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Träfflista för sökning "WFRF:(Johansson Jan Erik) ;pers:(Halvarsson Mats 1965)"

Sökning: WFRF:(Johansson Jan Erik) > Halvarsson Mats 1965

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1.
  • Canovic, Sead, 1979, et al. (författare)
  • Oxidation of Co- and Ce-nanocoated FeCr steels: A microstructural investigation
  • 2013
  • Ingår i: Surface and Coatings Technology. - : Elsevier BV. - 0257-8972. ; 215, s. 62-74
  • Tidskriftsartikel (refereegranskat)abstract
    • The effect of novel Co and Ce nanocoatings on oxidation behaviour and chromium volatilization from a commercial Fe-22Cr steel (Sanergy HT) developed for solid oxide fuel cell interconnect applications is investigated. Three different coatings (10 nm Ce, 640 nm Co and 10 nm Ce + 640 nm Co) are studied. Uncoated and nanocoated samples are exposed isothermally at 850 C in the air with 3% H2O for 168 h. The detailed microstructure of the different coatings is investigated. The surface morphology and microstructure of the oxide scales are characterized by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), scanning transmission electron microscopy (STEM) and energy dispersive X-ray analysis (EDX). Cross-section TEM thin foils are prepared by using a combined FIB/SEM (focused ion beam/scanning electron microscope) instrument. A 640 nm cobalt coating strongly inhibits Cr volatilization but has only minor effects on oxidation rate. In contrast, a 10 nm Ce coating decreases the oxidation rate but has no significant effects on chromium volatilization. Combining the two coatings, i.e., applying a 640 nm Co coating on top of the 10 nm Ce, effectively reduces Cr evaporation and slows down the rate of alloy oxidation.
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3.
  • Jonsson, Torbjörn, 1970, et al. (författare)
  • The influence of KCl on the corrosion of an austenitic stainless steel (304L) in oxidizing humid conditions at 600 ºC: A microstructural study
  • 2009
  • Ingår i: Oxidation of Metals. - : Springer Science and Business Media LLC. - 1573-4889 .- 0030-770X. ; 72:3, s. 213-239
  • Tidskriftsartikel (refereegranskat)abstract
    • The effect of KCl on the corrosion behavior of the austenitic stainless steel 304L was studied at 600 A degrees C in 5% O(2) + 40% H(2)O + N(2). The breakdown of the protective oxide was investigated. This was done through a detailed microstructural characterization of the oxide scales formed after 1, 24 and 168 h. The oxidized samples were investigated by SEM/EDX, FIB and STEM/EDX. The presence of KCl(s) causes a breakdown of most of the protective scale, even though it is not in direct contact with KCl(s) particles, starting after just 1 h exposure. A fast growing porous oxide formed in direct contact with (former) KCl(s) particles and an about 2 mu m thick scale covered most of the surface. Only some regions were covered by a thin scale. K(2)CrO(4) particles were randomly distributed all over the scale after 1 h exposure. The particles are situated above the oxide scale and are not in direct contact with the subjacent metal. The thin scale contains lower Cr levels than has been observed in corresponding scales formed in the absence of KCl. The breakdown of the protective scale is suggested to be caused primarily by the formation of K(2)CrO(4), depleting the protective oxide in chromium. In addition, chromia evaporation contributes to chromia depletion and breakdown of the protective scale. Very little or no transition metal chlorides were found after breakaway oxidation. Cl is suggested to play a minor role in the initial breakdown of the protective scale. The presence of KCl particles caused local rapid oxidation, which results in an outward growing Fe and Fe-Cr rich porous oxide.
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4.
