| 1. |
- Iacocca, Ezio, 1986, et al.
(author)
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Spin-current-mediated rapid magnon localisation and coalescence after ultrafast optical pumping of ferrimagnetic alloys
- 2019
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In: Nature Communications. - : Springer Science and Business Media LLC. - 2041-1723 .- 2041-1723. ; 10:1
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Journal article (peer-reviewed)abstract
- Sub-picosecond magnetisation manipulation via femtosecond optical pumping has attracted wide attention ever since its original discovery in 1996. However, the spatial evolution of the magnetisation is not yet well understood, in part due to the difficulty in experimentally probing such rapid dynamics. Here, we find evidence of a universal rapid magnetic order recovery in ferrimagnets with perpendicular magnetic anisotropy via nonlinear magnon processes. We identify magnon localisation and coalescence processes, whereby localised magnetic textures nucleate and subsequently interact and grow in accordance with a power law formalism. A hydrodynamic representation of the numerical simulations indicates that the appearance of noncollinear magnetisation via optical pumping establishes exchange-mediated spin currents with an equivalent 100% spin polarised charge current density of 10 7 A cm −2 . Such large spin currents precipitate rapid recovery of magnetic order after optical pumping. The magnon processes discussed here provide new insights for the stabilization of desired meta-stable states.
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| 2. |
- Jungfleisch, M. B., et al.
(author)
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Dynamic response of an artificial square spin ice
- 2016
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In: Physical Review B. - 2469-9969 .- 2469-9950. ; 93:10
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Journal article (peer-reviewed)abstract
- Magnetization dynamics in an artificial square spin-ice lattice made of Ni80Fe20 with magnetic field applied in the lattice plane is investigated by broadband ferromagnetic resonance spectroscopy. The experimentally observed dispersion shows a rich spectrum of modes corresponding to different magnetization states. These magnetization states are determined by exchange and dipolar interaction between individual islands, as is confirmed by a semianalytical model. In the low field regime below 400 Oe a hysteretic behavior in the mode spectrum is found. Micromagnetic simulations reveal that the origin of the observed spectra is due to the initialization of different magnetization states of individual nanomagnets. Our results indicate that it might be possible to determine the spin-ice state by resonance experiments and are a first step towards the understanding of artificial geometrically frustrated magnetic systems in the high-frequency regime.
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| 3. |
- Marganiec, J., et al.
(author)
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Coulomb and nuclear excitations of narrow resonances in 17Ne
- 2016
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In: Physics Letters, Section B: Nuclear, Elementary Particle and High-Energy Physics. - : Elsevier BV. - 0370-2693 .- 1873-2445. ; 759, s. 200-205
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Journal article (peer-reviewed)abstract
- New experimental data for dissociation of relativistic 17Ne projectiles incident on targets of lead, carbon, and polyethylene targets at GSI are presented. Special attention is paid to the excitation and decay of narrow resonant states in 17Ne. Distributions of internal energy in the O15+p+p three-body system have been determined together with angular and partial-energy correlations between the decay products in different energy regions. The analysis was done using existing experimental data on 17Ne and its mirror nucleus 17N. The isobaric multiplet mass equation is used for assignment of observed resonances and their spins and parities. A combination of data from the heavy and light targets yielded cross sections and transition probabilities for the Coulomb excitations of the narrow resonant states. The resulting transition probabilities provide information relevant for a better understanding of the 17Ne structure.
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| 4. |
- Marganiec, J., et al.
(author)
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Experimental study of the O-15(2p, gamma) Ne-17 cross section by Coulomb Dissociation for the rp process
- 2016
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In: Journal of Physics: Conference Series. - : IOP Publishing. - 1742-6588 .- 1742-6596. ; 665:1
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Conference paper (peer-reviewed)abstract
- The time-reversed reaction O-15(2p, gamma) Ne-17 has been studied by the Coulomb dissociation technique. Secondary 17Ne ion beams at 500 AMeV have been produced by fragmentation reactions of Ne-20 in a beryllium production target and dissociated on a secondary Pb target. The incoming beam and the reaction products have been identified with the kinematically complete LAND-(RB)-B-3 experimental setup at GSI. The excitation energy prior to decay has been reconstructed by using the invariant-mass method. The preliminary differential and integral Coulomb Dissociation cross sections (sigma(Coul)) have been calculated, which provide a photoabsorption (sigma(photo)) and a radiative capture cross section (sigma(cap)). Additionally, important information about the nuclear structure of the Ne-17 nucleus will be obtained. The analysis is in progress.
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| 5. |
- Marganiec, J., et al.
