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Träfflista för sökning "WFRF:(Boström Dan) ;pers:(Shchukarev Andrey)"

Sökning: WFRF:(Boström Dan) > Shchukarev Andrey

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1.
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2.
  • Gemo, Nicola, et al. (författare)
  • TiO2 nanoparticles vs. TiO2 nanowires as support in hydrogen peroxide direct synthesis : the influence of N and Au doping
  • 2016
  • Ingår i: RSC Advances. - : Royal Society of Chemistry. - 2046-2069. ; 6:105, s. 103311-103319
  • Tidskriftsartikel (refereegranskat)abstract
    • The performance of Pd on titania support were evaluated in the direct synthesis of hydrogen peroxide. The equipment used was a high pressure, semi-batch apparatus equipped with a special injection system. Pd (1 wt%) catalysts on TiO2 materials with different nature were prepared by wet impregnation method. Three aspects were investigated: (a) the structure of the support (nanoparticles vs. nanowires); (b) the addition of a second active metal (Au); (c) the influence of N-doping of the support. All samples were characterized by means of XPS, TEM and XRD analyses. TiO2 nanoparticle supported catalyst demonstrated higher H2O2 selectivity and higher turnover frequency (TOF) than the catalysts based on TiO2 nanowires. The addition of Au to the Pd TiO2 nanowire catalyst improved the H2O2 selectivity due to altered particle size and electronic effects. Both N-doped versions of the catalysts gave rise to higher H2O2 selectivity than the parent non-doped ones. The synthetic procedure was the source of this observation: larger mean Pd nanoparticles were present, thus favouring the formation of H2O2 as the primary product.
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3.
  • Kaplun, Marina, et al. (författare)
  • Crystal structures and spectroscopic properties of palladium complexes isolated from Pd–EDTA solutions
  • 2005
  • Ingår i: Inorganica Chimica Acta. - : Elsevier. - 0020-1693 .- 1873-3255. ; 358:3, s. 527-534
  • Tidskriftsartikel (refereegranskat)abstract
    • Two complexes were isolated from aqueous Pd(NO3)2–Na2H2EDTA solutions and studied by single crystal X-ray diffraction, IR/Raman spectroscopy, and photoelectron spectroscopy. The first complex, Pd(Hkpda)2 (kpda = ketopiperazinediacetate dianion, C8H10N2O5), forms yellow parallelepipeds during slow evaporation of Pd(NO3)2–Na2H2EDTA solution at 25 °C, and is a result of EDTA oxidation. The second one, [Pd(μ-H2EDTA)]2 · 2NaNO3 · 7.5H2O, with two EDTA molecules acting as bridges between two palladium atoms, forms yellow bipyramides during fast evaporation at 60 °C. In both complexes, the palladium atoms adopt a planar trans-geometry by bonding to two nitrogen and two oxygen atoms of two ligand molecules.
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4.
  • Kirilin, A, et al. (författare)
  • Chemo-Bio Catalyzed Synthesis of R-1-Phenylethyl Acetate over Bimetallic PdZn Catalysts, Lipase, and Ru/Al2O3 : part II
  • 2011
  • Ingår i: Kinetics and catalysis. - : Maik Nauka/Interperiodica. - 0023-1584 .- 1608-3210. ; 52:1, s. 77-81
  • Tidskriftsartikel (refereegranskat)abstract
    • One-pot synthesis of R-1-phenyethylacetate at 70 degrees C was investigated using three different catalysts simultaneously, namely a bimetallic PdZn/Al2O3 as a hydrogenation catalyst, an immobilized lipase as an acylation catalyst and Ru/Al2O3 as a racemization catalyst. The most active bimetallic catalyst was PdZn/Al2O3 calcined at 300 degrees C and reduced at 400 degrees C, whereas the most selective although less active catalyst was the one being calcined and reduced at 500 degrees C. The highest selectivity to R-1-phenylethyl acetate over this catalyst was 32 at 48% conversion. Ru/Al2O3 was confirmed to have a positive effect on the formation of the desired product, although it was not very active in the racemization during one-pot synthesis.
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5.
  • Kirilin, A, et al. (författare)
  • Chemo-bio catalyzed synthesis of R-1-phenylethyl acetateover bimetallic PdZn catalysts, lipase and Ru/Al2o3. Part I
  • 2011
  • Ingår i: Kinetics and catalysis. - Moskva : Nauka. - 0023-1584 .- 1608-3210. ; 52:1, s. 78-82
  • Tidskriftsartikel (refereegranskat)abstract
    • The effect of calcination and reduction temperature on the physical properties of PdZn/Al2O3 catalysts, prepared by coprecipitation deposition technique and characterized by XPS, XRD and TEM methods are reported. The temperatures were varied in a range of 300–500°C. The catalyst calcined at 300°C and reducedat 400°C exhibited the metal particle size of 2–6 nm and contained the highest surface concentrations of Pd and Zn according to XPS measurements. The size and the fraction of large particles (above 10 nm) increased with increasing the calcinations and reduction temperatures.
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  • Resultat 1-5 av 5

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