| 1. |
-
- 2019
-
Tidskriftsartikel (refereegranskat)
|
|
| 2. |
- Buffolo, M., et al.
(författare)
-
Modeling of the Optical and Electrical Degradation of 845 nm VCSILs
- 2023
-
Ingår i: 2023 Conference on Lasers and Electro-Optics, CLEO 2023.
-
Konferensbidrag (refereegranskat)abstract
- Optical and electrical degradation of novel micro-transfer-printed VCSILs is investigated. Modeling of experimental data suggests that the main degradation mechanism is represented by the relocation of impurities, originating from the p-side, toward the active region.
|
|
| 3. |
- Dissanayake, M. A. K. L., et al.
(författare)
-
High-efficiency dye-sensitized solar cells fabricated with electrospun PVdF-HFP polymer nanofibre-based gel electrolytes
- 2023
-
Ingår i: Bulletin of Materials Science. - 0973-7669 .- 0250-4707. ; 46:2
-
Tidskriftsartikel (refereegranskat)abstract
- Poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) electrospun polymer nanofibre-based quasi-solid or gel electrolytes were successfully fabricated by incorporating a liquid electrolyte within the nanofibre membrane. The dye-sensitized solar cells (DSSCs) fabricated with gel and with liquid electrolyte were characterized by photocurrent–voltage measurements and electrochemical impedance spectroscopy measurements. The maximum efficiency (η) of 6.79% was observed for the DSSC fabricated with optimized nanofibre membrane thickness, corresponding to 4 min of electrospinning time. The optimized PVdF-HFP nanofibre gel electrolyte shows an ionic conductivity of 7.16 × 10−3 S cm–1 at 25°C, while the corresponding liquid electrolyte exhibits an ionic conductivity of 11.69 × 10–3 S cm–1 at the same temperature. The open circuit voltage (Voc), short circuit current density (Jsc) and fill factor were recorded as 801.40 mV, 12.70 mA cm–2, and 66.67%, respectively, at an incident light intensity of 100 mW cm–2 with a 1.5 AM filter. The nanofibre gel electrolyte-based cell showed an efficiency of 6.79%, whereas the efficiency of the conventional liquid electrolyte-based cell was 7.28% under the same conditions. Furthermore, nanofibre gel electrolyte-based cells exhibited better stability, maintaining 85.40% of initial efficiency after 120 h. These results show that the optimized, polymer nanofibre-based gel electrolyte can be used successfully to replace the liquid electrolyte in DSSCs without much loss of efficiency but improving the stability while minimizing most of the drawbacks associated with liquid electrolytes.
|
|
| 4. |
- Zenari, M., et al.
(författare)
-
Analysis of defect-related optical degradation of VCSILs for photonic integrated circuits
- 2023
-
Ingår i: Proceedings of SPIE - The International Society for Optical Engineering. - : SPIE. - 0277-786X .- 1996-756X. ; 12439
-
Konferensbidrag (refereegranskat)abstract
- Laser diodes are of paramount importance for on-chip telecommunications applications, and a wide range of sensing devices that require near-infrared sources. In this work, the devices under test are vertical-cavity silicon-integrated lasers (VCSILs) designed for operation at 845 nm in photonic integrated circuits (PICs). We focus on the analysis of the degradation of the optical performance during aging. To investigate the reliability of the devices, we carried out several stress tests at constant current, ranging from 3.5 mA to 4.5 mA representing a highly accelerated stress condition. We observed two different degradation modes. In the first part of the experiments, the samples exhibited a worsening of the threshold current, but the sub-threshold emission was unaffected by degradation. We associated this behavior to the diffusion of impurities that, from the p-contact, were crossing the upper mirror implying a worsening of the DBR optical absorption. In the second stage of the stress test, the devices showed a higher degradation rate of the threshold current, whose variation was found to be linearly correlated to the worsening of the sub-threshold emission. We related this second degradation mode to the migration of the same impurities degrading the top DBR that, when reaching the active region of the laser, induced an increase in the non-radiative recombination rate. In addition to that, we related the two degradation modes to the change in series resistance, which was ascribed to the resistivity increment of the top DBR first and of oxide aperture afterwards.
|
|
| 5. |
- Zenari, M., et al.
(författare)
-
Understanding the optical degradation of 845nm micro-transfer-printed VCSILs for photonic integrated circuits
- 2023
-
Ingår i: IEEE Journal of Quantum Electronics. - 0018-9197 .- 1558-1713. ; 59:4
-
Tidskriftsartikel (refereegranskat)abstract
- For the first time we investigate the optical degradation of vertical-cavity silicon-integrated lasers (VCSILs) designed for operation at 845 nm in photonic integrated circuits (PICs). The study is based on the combined electro-optical characterization of VCSIL, submitted to constant-current stress tests at different current levels. The original results obtained within the manuscript indicate that degradation is related to the diffusion of impurities. Remarkably, depending on the region through which these impurities are migrating, the diffusion process affects device characteristics in different ways. During Phase 1 (Ph1), compensating impurities originating from the metal-semiconductor contact cross the top DBR, thus degrading mirror reflectivity, which is rarely observed in the literature, and leading to an increase in the threshold current of the device. As the impurities start reaching the active region we observe the onset of Phase 2 (Ph2), during which both threshold current and sub-threshold slope worsen, due to the increase of the Shockley-Read-Hall recombination rate. This phase is also characterized by a measurable increase in series resistance, which is ascribed to a change in the resistance of the oxide aperture. The identification of the root cause of physical degradation represents a fundamental step for future lifetime improvement of these novel optical sources, which are set to replace conventional solid-state sources in the 0.85 μm communication window.
|
|
| 6. |
- Dissanayake, M. A. K. L., et al.
