| 1. |
- Arvidsson, Rickard, 1984, et al.
(författare)
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Energy use and climate change improvements of Li/S batteries based on life cycle assessment
- 2018
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Ingår i: Journal of Power Sources. - : Elsevier BV. - 0378-7753. ; 383, s. 87-92
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Tidskriftsartikel (refereegranskat)abstract
- We present a life cycle assessment (LCA) study of a lithium/sulfur (Li/S) cell regarding its energy use (in electricity equivalents, kWhel) and climate change (in kg carbon dioxide equivalents, CO2 eq) with the aim of identifying improvement potentials. Possible improvements are illustrated by departing from a base case of Li/S battery design, electricity from coal power, and heat from natural gas. In the base case, energy use is calculated at 580 kWhel kWh−1 and climate change impact at 230 kg CO2 eq kWh−1 of storage capacity. The main contribution to energy use comes from the LiTFSI electrolyte salt production and the main contribution to climate change is electricity use during the cell production stage. By (i) reducing cell production electricity requirement, (ii) sourcing electricity and heat from renewable sources, (iii) improving the specific energy of the Li/S cell, and (iv) switching to carbon black for the cathode, energy use and climate change impact can be reduced by 54 and 93%, respectively. For climate change, our best-case result of 17 kg CO2 eq kWh−1 is of similar magnitude as the best-case literature results for lithium-ion batteries (LIBs). The lithium metal requirement of Li/S batteries and LIBs are also of similar magnitude.
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| 2. |
- Arvidsson, Rickard, 1984, et al.
(författare)
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Potential improvements of the life cycle environmental impacts of a Li/S battery cell
- 2018
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- The lithium sulfur (Li/S) battery is a promising battery chemistry for two reasons: it requires no scarce metals apart from the lithium itself and it brings the promise of high specific energy density at the cell level. However, the environmental impacts of this battery type remain largely unstudied. In this study, we conducted a life cycle assessment (LCA) of the production of an Li/S cell to calculate these impacts. The anode consists of a lithium foil and the cathode consists of a carbon/sulfur composite. The electrolyte is a mixture of dioxalane, dimethoxyethane, lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) and lithium nitrate. The current collector for the cathode is an aluminium foil and a tri-layer membrane of polypropylene and polyethylene acts as separator. The functional unit of the study is 1 kWh specific energy storage. Three key environmental impacts were considered: energy use, climate change and lithium requirement. In our baseline scenario, we consider the pilot-scale production of a battery with a specific energy of 300 kWh/kg, having the mesoporous material CMK-3 as carbon material in the carbon/sulfur cathode, and using coal power and natural gas heat as energy sources. This scenario results in an energy use of 580 kWh/kWhstored and a climate change impact of 230 kg CO2eq/kWhstored. The main contributor to energy use is the LiTFSI production and the main contributor to climate change is electricity use during cell production. We then model a number of possible improvements sequentially: (1) reduction of cell production electricity requirement due to production at industrial-scale, (2) sourcing of electricity and heat from renewable instead of fossil sources (i.e. solar power and biogas heat), (3) improvement of the specific energy of the Li/S cell to 500 kWh/kg and (4) a shift of the carbon material in the cathode to carbon black (without considering changes in performance). By implementing all these four improvements, energy use and climate change impact can be reduced by an impressive 54 and 93%, respectively. In particular, the improvements related to industrial-scale production and sourcing of renewable energy are considerable, whereas the shift of carbon material is of minor importance. For climate change, the best-case result of 17 kg CO2eq/kWhstored is similar to the best-case results reported in the scientific literature for lithium-ion batteries (LIBs). Regarding lithium requirement, the lithium metal requirement of Li/S batteries and LIBs are also of similar magnitude (0.33-0.55 kg/kWhstored and 0.2 kg/kWhstored, respectively). Using different allocation approaches did not alter the main conclusions of the study.
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| 3. |
- Wagner, Annemarie, 1954, et al.
