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- Fan, Y., et al.
(författare)
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Mechanical preparation of nano titanium dioxide powder and its optical properties
- 2007
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Ingår i: Journal of the Chinese Ceramic Society. - 0454-5648. ; 35:7, s. 832-837
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Tidskriftsartikel (refereegranskat)abstract
- mechanical preparation of the nano-sized particles of TiO2 powder by a stirred bead mill was investigated. The particle sizes of the ground products were determined by the acoustic particle sizer, the nitrogen gas adsorption method and a scanning electron microscopy. The diameter of the nano-sized particles, which were obtained after milling for 7 h, is about 50 nm and the specific surface area is up to 70 m2/g. The surface and structure of the samples have been investigated with X-ray diffraction. It is indicated that an intense comminution in the mill leads to a progressive loss in crystallinity of TiO2. The catalytic degradation of methyl orange in water was also studied by a photometer. The results show that the nano-sized particles of TiO2 powder prepared by milling possess photocatalysis effect and are capable of absorption of ultraviolet radiation
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| 3. |
- Shi, F., et al.
(författare)
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Synthesis and properties of a new donor model compound for PSII
- 2004
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Ingår i: Gaodeng xuéxiào huàxué xuébào. - 0251-0790. ; 25:9, s. 1666-1672
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Tidskriftsartikel (refereegranskat)abstract
- As a model compound for redox components on the donor side of photosystem II (PS II) in green plants, a supramolecular complex 2 was synthesized and characterized. In this complex, two {[(2-hydroxy-3-(morpholin-4-ylmethyl)-5-tert-butyl-benzyl)(pyridyl-2-methyl)amino]methyl} arms are linked to the ortho-positions of a phenol which is expected covalently to be linked to Ru(II) tris-bipyridine through an amide bond. The arms on the substituted-phenol can coordinate two Mn(III) ions. The structure of complex 2 was confirmed by electrospray ionization mass spectrometry (ESI-MS) and 2D-NMR (gCOSY, HSQC and HMBC). Its photochemical and electrochemical properties were studied. The results showed that the MLCT band of the compound was red-shifted compared to that of [Ru(byp)(3)](2+) and the luminescence quantum yield was enhanced. In addition, the oxidation potential of ruthenium was higher than the phenol(+)/phenol and Mn(III, IV)/Mn(III) which was consisted with the electron transfer sequence of the donor side of PS II in nature. All these showed that this compound was a good model to mimic the donor side of PS II.
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