(författare)
-
A novel multilayered photoelectrode with nitrogen doped TiO2 for efficiency enhancement in dye sensitized solar cells
- 2017
-
Ingår i: Journal of Photochemistry and Photobiology A: Chemistry. - : Elsevier BV. - 1010-6030. ; 349, s. 63-72
-
Tidskriftsartikel (refereegranskat)abstract
- Nitrogen doped TiO2 powder samples were synthesized by a modified wet chemical method using aqueous ammonia and nitrogen gas purged on titanium tetra isopropoxide (TTIP). Photolectrodes with different combinations of layers of nitrogen − doped TiO2, undoped TiO2 and Degussa P25 TiO2 powders were used in dye sensitized solar cells (DSSCs). The highest conversion efficiency of 8.00% was achieved by the cells fabricated with compact layer/P25/N-doped TiO2 multilayer photoelectrode. This is an impressive enhancement in efficiency close to 89% with respect to a similar multilayer electrode made with undoped TiO2 which showed a conversion efficiency of 4.22%. The enhancement in the efficiency appears to be due to the increased photocurrent density of the DSSCs resulting mainly from energy band gap narrowing due to N-doping with some contribution from increased dye uptake by the novel multilayer electrode. These results have been substantiated by the reduced charge transfer resistance obtained from Electrochemical Impedance Spectra and the enhanced IPCE spectra of the DSSCs with N-doped TiO2 based multilayer electrode. © 2017 Elsevier B.V.
|
|
| 7. |
- Dissanayake, M. A. K. L., et al.
(författare)
-
Highly efficient, PbS:Hg quantum dot-sensitized, plasmonic solar cells with TiO2 triple-layer photoanode
- 2019
-
Ingår i: Journal of Solid State Electrochemistry. - : Springer Science and Business Media LLC. - 1433-0768 .- 1432-8488. ; 23:6, s. 1787-1794
-
Tidskriftsartikel (refereegranskat)abstract
- Highly efficient, PbS:Hg quantum dot-sensitized, plasmonic solar cells with TiO2 triple-layer photoanode were fabricated by successive ionic layer adsorption and reaction (SILAR) method. These nanostructured photoanodes were characterized by optical and morphological techniques and the solar cells were characterized by optical and electrical techniques. The light absorption by the photoanode was enhanced by effective light scattering process using a triple-layer TiO2 nanostructure, fabricated with a TiO2 nanofiber layer sandwiched between two TiO2 nanoparticle layers. The best plasmon-enhanced quantum dot-sensitized solar cell showed an efficiency of 5.41% with short circuit current density of 18.02mAcm(-2) and open-circuit voltage of 679.83mV. The overall efficiency and photocurrent density of the Q-dot-sensitized solar cell are enhanced by 15.84% and 38.83% respectively due to the plasmonic effect. The enhanced efficiency appears to be due to the improved short circuit current density by increased light absorption by the triple-layered photoanode nanostructure as well as by the localized surface plasmon resonance (LSPR) effect of the plasmonic gold nanoparticles. This is the first report on plasmon-enhanced, triple-layered TiO2 photoanode sensitized with PbS:Hg Q-dots.
|
|
| 8. |
- Liu, Jian, 1985, et al.
(författare)
-
Electrically Programmed Doping Gradients Optimize the Thermoelectric Power Factor of a Conjugated Polymer
- 2024
-
Ingår i: Advanced Functional Materials. - 1616-3028 .- 1616-301X. ; In Press
-
Tidskriftsartikel (refereegranskat)abstract
- Functionally graded materials (FGMs) are widely explored in the context of inorganic thermoelectrics, but not yet in organic thermoelectrics. Here, the impact of doping gradients on the thermoelectric properties of a chemically doped conjugated polymer is studied. The in-plane drift of counterions in moderate electric fields is used to create lateral doping gradients in films composed of a polythiophene with oligoether side chains, doped with 2,3,5,6-tetrafluoro-tetracyanoquinodimethane (F4TCNQ). Raman microscopy reveals that a bias voltage of as little as 5 V across a 50 µm wide channel is sufficient to trigger counterion drift, resulting in doping gradients. The effective electrical conductivity of the graded channel decreases with bias voltage, while an overall increase in Seebeck coefficient is observed, yielding an up to eight-fold enhancement in power factor. Kinetic Monte Carlo simulations of graded films explain the increase in power factor in terms of a roll-off of the Seebeck coefficient at high electrical conductivities in combination with a mobility decay due to increased Coulomb scattering at high dopant concentrations. Therefore, the FGM concept is found to be a way to improve the thermoelectric performance of not yet optimally doped organic semiconductors, which may ease the screening of new materials as well as the fabrication of devices.
|
|