(författare)
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Carbon Dioxide Capture from Ambient Air Using Amine-Grafted Mesoporous Adsorbents
- 2013
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Ingår i: International Journal of Spectroscopy. - : Hindawi Limited. - 1687-9457 .- 1687-9449. ; 2013
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Tidskriftsartikel (refereegranskat)abstract
- Anthropogenic emissions of carbon dioxide (CO2) have been identified as a major contributor to climate change. An attractive approach to tackle the increasing levels of CO2 in the atmosphere is direct extraction via absorption of CO2 from ambient air, to be subsequently desorbed and processed under controlled conditions. The feasibility of this approach depends on the sorbent material that should combine a long lifetime with nontoxicity, high selectivity for CO2, and favorable thermodynamic cycling properties. Adsorbents based on pore-expanded mesoporous silica grafted with amines have previously been found to combine high CO2 adsorption capacity at low partial pressures with operational stability under highly defined laboratory conditions. Here we examine the real potential and functionality of these materials by using more realistic conditions using both pure CO2, synthetic air, and, most importantly, ambient air. Through a combination of thermogravimetric analysis and Fourier transform infrared (TGA-FTIR) spectroscopy we address the primary functionality and by diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy the observed degradation of the material on a molecular level.
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| 4. |
- Wickerts, Sanna, 1992, et al.
(författare)
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Energy storage with less metal scarcity? Prospective life cycle assessment of lithium-sulfur batteries with a focus on mineral resources.
- 2021
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- In order to reduce the global dependency on fossil fuels by adopting renewable energy technologies and advancing electromobility, batteries are a key technology. Lithium-ion batteries (LIBs) are currently the dominant rechargeable battery technology, mainly due to their high energy density. However, most LIBs contain a number of geochemically scarce metals, e.g.cobalt, lithium and nickel. The production of LIBs is furthermore associated with considerable environmental impacts. Battery researchers and companies therefore try to develop the next generation batteries (NGBs) with the same or even higher energy densities than LIBs, while requiring less of scarce metals and causing lower environmental impacts. One promising NGB technology is the lithium-sulfur (Li-S) battery, with a potential to significantly improve energy density as compared to current state-of-the-art LIBs. Although Li-S batteries still face a number of scientific and technical challenges, they have a significant advantage over LIBs from a resource point of view: the cells do not require any scarce metals besides lithium. Using prospective life cycle assessment, we will assess the life-cycle environmental impacts of Li-S batteries and compare them to those of LIBs, both modeled at large-scale production. In order to investigate the effect of using less scarce metals on resource impacts, the mineral resource impact category will be given extra attention. We will therefore include a range of mineral resource impact assessment methods, e.g. the abiotic depletion indicator, the surplus ore indicator, and the recently developed crustal scarcity indicator, which takes an explicit long-term perspective on elemental resources in the Earth’s crust. The overall aim is thus to compare the prospective life-cycle impacts of this particular NGB to those of LIBs, with a focus on mineral resources.
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| 5. |
- Wickerts, Sanna, 1992, et al.
(författare)
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How environmentally friendly are batteries with no rare or critical materials?
- 2022
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- Rechargeable batteries are increasingly used in a number of applications, such as consumer electronics, electric vehicles, and stationary energy storage. An increased use in the latter two applications is envisioned to reduce greenhouse gas emissions.However, the dominant rechargeable battery technology – the lithium-ion battery (LIB) – impacts the environment in several ways throughout its life cycle. In addition, LIBs require critical and/or geochemically scarce materials, such as lithium, natural graphite, and sometimes nickel and cobalt. One promising next generation battery (NGB) is the sodium-ion battery (SIB). While other NGBs can provide higher energy densities, the SIB technology holds great promise from a resource point of view, since it can be made to contain mostly low-cost, abundant and readily available elements, such as sodium and iron. In addition, the manufacturing processes and equipment developed for LIBs can in principle be re-used, enabling convenient scale-up of production. We here assess the life-cycle impacts of a specific SIB with a low content of scarce metals using prospective life cycle assessment (LCA). The SIB is assumed to be a mature technology produced at large scale and this we accomplish by using data from a small-scale producer and scale these up using available large-scale factory data for LIB production. We use a functional unit of 1 kWh of installed battery cell storage capacity and focus on climate and mineral resource impacts, since those have been highlighted in several publications and guidance documents as particularly important to address in LCAs of batteries. Different shares of renewables are considered in energy supply scenarios, along with scenarios for specific energy density developments. The impacts are compared to those of large-scale produced LIBs and to another NGB – the lithium-sulfur battery. To investigate mineral resource impacts of the different technologies in depth, we include two resource impact assessment methods, the crustal scarcity indicator and the surplus ore potential. The aims of the study are (i) to assess the prospective life cycle impacts of the SIB technology in order to reveal whether it is preferable to other battery technologies from an environmental and resource point of view, and (ii) to understand the environmental profile of the SIB in order to identify hotspots.