  • Canovic, Sead, 1979, et al. (författare)
  • Microstructural Investigation of the Initial Oxidation of the FeCrAlRE Alloy Kanthal AF in Dry and Wet O-2 at 600 and 800 degrees C
  • 2010
  • Ingår i: Journal of the Electrochemical Society. - : The Electrochemical Society. - 1945-7111 .- 0013-4651. ; 157:6, s. C223-C230
  • Tidskriftsartikel (refereegranskat)abstract
    • The FeCrAlRE (where RE is reactive element) alloy Kanthal AF was exposed isothermally at 600 and 800 degrees C for 72 h in dry O-2 and in O-2 with 10 vol % H2O. The mass gains were 3-5 times higher at the higher temperature. The presence of water vapor increased the oxidation rate at 800 degrees C, while no significant effect was observed at 600 degrees C. A thin two-layered oxide formed at 600 degrees C: an outer (Fe, Cr)(2)O-3 corundum-type oxide, containing some Al, and an inner, probably amorphous, Al-rich oxide. At 800 degrees C a two-layered oxide formed in both environments. The inner layer consisted of inward grown alpha-Al2O3. In dry O-2 the originally formed outward grown gamma-Al2O3 had transformed to alpha-Al2O3 after 72 h. Water vapor stabilized the outward grown gamma-Al2O3 and hence no transformation occurred after 72 h in humid environment. RE-rich oxide particles with varying composition (Y, Zr, and Ti) were distributed in the base oxide at both temperatures and in both environments. The RE-rich particles were separated from the alloy substrate by a layer of Al-rich oxide. At 800 degrees C the Y-rich RE particles were surrounded by thick oxide patches in both dry and humid O-2.
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5.
  • Engkvist, Josefin, 1972, et al. (författare)
  • Alumina scale formation on a powder metallurgical FeCrAl alloy (Kanthal APMT) at 900-1100°C in dry O2 and in O2 + H2O
  • 2010
  • Ingår i: Oxidation of Metals. - : Springer Science and Business Media LLC. - 1573-4889 .- 0030-770X. ; 73:1, s. 233-253
  • Tidskriftsartikel (refereegranskat)abstract
    • A Rapidly Solidified Powder (RSP) metallurgical FeCrAl alloy, Kanthal APMT, was exposed in dry and humid O-2 for 72 h at 900-1,100 A degrees C. The formed oxide scales were characterized using gravimetry in combination with advanced analysis techniques (SEM, EDX, TEM, XRD, AES and SIMS). The oxide scales were at all exposures composed of two-layered alpha-Al2O3 scales exhibiting a top layer of equiaxed grains and a bottom layer containing elongated grains. A Cr-rich zone, originating in the native oxide present before exposure, separated these two layers. The top alpha-Al2O3 layer is suggested to have formed by transformation of outwardly grown metastable alumina, while the inward-grown bottom alpha-Al2O3 layer had incorporated small Zr-, Hf- and Ti-rich oxide particles present in the alloy matrix. The scale also contained larger Y-rich oxide particles. Furthermore, in the temperature range studied, the presence of water vapour accelerated alloy oxidation somewhat and affected scale morphology.
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6.
  • Esmaily, Mohsen, 1987, et al. (författare)
  • A new semi-solid casting technique for fabricating SiC-reinforced Mg alloys matrix composites
  • 2016
  • Ingår i: Composites Part B: Engineering. - : Elsevier BV. - 1359-8368 .- 1879-1069. ; 94, s. 176-189
  • Tidskriftsartikel (refereegranskat)abstract
    • The capability of the newly developed rheocasting (RC) technique in combination with the RheoMetal process for producing SiC particulate-reinforced AM50 and AZ91D matrix composites (Mg-based MMCs) was investigated. The quality of the MMCs was studied by analyzing the fraction of casting pores, number density of SiC clusters and the uniformity of SiC particles. Solid fraction, particle size and oxidation of SiC particles had strong impacts on the overall quality of the MMCs. The MMCs produced by 40% solid fraction and oxidized micron-sized SiC particles exhibited an excellent casting quality. A low-quality MMC was obtained when non-oxidized sub-micron sized SiC particles were employed. The results showed the formation of various types intermetallic particles and carbides such as MgO, Mg2Si, Al2MgC2, Mg2C3, Al4C3 as the interfacial reaction products of SiC/Mg alloy's melts. Mg hydride (alpha-MgH2) was also identified in inter-dendritic regions of the MMCs for the first time.
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7.
