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Sökning: WFRF:(Fu M) > Mälardalens universitet

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1.
  • Farooq, U., et al. (författare)
  • Efficient transformation in characteristics of cations supported-reduced graphene oxide nanocomposites for the destruction of trichloroethane
  • 2017
  • Ingår i: Applied Catalysis A. - : Elsevier B.V.. - 0926-860X .- 1873-3875. ; 544, s. 10-20
  • Tidskriftsartikel (refereegranskat)abstract
    • Experiments were conducted to investigate the use of graphene-oxide supported metallic nanocomposites for improving the degradation of trichloroethane (TCA) by sodium percarbonate (SPC). Two methods of production, chemical reduction (CR) and solvo-thermal (ST), were tested for preparation of single (Fe) and binary (Fe-Cu) nanocomposites supported by reduced graphene oxide (rGO). A variety of analytical techniques including N2 adsorption Brunauer-Emmett-Teller (BET), x-ray diffraction (XRD), fourier-transfrom infrared spectroscopy (FTIR), and transmisison electron microscopy (TEM) were applied to characterize the physicochemical and microstructural properties of the synthesized nanocomposites. The characterization indicated that the CR method produced nanocomposites that comprised only mesoporous structure. Conversely, both micro and mesoporous structures were present for samples produced with the ST method. The synthesized single and bimetallic composites produced from the ST method showed higher surface areas, i.e. 93.6 m2/g and 119.2 m2/g as compared to the ones synthesized via the CR method, i.e. 13.8 m2/g and 38.0 m2/g respectively. The results of FTIR and XRD analyses confirmed that the ST method produced highly crystalline nanocomposites. SEM and TEM analysis validated that metallic particles with definite morphology well distributed on the surface of rGO. X-ray photoelectron spectroscopy (XPS) analysis confirmed the homogeneity nanocomposites and occurrence of variation in copper oxidation states during degradation process. EDS mapping validate the homogeneous distribution of Cu and Fe at reduced graphene oxide surface. The Fe-Cu/rGO (ST) activated SPC system effectively degraded TCA (92%) in 2.5 h at low nanocomposite dose compared to the Fe-Cu/rGO (CR) and only Fe, for which the maximum degradation efficiencies achieved were 81% and 34%. In conclusion, excellent catalytic characteristics were observed for the ST-synthesized single and bimetallic (Fe/rGO, Fe-Cu/rGO) catalysts. These catalysts were successful in improving the degradation of TCA via activated SPC. 
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2.
  • Danish, M., et al. (författare)
  • The Effect of Chelating Agents on Enhancement of 1,1,1-Trichloroethane and Trichloroethylene Degradation by Z-nZVI-Catalyzed Percarbonate Process
  • 2016
  • Ingår i: Water, Air and Soil Pollution. - : Springer Science and Business Media LLC. - 0049-6979 .- 1573-2932. ; 227:9
  • Tidskriftsartikel (refereegranskat)abstract
    • This study primarily focused on the performance of 1,1,1-trichloroethane (1,1,1-TCA) and trichloroethylene (TCE) degradation involving redox reactions in zeolite-supported nanozerovalent iron composite (Z-nZVI)-catalyzed sodium percarbonate (SPC) system in aqueous solution with five different chelating agents (CAs) including oxalic acid (OA), citric acid monohydrate (CAM), glutamic acid (GA), ethylenediaminetetraacetic acid (EDTA), and L-ascorbic acid (ASC). The experimental results showed that the addition of OA achieved almost 100 % degradation of 1,1,1-TCA and TCE. The addition of CAM and GA also significantly increased the contaminant degradation, while excessive addition of them inhibited the degradation. In contrast, EDTA and ASC showed negative impacts on 1,1,1-TCA and TCE degradation, which might be due to the strong reactivity with iron and OH● scavenging characteristics. The efficiency with CA addition on 1,1,1-TCA and TCE degradation decreased in the order of OA > CAM > GA > no CAs > EDTA > ASC. The extensive investigations using probe compound tests and scavenger tests revealed that both contaminants degraded primarily by OH● and O2 –● in chelated Z-nZVI-catalyzed SPC system. The significant improvement in 1,1,1-TCA and TCE degradation efficiency was accredited due to the (i) increase in concentration of Fe2+ and (ii) continuous generation of OH● radicals and maintenance of its quantity, ensuring more stability in the aqueous solution. Finally, the complete mineralization of 1,1,1-TCA and TCE in the OA-chelated, Z-nZVI-catalyzed SPC system was confirmed without any chlorinated intermediate by-products detected, demonstrating a great potential of this technique in the application of groundwater remediation.
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  • Resultat 1-2 av 2
Typ av publikation
tidskriftsartikel (2)
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refereegranskat (2)
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Zhang, X. (2)
Lu, S. (2)
Fu, X (2)
Danish, M. (2)
Ahmad, A. (1)
Naqvi, Muhammad (1)
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Naqvi, Muhammad, 198 ... (1)
Xue, Y. (1)
Farooq, U. (1)
Gu, X. (1)
Miao, Z. (1)
Qureshi, A. S. (1)
Qiu, Z. (1)
Sui, Q. (1)
Brusseau, M. L. (1)
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Karlstads universitet (1)
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Engelska (2)
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Naturvetenskap (1)
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