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| 6. |
- Wickerts, Sanna, 1992, et al.
(författare)
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Prospective Life Cycle Assessment of Lithium-Sulfur Batteries for Stationary Energy Storage
- 2023
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Ingår i: ACS Sustainable Chemistry & Engineering. - 2168-0485. ; 11:26, s. 9553-9563
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Tidskriftsartikel (refereegranskat)abstract
- The lithium-sulfur (Li-S) battery represents a promisingnext-generationbattery technology because it can reach high energy densities withoutcontaining any rare metals besides lithium. These aspects could giveLi-S batteries a vantage point from an environmental and resourceperspective as compared to lithium-ion batteries (LIBs). Whereas LIBsare currently produced at a large scale, Li-S batteries are not. Therefore,prospective life cycle assessment (LCA) was used to assess the environmentaland resource scarcity impacts of Li-S batteries produced at a largescale for both a cradle-to-gate and a cradle-to-grave scope. Six scenarioswere constructed to account for potential developments, with the overallaim of identifying parameters that reduce (future) environmental andresource impacts. The specific energy density and the type of electrolytesalt are the two most important parameters for reducing cradle-to-gateimpacts, whereas for the cradle-to-grave scope, the electricity source,the cycle life, and, again, the specific energy density, are the mostimportant. Additionally, we find that hydrometallurgical recyclingof Li-S batteries could be beneficial for lowering mineral resourceimpacts but not necessarily for lowering other environmental impacts. Life cycle assessment of lithium-sulfurbatteries indicatesa similar environmental impact but a potentially lower mineral resourceimpact compared to lithium-ion batteries.
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| 7. |
- Wickerts, Sanna, 1992, et al.
(författare)
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Prospective life cycle assessment of sodium-ion batteries made from abundant elements
- 2024
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Ingår i: Journal of Industrial Ecology. - 1530-9290 .- 1088-1980. ; 28:1, s. 116-129
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Tidskriftsartikel (refereegranskat)abstract
- Batteries are enablers for reducing fossil-fuel dependency and climate-change impacts. In this study, a prospective life cycle assessment (LCA) of large-scale production of two different sodium-ion battery (SIB) cells is performed with a cradle-to-gate system boundary. The SIB cells modeled have Prussian white cathodes and hard carbon anodes based only on abundant elements and thus constitute potentially preferable options to current lithium-ion battery (LIB) cells from a mineral resource scarcity point of view. The functional unit was 1 kWh theoretical electricity storage capacity, and the specific energy density of the cells was 160 Wh/kg. Data for the cathode active material come from a large-scale facility under construction and data for the SIB cell production is based on a large-scale LIB cell gigafactory. For other SIB cell materials, prospective inventory data was obtained from a generic eight-step procedure developed, which can be used by other LCA practitioners. The results show that both SIB cells indeed have considerably lower mineral resource scarcity impacts than nickel-manganese-cobalt (NMC)-type LIB cells in a cradle-to-gate perspective, while their global warming impacts are on par. Main recommendations to SIB manufacturers are to source fossil-free electricity for cell production and use hard carbon anodes based on lignin instead of phenolic resin. Additionally, since none of the assessed electrolytes had clearly lower cradle-to-gate impacts than any other, more research into SIB electrolyte materials with low environmental and resource impacts should be prioritized. An improvement of the SIB cell production model would be to obtain large-scale production data specific to SIB cells.
