| 1. |
- Wickerts, Sanna, 1992, et al.
(author)
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Prospective life cycle assessment of sodium-ion batteries made from abundant elements
- 2024
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In: Journal of Industrial Ecology. - 1530-9290 .- 1088-1980. ; 28:1, s. 116-129
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Journal article (peer-reviewed)abstract
- Batteries are enablers for reducing fossil-fuel dependency and climate-change impacts. In this study, a prospective life cycle assessment (LCA) of large-scale production of two different sodium-ion battery (SIB) cells is performed with a cradle-to-gate system boundary. The SIB cells modeled have Prussian white cathodes and hard carbon anodes based only on abundant elements and thus constitute potentially preferable options to current lithium-ion battery (LIB) cells from a mineral resource scarcity point of view. The functional unit was 1 kWh theoretical electricity storage capacity, and the specific energy density of the cells was 160 Wh/kg. Data for the cathode active material come from a large-scale facility under construction and data for the SIB cell production is based on a large-scale LIB cell gigafactory. For other SIB cell materials, prospective inventory data was obtained from a generic eight-step procedure developed, which can be used by other LCA practitioners. The results show that both SIB cells indeed have considerably lower mineral resource scarcity impacts than nickel-manganese-cobalt (NMC)-type LIB cells in a cradle-to-gate perspective, while their global warming impacts are on par. Main recommendations to SIB manufacturers are to source fossil-free electricity for cell production and use hard carbon anodes based on lignin instead of phenolic resin. Additionally, since none of the assessed electrolytes had clearly lower cradle-to-gate impacts than any other, more research into SIB electrolyte materials with low environmental and resource impacts should be prioritized. An improvement of the SIB cell production model would be to obtain large-scale production data specific to SIB cells.
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| 2. |
- Wagner, Annemarie, 1954, et al.
(author)
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Carbon Dioxide Capture from Ambient Air Using Amine-Grafted Mesoporous Adsorbents
- 2013
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In: International Journal of Spectroscopy. - : Hindawi Limited. - 1687-9457 .- 1687-9449. ; 2013
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Journal article (peer-reviewed)abstract
- Anthropogenic emissions of carbon dioxide (CO2) have been identified as a major contributor to climate change. An attractive approach to tackle the increasing levels of CO2 in the atmosphere is direct extraction via absorption of CO2 from ambient air, to be subsequently desorbed and processed under controlled conditions. The feasibility of this approach depends on the sorbent material that should combine a long lifetime with nontoxicity, high selectivity for CO2, and favorable thermodynamic cycling properties. Adsorbents based on pore-expanded mesoporous silica grafted with amines have previously been found to combine high CO2 adsorption capacity at low partial pressures with operational stability under highly defined laboratory conditions. Here we examine the real potential and functionality of these materials by using more realistic conditions using both pure CO2, synthetic air, and, most importantly, ambient air. Through a combination of thermogravimetric analysis and Fourier transform infrared (TGA-FTIR) spectroscopy we address the primary functionality and by diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy the observed degradation of the material on a molecular level.
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| 3. |
- Arvidsson, Rickard, 1984, et al.
(author)
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Energy use and climate change improvements of Li/S batteries based on life cycle assessment
- 2018
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In: Journal of Power Sources. - : Elsevier BV. - 0378-7753. ; 383, s. 87-92
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Journal article (peer-reviewed)abstract
- We present a life cycle assessment (LCA) study of a lithium/sulfur (Li/S) cell regarding its energy use (in electricity equivalents, kWhel) and climate change (in kg carbon dioxide equivalents, CO2 eq) with the aim of identifying improvement potentials. Possible improvements are illustrated by departing from a base case of Li/S battery design, electricity from coal power, and heat from natural gas. In the base case, energy use is calculated at 580 kWhel kWh−1 and climate change impact at 230 kg CO2 eq kWh−1 of storage capacity. The main contribution to energy use comes from the LiTFSI electrolyte salt production and the main contribution to climate change is electricity use during the cell production stage. By (i) reducing cell production electricity requirement, (ii) sourcing electricity and heat from renewable sources, (iii) improving the specific energy of the Li/S cell, and (iv) switching to carbon black for the cathode, energy use and climate change impact can be reduced by 54 and 93%, respectively. For climate change, our best-case result of 17 kg CO2 eq kWh−1 is of similar magnitude as the best-case literature results for lithium-ion batteries (LIBs). The lithium metal requirement of Li/S batteries and LIBs are also of similar magnitude.
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| 4. |
- Wickerts, Sanna, 1992, et al.
(author)
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How environmentally friendly are batteries with no rare or critical materials?
