤ ϕ ≤ 15) on the defluoridation of water was analysed. The effect of the electrolysing activity on the electrodes' morphology was studied using scanning electron microscopy (SEM). Additionally, the operational cost was calculated. The results confirmed the removal of fluoride using S-SECR met the guideline of the World Health Organization (WHO) for fluoride levels in drinking water of ≤1.5 mg/L. S-SECR abated fluoride concentration from 20 mg/L to the WHO's guideline at δ, ϕ, pH, operational cost, and power consumption of 2.5 mA cm−2, 5 mm, 7, 0.346 USD m−3, and 5.03 kWh m−3, respectively. It was also found the S-SECR enhanced the detention time by 190% compared to the traditional reactors. The appearance of dents and irregularities on the surface of anodes in the SEM images proves the electrolysing process.
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| 9. |
- Ahmed, Dooraid N., et al.
(författare)
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Waste foundry sand/MgFe-layered double hydroxides composite material for efficient removal of Congo red dye from aqueous solution
- 2020
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Ingår i: Scientific Reports. - USA : Nature Publishing Group. - 2045-2322. ; 10, s. 1-12
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Tidskriftsartikel (refereegranskat)abstract
- We aimed to obtain magnesium/iron (Mg/Fe)-layered double hydroxides (LDHs) nanoparticles-immobilized on waste foundry sand-a byproduct of the metal casting industry. XRD and FT-IR tests were applied to characterize the prepared sorbent. The results revealed that a new peak reflected LDHs nanoparticles. In addition, SEM-EDS mapping confirmed that the coating process was appropriate. Sorption tests for the interaction of this sorbent with an aqueous solution contaminated with Congo red dye revealed the efficacy of this material where the maximum adsorption capacity reached approximately 9127.08 mg/g. The pseudo-first-order and pseudo-second-order kinetic models helped to describe the sorption measurements, indicating that the physical and chemical forces governed the removal process.
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| 10. |
- Akram, Revan, et al.
(författare)
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Source Rock Evaluation and 1-D Basin Modelling Approach for the Sargelu Formation, Atrush-2 Well, Kurdistan Region-Iraq
- 2021
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Ingår i: Open Journal of Geology. - USA : Scientific Research Publishing. - 2161-7570 .- 2161-7589. ; 11:3, s. 49-60
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Tidskriftsartikel (refereegranskat)abstract
- The present study focuses on source rock evaluation of the Sargelu Formation by using core chips of rocks collected from well Atrush-2, Duhok, Kurdistan Region-Iraq. The Rock-Eval pyrolysis and vitrinite reflectance were executed. Subsequently, the selected parameters were used for source rock evaluation and 1-D Basin Modelling calibration. The upper part of the formation mainly comprises argillaceous limestone with low content of organic matter (0.64% - 1% TOC). By contrast, the lower part is dominated with shale interval and contains high amounts of TOC values (>4% for 1272 - 1278 m) reveling good to very good quality source rock. Accordingly, good to very good hydrocarbon generation potential is suggested for this formation. Organic matter of the Sargelu Formation contains type II and mixed-type II-III kerogen. The values of Tmax and vitrinite reflectance (Ro%) demonstrate that the formation is thermally mature and in the oil zone. In order to construct a thermal history of the formation and determine the timing of hydrocarbon maturation and generation, the 1-D basin modelling PetroMod 2019.1 was used in this study. Based on the 1-D Basin modelling simulation and its outputs, about 3500 m of overburden have been eroded at the study area. The present-day heat flow was found to be 30 mW/m2. The organic matter of Sargelu Formation entered the early oil zone in 64 Ma and reached the main oil zone ca. 5 Ma. The formation is still in the main oil zone at present-day. In well Atrush-2, the highest rate of oil generation for the Sargelu Formation was in the 8.5 Ma, the onset of oil expulsion from Sargelu Formation was in 50 Ma and the expulsion mass has been reached 0.5 Mtons at present-day.
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