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- Chen, Shujing, et al.
(författare)
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Manufacturing Graphene-Encapsulated Copper Particles by Chemical Vapor Deposition in a Cold Wall Reactor
- 2019
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Ingår i: ChemistryOpen. - : Wiley. - 2191-1363. ; 8:1, s. 58-63
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Tidskriftsartikel (refereegranskat)abstract
- Functional fillers, such as Ag, are commonly employed for effectively improving the thermal or electrical conductivity in polymer composites. However, a disadvantage of such a strategy is that the cost and performance cannot be balanced simultaneously. Therefore, the drive to find a material with both a cost efficient fabrication process and excellent performance attracts intense research interest. In this work, inspired by the core-shell structure, we developed a facile manufacturing method to prepare graphene-encapsulated Cu nanoparticles (GCPs) through utilizing an improved chemical vapor deposition (CVD) system with a cold wall reactor. The obtained GCPs could retain their spherical shape and exhibited an outstanding thermal stability up to 179 degrees C. Owing to the superior thermal conductivity of graphene and excellent oxidation resistance of GCPs, the produced GCPs are practically used in a thermally conductive adhesive (TCA), which commonly consists of Ag as the functional filler. Measurement shows a substantial 74.6 % improvement by partial replacement of Ag with GCPs.
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| 2. |
- Shan, Bo, et al.
(författare)
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Preparation of graphene/aligned carbon nanotube array composite films for thermal packaging applications
- 2019
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Ingår i: Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes. - : IOP Publishing. - 0021-4922 .- 1347-4065. ; 58
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Tidskriftsartikel (refereegranskat)abstract
- Vertically aligned carbon nanotube arrays (VACNTs) have been successfully achieved by CVD. The carbon nanotubes were almost triple-walled. Furthermore, the graphene/VACNT composite films have been prepared as thermal interface materials, using photolithographic and densification processes. Compared with pure epoxy resin, the longitudinal thermal conductivity of the composite films was obviously improved, which confirmed that VACNTs provided additional longitudinal heat transfer channels in the films. Furthermore, their longitudinal thermal conductivity was largely dependent on the distribution of VACNTs. The transversal thermal conductivity of the composite film with a pattern size of 300 mu m was about seven times higher than that of pure epoxy resin. This indicated that graphene provided additional horizontal heat transfer channels to achieve the enhancement of transversal thermal conductivity in composite films. (C) 2019 The Japan Society of Applied Physics
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