- 2022
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Conference paper (other academic/artistic)abstract
- Rechargeable batteries are increasingly used in a number of applications, such as consumer electronics, electric vehicles, and stationary energy storage. An increased use in the latter two applications is envisioned to reduce greenhouse gas emissions.However, the dominant rechargeable battery technology – the lithium-ion battery (LIB) – impacts the environment in several ways throughout its life cycle. In addition, LIBs require critical and/or geochemically scarce materials, such as lithium, natural graphite, and sometimes nickel and cobalt. One promising next generation battery (NGB) is the sodium-ion battery (SIB). While other NGBs can provide higher energy densities, the SIB technology holds great promise from a resource point of view, since it can be made to contain mostly low-cost, abundant and readily available elements, such as sodium and iron. In addition, the manufacturing processes and equipment developed for LIBs can in principle be re-used, enabling convenient scale-up of production. We here assess the life-cycle impacts of a specific SIB with a low content of scarce metals using prospective life cycle assessment (LCA). The SIB is assumed to be a mature technology produced at large scale and this we accomplish by using data from a small-scale producer and scale these up using available large-scale factory data for LIB production. We use a functional unit of 1 kWh of installed battery cell storage capacity and focus on climate and mineral resource impacts, since those have been highlighted in several publications and guidance documents as particularly important to address in LCAs of batteries. Different shares of renewables are considered in energy supply scenarios, along with scenarios for specific energy density developments. The impacts are compared to those of large-scale produced LIBs and to another NGB – the lithium-sulfur battery. To investigate mineral resource impacts of the different technologies in depth, we include two resource impact assessment methods, the crustal scarcity indicator and the surplus ore potential. The aims of the study are (i) to assess the prospective life cycle impacts of the SIB technology in order to reveal whether it is preferable to other battery technologies from an environmental and resource point of view, and (ii) to understand the environmental profile of the SIB in order to identify hotspots.
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| 5. |
- Wickerts, Sanna, 1992, et al.
(author)
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Prospective Life Cycle Assessment of Lithium-Sulfur Batteries for Stationary Energy Storage
- 2023
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In: ACS Sustainable Chemistry & Engineering. - 2168-0485. ; 11:26, s. 9553-9563
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Journal article (peer-reviewed)abstract
- The lithium-sulfur (Li-S) battery represents a promisingnext-generationbattery technology because it can reach high energy densities withoutcontaining any rare metals besides lithium. These aspects could giveLi-S batteries a vantage point from an environmental and resourceperspective as compared to lithium-ion batteries (LIBs). Whereas LIBsare currently produced at a large scale, Li-S batteries are not. Therefore,prospective life cycle assessment (LCA) was used to assess the environmentaland resource scarcity impacts of Li-S batteries produced at a largescale for both a cradle-to-gate and a cradle-to-grave scope. Six scenarioswere constructed to account for potential developments, with the overallaim of identifying parameters that reduce (future) environmental andresource impacts. The specific energy density and the type of electrolytesalt are the two most important parameters for reducing cradle-to-gateimpacts, whereas for the cradle-to-grave scope, the electricity source,the cycle life, and, again, the specific energy density, are the mostimportant. Additionally, we find that hydrometallurgical recyclingof Li-S batteries could be beneficial for lowering mineral resourceimpacts but not necessarily for lowering other environmental impacts. Life cycle assessment of lithium-sulfurbatteries indicatesa similar environmental impact but a potentially lower mineral resourceimpact compared to lithium-ion batteries.
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| 6. |
- Sun, Bing, et al.
(author)
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Ion transport in polycarbonate based solid polymer electrolytes : experimental and computational investigations
- 2016
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In: Physical Chemistry, Chemical Physics - PCCP. - : Royal Society of Chemistry (RSC). - 1463-9076 .- 1463-9084. ; 18:14, s. 9504-9513
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Journal article (peer-reviewed)abstract
- Among the alternative host materials for solid polymer electrolytes (SPEs), polycarbonates have recently shown promising functionality in all-solid-state lithium batteries from ambient to elevated temperatures. While the computational and experimental investigations of ion conduction in conventional polyethers have been extensive, the ion transport in polycarbonates has been much less studied. The present work investigates the ionic transport behavior in SPEs based on poly(trimethylene carbonate) (PTMC) and its co-polymer with epsilon-caprolactone (CL) via both experimental and computational approaches. FTIR spectra indicated a preferential local coordination between Li+ and ester carbonyl oxygen atoms in the P(TMC20CL80) co-polymer SPE. Diffusion NMR revealed that the co-polymer SPE also displays higher ion mobilities than PTMC. For both systems, locally oriented polymer domains, a few hundred nanometers in size and with limited connections between them, were inferred from the NMR spin relaxation and diffusion data. Potentiostatic polarization experiments revealed notably higher cationic transference numbers in the polycarbonate based SPEs as compared to conventional polyether based SPEs. In addition, MD simulations provided atomic-scale insight into the structure-dynamics properties, including confirmation of a preferential Li+-carbonyl oxygen atom coordination, with a preference in coordination to the ester based monomers. A coupling of the Li-ion dynamics to the polymer chain dynamics was indicated by both simulations and experiments.