  • Esmaily, Mohsen, 1987, et al. (författare)
  • Atmospheric Corrosion of Mg Alloy AZ91D Fabricated by aSemi-Solid Casting Technique: The Influence of Microstructure
  • 2015
  • Ingår i: Journal of the Electrochemical Society. - : The Electrochemical Society. - 0013-4651 .- 1945-7111. ; 162:7, s. C311-C321
  • Tidskriftsartikel (refereegranskat)abstract
    • The atmospheric corrosion behavior of alloy AZ91D produced by a semi-solid metal (SSM) technique and by conventional high pressure die casting (HPDC) was investigated for up to 1176 hours in the laboratory. Alloy AZ91D in the SSM state was fabricated using a rheocasting (RC) technique in which the slurry was prepared by the RheoMetal process. Exposures were performed in 95% RH air at 22 and 4 degrees C. The RC alloy AZ91D exhibited significantly better corrosion resistance than the HPDC material at two temperatures studied. The effect of casting technology on corrosion is explained in terms of the microstructural differences between the materials. For example, the larger number density of cathodic beta phase particles in the HPDC material initially causes relatively rapid corrosion compared to the RC material. During later stages of corrosion, the more network-like beta phase particles in the RC alloy act as a corrosion barrier, further improving the relative corrosion resistance of the RC material.
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8.
  • Esmaily, Mohsen, 1987, et al. (författare)
  • Bobbin and conventional friction stir welding of thick extruded AA6005-T6 profiles
  • 2016
  • Ingår i: Materials and Design. - : Elsevier BV. - 1873-4197 .- 0264-1275. ; 108, s. 114-125
  • Tidskriftsartikel (refereegranskat)abstract
    • Conventional and bobbin friction stir welding processes (FSW and BFSW, respectively) were employed for joining 10 mm thick extruded AA6005-T6 profiles. The FSW and BFSW techniques were employed using two sets of parameters resulting in slow and fast processes. In general, the bobbin tool enabled welding with faster welding speeds than the conventional FSW technique. A comprehensive in-situ thermal analysis was performed using thermocouples. It was evident that, in a like-for-like comparison, i.e., employing the same set of welding parameters, the BFSW technique introduces a somewhat higher peak temperature, however, lower heat input and, more importantly, a higher cooling rate than the conventional FSW. Accordingly, a somewhat finer microstructure was formed in the stir zone of the BFSW samples than in the FSW ones, resulting in higher hardness values, and slightly higher ultimate strengths in the BFSW samples.
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9.
  • Esmaily, Mohsen, 1987, et al. (författare)
  • Corrosion behavior of alloy AM50 in semi-solid cast and high pressure die cast states in cyclic conditions
  • 2015
  • Ingår i: Corrosion. - : Association for Materials Protection and Performance (AMPP). - 0010-9312 .- 1938-159X. ; 71:6, s. 737-748
  • Tidskriftsartikel (refereegranskat)abstract
    • The atmospheric corrosion behavior of the Mg-Al alloy AM50 produced by high pressure die casting (HPDC) and a semi-solid metal (SSM) technique was studied under alternating wet-dry conditions for up to 672 hours. The alloy AM50 in the SSC state was fabricated using rheocasting (RC) technique in which the slurry was prepared by the newly developed RheoMetal process. To simulate the real-world atmospheric environment, the exposure program included a 6 hour wet phase (including rain with 0.5 % NaCl), a 2.5 hours transition phase followed by a 15.5 hours dry phase at 50°C and 70% relative humidity (RH). The results showed that the RC alloy was substantially less prone to corrosion than the HPDC material in the cyclic wet/dry atmosphere. Based on the gravimetric results and microstructural characterization studies, this was attributed to a lower fraction of porosity and to the barrier role of β phase particles in the RC.
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10.
  • Esmaily, Mohsen, 1987, et al. (författare)
  • Corrosion behaviour of friction stir-welded AA6005-T6 using a bobbin tool
  • 2016
  • Ingår i: Corrosion Science. - : Elsevier BV. - 0010-938X. ; 111, s. 98-109
  • Tidskriftsartikel (refereegranskat)abstract
    • The atmospheric corrosion of extruded AA6005-T6 weldments produced with bobbin friction stir welding (BFSW) using fast and slow process parameters has been analyzed. The weldments of the same material fabricated using conventional FSW were also exposed as reference. Copper-rich phase particles were detected at the grain boundaries in the stir zone of both specimens. It was evident that the BFSW specimens exhibit better corrosion behaviour than the specimens produced using the slow process parameters. An effort was made to carefully attribute the improved corrosion resistance of the fast BFSW specimens to the difference in the microstructure of the weldments. (C) 2016 Elsevier Ltd. All rights reserved.
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