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| 8. |
- Adebahr, Josefina, 1973, et al.
(författare)
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Ab initio calculations, Raman and NMR investigation of the plastic crystal di-methyl pyrrolidinium iodide
- 2003
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Ingår i: Electrochimica Acta. - 0013-4686. ; 48:14-16, s. 2283-2289
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Tidskriftsartikel (refereegranskat)abstract
- Above 110 °C the symmetric di-methyl-pyrrolidinium iodide salt forms a plastic crystal phase of interest in the area of new electrolyte materials. In this study ab initio calculations of this material has been conducted in order to assign the vibrational spectra. Raman spectroscopy measurements on the solid salt as well as on the salt dissolved in different solvents has been performed and these have been compared to the theoretical spectra. Furthermore, Raman spectra as a function of temperature have been recorded to investigate possible changes in inter-ionic interaction and/or structure through the phase transition. 1 H NMR linewidth measurements as a function of temperature showed a large decrease in linewidth above 100 °C, attributed here to an increase in mobility in agreement with a previously reported phase transition at ∼ 110 °C. © 2003 Elsevier Science Ltd. All rights reserved.
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| 9. |
- Ahmed, Mukhtiar, et al.
(författare)
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Aromatic Heterocyclic Anion Based Ionic Liquids and Electrolytes
- 2023
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Ingår i: Physical Chemistry, Chemical Physics - PCCP. - : Royal Society of Chemistry. - 1463-9076 .- 1463-9084. ; 25:4, s. 3502-3512
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Tidskriftsartikel (refereegranskat)abstract
- Five new ionic materials comprising fluorine-free aromatic heterocyclic anions based on pyridine and pyrazine combined with a common n-tetrabutylphosphonium cation, (P4444)+, result in two room temperature ionic liquids (RTILs), one semi-solid, and two organic ionic plastic crystals (OIPCs) with melting points >20 °C. The OIPCs showed a plastic crystalline phase, multiple solid–solid transitions, and plastic crystalline and melt phases. For both the neat RTILs and the Li+ conducting electrolytes, the nature and strength of the ion–ion interactions mainly depend on the position of the nitrogen atom with respect to the carboxylate group in the anions. Furthermore, for the RTILs the ionic conductivity is effected by the electronic structure and flexibility of the ions and the anions diffuse faster than the (P4444)+ cation, but are slowed down in the electrolytes due to the strong electrostatic interactions between the carboxylate group of the anions and the Li+, as shown both experimentally and computationally. Overall, this study describes the effect of structural tuning of aromatic anions on the ion–ion interactions and introduces new ionic materials with promising properties to be used as solid and liquid electrolytes in energy storage devices.
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| 10. |
- Ahmed, Mukhtiar, et al.
(författare)
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Ionic Liquids and Electrolytes with Flexible Aromatic Anions
- 2023
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Ingår i: Chemistry - A European Journal. - : John Wiley & Sons. - 0947-6539 .- 1521-3765. ; 29:41
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Tidskriftsartikel (refereegranskat)abstract
- Five new n-tetrabutylphosphonium (P4444)+ cation based ionic liquids (ILs) with oligoether substituted aromatic carboxylate anions have been synthesized. The nature and position of the oligoether chain affect thermal stability (up to 330 ºC), phase behaviour (Tg < -55 ºC) and ion transport. Furthermore, with the aim of application in lithium batteries, electrolytes were created for two of the ILs by 10 mol% doping using the corresponding Li-salts. This affects the ion diffusion negatively, from being higher and equal for cations and anions to lower for all ions and unequal. This is due to the stronger ionic interactions and formation of aggregates, primarily between the Li+ ions and the carboxylate group of the anions. Electrochemically, the electrolytes have electrochemical stability windows up to 3.5 V, giving some promise for battery application.
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