(author)
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Studies of continuum states in (16) Ne using three-body correlation techniques
- 2015
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In: European Physical Journal A. - : Springer Science and Business Media LLC. - 1434-601X .- 1434-6001. ; 51:1, s. 1-9
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Journal article (peer-reviewed)abstract
- Two-proton decay of the unbound nucleus Ne-16 , produced in one-neutron knockout from a 500 MeV/u Ne-17 beam, has been studied at GSI. The ground state, at a resonance energy 1.388(15) MeV, ( MeV) above the O-14 +p+p threshold, and two narrow resonances at MeV and 7.57(6) MeV have been investigated. A comparison of the energy difference between the first excited 2(+) state and the 0(+) ground state in Ne-16 with its mirror nucleus C-16 reveals a small Thomas-Ehrman shift (TES) of keV. A trend of the TES for the T = 2 quintet is obtained by completing the known data with a prediction for F-16 obtained from an IMME analysis. The decay mechanisms of the observed three resonances were revealed from an analysis of the energy and angular correlations of the O-14 +p+p decay products. The ground state decay can be considered as a genuine three-body (democratic) mode and the excited states decay sequentially via states in the intermediate nucleus F-15 , the 3.22 MeV state predominantly via the F-15 ground-state resonance, while the 7.57 MeV state decays via the 5/2(+) resonance in F-15 at 2.8 MeV above the O-14 +p+p threshold. Further, from an analysis of angular correlations, the spin-parity of the 7.57 MeV state has been determined as and assigned as the third 2(+) state in Ne-16 based on a comparison with C-16.
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| 6. |
- Dicke, B., et al.
(author)
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Transferring the entatic-state principle to copper photochemistry
- 2018
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In: Nature Chemistry. - : Springer Science and Business Media LLC. - 1755-4349 .- 1755-4330. ; 10:3, s. 355-362
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Journal article (peer-reviewed)abstract
- The entatic state denotes a distorted coordination geometry of a complex from its typical arrangement that generates an improvement to its function. The entatic-state principle has been observed to apply to copper electron-transfer proteins and it results in a lowering of the reorganization energy of the electron-transfer process. It is thus crucial for a multitude of biochemical processes, but its importance to photoactive complexes is unexplored. Here we study a copper complex-with a specifically designed constraining ligand geometry-that exhibits metal-to-ligand charge-transfer state lifetimes that are very short. The guanidine-quinoline ligand used here acts on the bis(chelated) copper(I) centre, allowing only small structural changes after photoexcitation that result in very fast structural dynamics. The data were collected using a multimethod approach that featured time-resolved ultraviolet-visible, infrared and X-ray absorption and optical emission spectroscopy. Through supporting density functional calculations, we deliver a detailed picture of the structural dynamics in the picosecond-to-nanosecond time range.
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| 7. |
- Rahm, Martin, 1982, et al.
(author)
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Atomic and Ionic Radii of Elements 1-96
- 2016
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In: Chemistry - A European Journal. - : Wiley. - 1521-3765 .- 0947-6539. ; 22, s. 14625-14632
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Journal article (peer-reviewed)abstract
- Atomic and cationic radii have been calculated for the first 96 elements, together with selected anionic radii. The metric adopted is the average distance from the nucleus where the electron density falls to 0.001 electrons per bohr3, following earlier work by Boyd. Our radii are derived using relativistic all-electron density functional theory calculations, close to the basis set limit. They offer a systematic quantitative measure of the sizes of non-interacting atoms, commonly invoked in the rationalization of chemical bonding, structure, and different properties. Remarkably, the atomic radii as defined in this way correlate well with van der Waals radii derived from crystal structures. A rationalization for trends and exceptions in those correlations is provided.
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| 8. |
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| 9. |
- Rahm, Martin, 1982, et al.
(author)
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Squeezing All Elements in the Periodic Table: Electron Configuration and Electronegativity of the Atoms under Compression
- 2019
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In: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 1520-5126 .- 0002-7863. ; 141:26, s. 10253-10271
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Journal article (peer-reviewed)abstract
- We present a quantum mechanical model capable of describing isotropic compression of single atoms in a non-reactive neon-like environment. Studies of 93 atoms predict drastic changes to ground-state electronic configurations and electronegativity in the pressure range of 0-300 GPa. This extension of atomic reference data assists in the working of chemical intuition at extreme pressure and can act as a guide to both experiments and computational efforts. For example, we can speculate on the existence of pressure-induced polarity (red-ox) inversions in various alloys. Our study confirms that the filling of energy levels in compressed atoms more closely follows the hydrogenic aufbau principle, where the ordering is determined by the principal quantum number. In contrast, the Madelung energy ordering rule is not predictive for atoms under compression. Magnetism may increase or decrease with pressure, depending on which atom is considered. However, Hund's rule is never violated for single atoms in the considered pressure range. Important (and understandable) electron shifts, s→p, s→d, s→f, and d→f are essential chemical and physical consequences of compression. Among the specific intriguing changes predicted are an increase in the range between the most and least electronegative elements with compression; a rearrangement of electronegativities of the alkali metals with pressure, with Na becoming the most electropositive s1 element (while Li becomes a p group element and K and heavier become transition metals); phase transitions in Ca, Sr, and Ba correlating well with s→d transitions; spin-reduction in all d-block atoms for which the valence d-shell occupation is dn (4 ≤ n ≤ 8); d→f transitions in Ce, Dy, and Cm causing Ce to become the most electropositive element of the f-block; f→d transitions in Ho, Dy, and Tb and a s→f transition in Pu. At high pressure Sc and Ti become the most electropositive elements, while Ne, He, and F remain the most electronegative ones.
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| 10. |
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