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| 7. |
- Oltean, Gabriel, et al.
(author)
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Towards Li-ion batteries operating at 80 °C: Ionic liquid versus conventional liquid electrolytes
- 2018
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In: Batteries. - : MDPI AG. - 2313-0105. ; 4, s. 2-6
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Journal article (peer-reviewed)abstract
- Li-ion battery (LIB) full cells comprised of TiO2-nanotube (TiO2-nt) and LiFePO4 (LFP)electrodes and either a conventional organic solvent based liquid electrolyte or an ionic liquid basedelectrolyte have been cycled at 80 °C. While the cell containing the ionic liquid based electrolyteexhibited good capacity retention and rate capability during 100 cycles, rapid capacity fading was found for the corresponding cell with the organic electrolyte. Results obtained for TiO2-nt and LFP half-cells indicate an oxidative degradation of the organic electrolyte at 80 °C. In all, ionic liquidbased electrolytes can be used to significantly improve the performance of LIBs operating at 80 °C.
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| 8. |
- Franco, Alejandro A., et al.
(author)
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Boosting Rechargeable Batteries R&D by Multiscale Modeling: Myth or Reality?
- 2019
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In: Chemical Reviews. - : American Chemical Society (ACS). - 0009-2665 .- 1520-6890. ; 119:7, s. 4569-4627
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Journal article (peer-reviewed)abstract
- This review addresses concepts, approaches, tools, and outcomes of multiscale modeling used to design and optimize the current and next generation rechargeable battery cells. Different kinds of multiscale models are discussed and demystified with a particular emphasis on methodological aspects. The outcome is compared both to results of other modeling strategies as well as to the vast pool of experimental data available. Finally, the main challenges remaining and future developments are discussed.
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| 9. |
- Lindberg, Simon, 1987, et al.
(author)
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Charge storage mechanism of α-MnO2 in protic and aprotic ionic liquid electrolytes
- 2020
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In: Journal of Power Sources. - : Elsevier BV. - 0378-7753 .- 1873-2755. ; 460
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Journal article (peer-reviewed)abstract
- In this work we have investigated the charge storage mechanism of MnO2 electrodes in ionic liquid electrolytes. We show that by using an ionic liquid with a cation that has the ability to form hydrogen bonds with the active material (MnO2) on the surface of the electrode, a clear faradaic contribution is obtained. This situation is found for ionic liquids with cations that have a low pKa, i.e. protic ionic liquids. For a protic ionic liquid, the specific capacity at low scan rate rates can be explained by a densely packed layer of cations that are in a standing geometry, with a proton directly interacting through a hydrogen bond with the surface of the active material in the electrode. In contrast, for aprotic ionic liquids there is no interaction and only a double layer contribution to the charge storage is observed. However, by adding an alkali salt to the aprotic ionic liquid, a faradaic contribution is obtained from the insertion of Li+ into the surface of the MnO2 electrode. No effect can be observed when Li+ is added to the protic IL, suggesting that a densely packed cation layer in this case prevent Li-ions from reaching the active material surface.
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| 10. |
- Lindahl, Niklas, 1981, et al.
(author)
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Aluminum Metal-Organic Batteries with Integrated 3D Thin Film Anodes
- 2020
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In: Advanced Functional Materials. - : Wiley. - 1616-301X .- 1616-3028. ; 30:51
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Journal article (peer-reviewed)abstract
- Aluminum 3D thin film anodes fully integrated with a separator are fabricated by sputtering and enable rechargeable aluminum metal batteries with high power performance. The 3D thin film anodes have an approximately four to eight times larger active surface area than a metal foil, which significantly both reduces the electrochemical overpotential, and improves materials utilization. In full cells with organic cathodes, that is, aluminum metal-organic batteries, the 3D thin film anodes provide 165 mAh g(-1)at 0.5 C rate, with a capacity retention of 81% at 20 C, and 86% after 500 cycles. Post-mortem analysis reveals structural degradation to limit the long-term stability at high rates. As the multivalent charge carrier active here is AlCl2+, the realistic maximal specific energy, and power densities at cell level are approximate to 100 Wh kg(-1)and approximate to 3100 W kg(-1), respectively, which is significantly higher than the state-of-the-art for Al batteries.
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